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A single cylinder indirect injection diesel engine was used to evaluate the emissions, fuel consumption, and ignition delay of non-petroleum liquid fuels derived from coal, shale, and tar sands. Correlations were made relating fuel properties with exhaust emissions, fuel consumption, and ignition delay. The results of the correlation study showed that the indicated fuel consumption, ignition delay, and CO emissions significantly correlated with the H/C ratio, specific gravity, heat of combustion, aromatics and saturates content, and cetane number, Multiple fuel properties were necessary to correlate the hydrocarbon emissions. The NOx emissions did not correlate well with any fuel property. Because these fuels from various resources were able to correlate succesfully with many of the fuel properties suggests that the degree of refinement or the chemical composition of the fuel is a better predictor of its performance than its resource.

The purpose of this paper is to make a preliminary assessment of the potential toxicity of compounds that might be emitted from diesel vehicles using urea/SCR technology. The use of urea as a reductant in the removal of NOx from the exhaust of diesel-powered vehicles has the potential to emit at least seven thermal decomposition products and unreacted urea from the tail-pipe. These compounds include: urea, ammonia, cyanate ion, biuret, cyanuric acid, ammelide, ammeline, and melamine. The toxicity data base for these compounds, in general, is poor. In addition, there have been few, if any, studies examining the inhalation route of exposure - the most likely route of exposure for people from vehicle exhaust. The measurement and identification of these compounds from the exhaust of urea/SCR- equipped vehicles is needed to prioritize the kinds of health effects studies required to understand the toxicity of these compounds.

Natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics are employed to investigate fuel-property effects on mixing-controlled combustion, using select research fuels-a #2 ultra-low sulfur emissions-certification diesel fuel (CF) and four of the Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8)-that varied in cetane number (CN), distillation characteristics, and aromatic content. The experiments were performed in a single-cylinder heavy-duty optical compression-ignition (CI) engine at two injection pressures, three dilution levels, and constant start-of-combustion timing. If the experimental results are analyzed only in the context of the FACE fuel design parameters, CN had the largest effect on emissions and efficiency.

Future European air quality standards for light duty diesel vehicles will include stringent NOx emission regulations. In order to meet these regulations, a lean NOx catalyst system may be necessary. Since the catalytic removal of NOx is very difficult with the large concentration of oxygen present in diesel exhaust, a reductant is usually added to the exhaust to increase the NOx conversion. This paper describes a lean NOx catalyst system for a Transit light-duty truck which uses a reductant solution of urea in water. In this work, a microprocessor was used to vary the amount of the reductant injected depending on the operating conditions of a 2,5 L naturally aspirated HSDI engine. The NOx conversions were 60% and 80% on the current European driving cycle and the U.S. FTP cycles, respectively. Data on the emissions of HC, CO, NOx, particulate mass and composition, individual HC species, aldehydes, PAH and most HC species were evaluated.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

The study investigated the characteristics of the combustion, the emissions and the thermal efficiency of a direct injection diesel engine fuelled with neat n-butanol. Engine tests were conducted on a single cylinder four-stroke direct injection diesel engine. The engine ran at 6.5 bar IMEP and 1500 rpm engine speed. The intake pressure was boosted to 1.0 bar (gauge), and the injection pressure was controlled at 60 or 90 MPa. The injection timing and the exhaust gas recirculation (EGR) rate were adjusted to investigate the engine performance. The effect of the engine load on the engine performance was also investigated. The test results showed that the n-butanol fuel had significantly longer ignition delay than that of diesel fuel. n-Butanol generally led to a rapid heat release pattern in a short period, which resulted in an excessively high pressure rise rate. The pressure rise rate could be moderated by retarding the injection timing and lowering the injection pressure.

Three techniques for the measurement of the oxides of nitrogen in automotive exhaust were evaluated. These included a “nitrous fume” analyzer, a gaseous NO2 colorimeter, and a movable mass spectrometer. All data obtained were compared to data from currently accepted wet chemical methods, the phenoldisulfonic acid and the “modified” Saltzman. Of the techniques evaluated, the mass spectrometer analysis of NO has been found to be the most useful for the study of nitrogen oxides in engine exhaust. The high cost of wet chemical analysis has indicated a need for an improved and continuous analytical method. The mass spectrometer approach measures NO within seconds of its discharge, thus minimizing any reactions prior to measurement.

