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Technical Paper

An Experimental Investigation on Low Temperature CDPF Regeneration Utilizing Hydrogen

2013-03-25
2013-01-0052
Soot particles accumulated in a DPF should be removed after a certain service time due to high pressure drop. The most common method is oxygen active regeneration which sometimes DPF cracking or melting. In this study, the authors aim to investigate the low temperature regeneration with hydrogen, which could prolong the DPF lifespan and facilitate CDPF regeneration efficiency. The DPF used in this research was coated with Pt/Al₂O₃ 25 g/ft₃ and all experiments were performed on engine test bench. Results showed that DPF regeneration can be realized at about 150°C or even lower. During regeneration, the inside temperature at front part (about 20 mm) of DPF was about 40°C higher than the other parts during regeneration. The maximum inside temperatures during regeneration depend only on the hydrogen concentration and soot oxidation can be calculated simply from the Arrhenius equation using the experimental temperatures.
Technical Paper

Combustion Characteristics and Generating Efficiency Using Biogas with Added Hydrogen

2013-10-14
2013-01-2506
Biogas has been used as a fuel because of its lean-burn capability, low cost, and direct application to current engine systems. However, some performance loss occurs when using biogas as a fuel in a typical gas engine. To compensate that performance loss, hydrogen can be added to enhance combustion. Given the increasing need to substitute energy sources, many studies have been performed to examine the performance of biogas-hydrogen blends. In this study, experiments and simulations of a gas engine fueled with biogas were compared to confirm the accuracy of the simulation model under a fixed excess air ratio of 1.2 and spark timing of 16 CA BTDC. Performance predictions were made numerically for various spark timings, excess air ratios, and amounts of added hydrogen. With increased amounts of added hydrogen, the cylinder pressure and heat release rate increased and the ignition delay was reduced.
Technical Paper

Comparison of NOx Level and BSFC for HPL EGR and LPL EGR System of Heavy-Duty Diesel Engine

2007-08-05
2007-01-3451
Diesel engines are the most commonly used power plant of freight and public transportations in the world. Also, the newly developed injection system, Common Rail system, increases the demands for both light and heavy duty diesel vehicles. On the other hand, stringent emission regulations are being proposed with growing concern on NOx and PM emissions from diesel engines. Future emission regulations require advanced emission control technologies, such as EGR and SCR. Exhaust gas recirculation (EGR) is a commonly used technique to reduce NOx emission. In this paper, a model-based investigation was conducted to compare the effect of high pressure loop (HPL) EGR and low pressure loop (LPL) EGR system on NOx level and BSFC of a heavy-duty diesel engine. A WAVE model was created to simulate EURO 3 engine and each component of the engine was modeled using CATIA and WaveMesher.
Technical Paper

Comparison of Soot Oxidation by NO2 Only and Plasma-Treated Gas Containing NO2, O2, and Hydrocarbons

2002-10-21
2002-01-2704
NO2 is an effective soot oxidizer operating at lower temperatures than O2. The effect of pure NO2 on soot oxidation was evaluated and compared with the gas treated by plasma, which initially consisted of NO, O2, and hydrocarbons. The cutout of a commercial DPF was used and the pressure difference across the DPF was monitored for an hour. The concentration of NO/NO2, CO, CO2 at the outlet of the DPF was measured as a function of time. CO and CO2 concentration was measured periodically by gas chromatography. The experiment was performed at 230, 250, 300, 350°C. When NO2 only was used as an oxidizing agent, there was a close relationship between the decrease of the pressure difference across the DPF, the CO and CO2 concentration at the outlet of the DPF, and the back conversion of NO2 to NO.
Technical Paper

Effect of Fuel Properties on Diesel PM Components

2007-07-23
2007-01-1941
In this study, compositions, size distributions and activation energy in oxidation of diesel PM were investigated. Benzene (C6H6) was mixed to diesel fuel as a promoter of PM formation, and further, ferrocene (Fe(C5H5)2) was added as a promoter for oxidation processes during in-cylinder combustion and after-treatment. The effect of those additions on the PM characteristics was discussed on the basis of measured results such as SOF and dry-soot ratio in PM, primary and aggregate particle size distributions of PM, activation energy of PM oxidation, and PM components with elemental analysis. As a result, it was shown that ferrocene had special effect on the PM size distribution and the activation energy.
Technical Paper

Effect of Hydrogen as an Additive on Lean Limit and Emissions of a Turbo Gasoline Direct Injection Engine