Urea-selective catalytic reduction (SCR) after-treatment systems are used for reducing oxides of nitrogen (NOx) emissions in medium and heavy duty diesel vehicles. This paper addresses control-oriented modeling, starting from first-principles, of SCR after-treatment systems. Appropriate simplifications are made to yield governing equations of the Urea-SCR. The resulting nonlinear partial differential equations (PDEs) are discretized and linearized to yield a family of linear finite-dimensional state-space models of the SCR at different operating points. It is further shown that this family of models can be reduced to three operating regions. Within each region, parametric dependencies of the system on physical mechanisms are derived. Further model reduction is shown to be possible in each of the three regions resulting in a second-order linear model with sufficient accuracy.

Homogeneous-charge compression-ignition (HCCI) technology has high potential to significantly reduce fuel consumption and NOx emissions over PFI engines. Control of the HCCI combustion process over the full range of conventional PFI operating conditions, however, has been a challenge. This study describes an HCCI-SI dual-mode engine system proposal based on new approaches to optimize the engine performance. A 0.658L single-cylinder engine was built and tested using these concepts. The engine was operated in HCCI mode from idle to 5.5 bar NMEP and up to 4750 rpm. NSFC in HCCI mode was about 175 g/kWh over most of the operating range except at very low load or near the high load boundary. At a part load of 1500 rpm and an equivalent BMEP of 2.62 bar, net indicated fuel efficiency was 50% higher than PFI engines and 30% higher than a prototype SC-DISI engine.

In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.

A fuel cell is an electrochemical engine which converts fuel and oxidant electrochemically into water, other chemical products and electricity. At present, depending on the electrolytic conducting media, five fuel cell types are recognized, the alkaline fuel cell (AFC), the proton exchange membrane fuel cell (PEMFC), the phosphoric acid fuel cell (PAFC), the molten carbonate fuel cell (MCFC), and the solid oxide fuel cell (SOFC). Various types of hydrogen containing fuels can be used in any of the fuel cells, however only the hydrogen-air fueled fuel cell operating at low to medium temperatures (0-450 C) can be considered to meet the zero emission vehicle (ZEV) requirements. Byproducts of the electrochemical reaction of the fuel cells when hydrocarbons and air are used include carbon monoxide, carbon dioxide and at higher temperatures nitrogen oxide.

Procedures are described for rapidly aging and for testing three-way catalysts on an engine dynamometer which are relatable to actual vehicle aging and CVS testing. The accelerated aging cycle consists of a modification of the AMA durability driving cycle; testing consists of the measurement of HC, CO and NOx conversion as a function of A/F with superimposed perturbations which simulate limit cycle variations of A/F in a closed-loop fuel control system.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.

Advances in fuel control strategy, emission system architecture, and catalyst technology have led to dramatic decreases in exhaust emissions in recent years. To continue this trend, especially at high mileages, the impact of engine oil derived contaminants will need to be minimized. In this study, the deactivating effects of oil-derived contaminants on advanced catalyst technologies was assessed using an oxalic acid washing technique to remove phosphorus and other oil-derived contaminants from fleet-aged automotive three-way exhaust catalysts. Acid washing removed most of the phosphorus on the catalyst (chief poison associated with decomposition of the engine oil antiwear additive ZDDP) without significantly affecting other catalyst properties. Catalysts from eight high-mileage vehicles were analyzed, representing four vehicle families.

The regulated and non-regulated emissions of a current diesel passenger car and two light-duty diesel trucks with catalysts and particulate traps were measured to better understand the effects of aftertreatment devises on the environment. The passenger car, a 1.8 L IDI TC Sierra, was tested both with and without three different diesel oxidation catalysts (DOC) and with two fuel sulfur levels, 0 and 0.05 wt%. One light-duty truck, a 2.5 L DI NA Transit, was tested on one fuel, 0.05 wt% sulfur, with and without three different particulate trap/regeneration systems and with and without a urea lean NOx catalyst (LNC) system. A second similar Transit was tested on the 0.05 wt% sulfur fuel with an electrically regenerated trap system. The results are compared to each other, regulated emission standards, and to emissions from gasoline vehicles.

Exhaust and evaporative emissions from three flexible/variable fuel vehicles (FFV/VFV) were measured as the vehicles operated on E85 fuel (a mixture of 85% ethanol and 15% gasoline) or on gasoline. One vehicle was a production vehicle designed for ethanol fuels and sold in 1992-93 and the other two vehicles were prototypes which were recalibrated 1992 model year methanol FFV's. The gasolines tested were Industry Average Fuel A and a reformulated gasoline Fuel C2 that met California 1996 regulatory requirements. The gasoline component of Fuel E85 was based on the reformulated gasoline. The major findings from this three-vehicle program were that E85 reduced NOx 49% compared to Fuel A and 37% compared to Fuel C2, but increased total toxics 108% (5 mg/mi) and 255% (20 mg/mi), respectively, primarily by increasing acetaldehyde. The NOx effect was significant for both engine-out and tailpipe emissions.

The effects of aromatics and mid-range volatility (E100) were investigated in a fleet of sixteen prototype European gasoline vehicles calibrated to meet the 1996 European emissions limits. A 3x3 fuel matrix was blended with independently varying aromatics and E100, other fuel properties being held constant. The test fleet was chosen with a wide variation in emissions, and vehicles fitted with close-coupled catalysts gave lowest emissions. There was also a wide variation in vehicle response to fuel properties. High HC emissions on some vehicles for fuels with low E100 (35% v/v) were attributed to driveability problems caused by these fuels. Reducing aromatics reduced composite cycle fleet average emissions of Carbon Monoxide (CO), Total Hydrocarbons (THC) and Carbon Dioxide (CO2) but increased Oxides of Nitrogen (NOx). Increasing volatility reduced HC emissions, increased NOx, had no effect on Carbon Dioxide and showed minimum CO at 50% v/v aromatics.

This paper summarizes some of the research which has been carried out at Ford Motor Co. in the area of NOx traps. Results from a large body of experimental work are reviewed and used to provide insight into the fundamental processes which govern NOx trap performance. In particular, the key parameters which control thermal durability and sulfur poisoning of the NOx trap are discussed in detail. In addition, a theoretical model of the NOx trap is described and used in the analysis and interpretation of the experimental results.

As part of the P2000 hydrogen fueled internal combustion engine (H2ICE) vehicle program, an engine dynamometer research project was conducted in order to systematically investigate the unique hydrogen related combustion characteristics cited in the literature. These characteristics include pre-ignition, NOx emissions formation and control, volumetric efficiency of gaseous fuel injection and related power density, thermal efficiency, and combustion control. To undertake this study, several dedicated, hydrogen-fueled spark ignition engines (compression ratios: 10, 12.5, 14.5 and 15.3:1) were designed and built. Engine dynamometer development testing was conducted at the Ford Research Laboratory and the University of California at Riverside. This engine dynamometer work also provided the mapping data and control strategy needed to develop the engine in the P2000 vehicle.

Internal combustion (IC) engines fueled by hydrogen are among the most efficient means of converting chemical energy to mechanical work. The exhaust has near-zero carbon-based emissions, and the engines can be operated in a manner in which pollutants are minimal. In addition, in automotive applications, hydrogen engines have the potential for efficiencies higher than fuel cells.[1] In addition, hydrogen engines are likely to have a small increase in engine costs compared to conventionally fueled engines. However, there are challenges to using hydrogen in IC engines. In particular, efficient combustion of hydrogen in engines produces nitrogen oxides (NOx) that generally cannot be treated with conventional three-way catalysts. This work presents the results of experiments which consider changes in direct injection hydrogen engine design to improve engine performance, consisting primarily of engine efficiency and NOx emissions.