2015-09-01
2015-01-1886
For gasoline engine, thermal efficiency can be improved by using lean burn. However, combustion instability occurs when gasoline engine is operated on lean condition. Hydrogen has features that can be used for improving combustion stability of gasoline engine. In this paper, an experimental study of hydrogen effect on lean limit was carried out using a four-cylinder 2.0L turbo gasoline direct injection engine. The engine torque was fixed at 110Nm on 1600RPM, 2000RPM and 2400RPM. The results showed that lean limit was extended and brake thermal efficiency was improved by hydrogen addition. Especially, at lower engine speed, the large improvement of lean limit was achieved. However, improvement of brake thermal efficiency was achieved at high speed. HC and CO2 emissions were decreased and NO emissions increased with hydrogen addition. CO emissions were slightly reduced with hydrogen addition.
Technical Paper

End-Gas Temperature Measurements in a DOHC Spark-Ignition Engine Using CARS

2000-03-06
2000-01-0237
CARS temperature measurements were carried out both in a constant volume combustion chamber and in a spark-ignition engine. The CARS temperature measurement under engine-like condition was validated by comparing the unburned gas temperatures for premixed propane-air flame in a constant volume combustion chamber obtained by CARS with predicted temperatures of 2-zone flame propagation simulation model. There was good agreement between the predicted temperatures and the mean values of 10 CARS measurements. The standard deviation of 10 measurements at each measuring timing was about ±40 K. End-gas temperatures were measured by CARS technique in a conventional 4-cylinder DOHC spark-ignition engine with the engine motoring and firing. The measured motoring temperature matched well with the adiabatic core temperature calculated from the measured cylinder pressure. The engine was fueled with primary reference fuel (PRF80) of 80% iso-octane and 20% n-heptane by volume.
Technical Paper

Evaluation of SOF Effects on Deposit Characteristics of the EGR Cooler Using a PM Generator

2011-04-12
2011-01-1156
The high concentration of particulate matter (PM) in diesel exhaust gas causes significant soot deposition on the wall of EGR cooler, and reduces the heat transfer performance of the EGR cooler and the reduction rate of NOx. The deposition of PM tends to be occurred more severely with "heavy wet PM," which is more frequently at the LTC (low temperature combustion) engine. The objective of this work is to evaluate the effects of soluble organic fraction (SOF) on deposit characteristics of the EGR cooler. To measure reliable mean particle concentration values and surrogate SOFs, the soot generator with SOF vaporizer was used. As for two surrogate SOFs, n-dodecane and diesel lube oil, deposit mass increased when they were injected. Especially from the experiment results, it was found that the lube oil effect was more significant than the n-dodecane effect and lube oil also had a stronger effect on reduction of thermal conductivity by filling pores in deposits.
Technical Paper

Experimental Study on the Oxidation of Model Gases - Propylene, N-Butane, Acetylene at Ambient Temperature by Non-Thermal Plasma and Photocatalyst

2001-09-24
2001-01-3514
Two features to facilitate chemical reactions at low temperature, non-thermal plasma and the weak dependency of photocatalyst on temperature, have been exploited by many researchers to effectively decompose hydrocarbon emissions emitted until the light-off of a three-way catalyst in spark ignition engines. To develop a realizable emissions reduction reactor, as part of such effort, this study investigates for the three model gases, propylene, n-butane and acetylene: 1) the conversion efficiency of the emissions reduction reactor, which utilizes the effect of dissociation, ionization-by-collision of the non-thermal plasma and the photocatalytic effect of TiO2, and 2) the concentrations of the products such as acetaldehyde, acetic acid, polymerized hydrocarbons and NO2. The operating parameters to obtain the plasma energy density ranging from 7.8 to 908 J/L were varied.
Technical Paper

Hydrogen Effect on the DeNOX Efficiency Enhancement of Fresh and Aged Ag/Al2O3 HC-SCR in a Diesel Engine Exhaust

2011-04-12
2011-01-1278
HC-SCR is more convenient when compared to urea-SCR, since for HC-SCR, diesel fuel can be used as the reductant which is already available onboard the vehicle. However, the DeNOX efficiency for HC-SCR is lower than that of urea-SCR in both low and high temperature windows. In an attempt to improve the DeNOX efficiency of HC-SCR, the effect of hydrogen were evaluated for the fresh and aged catalyst over 2 wt.% Ag/Al₂O₃ using a Euro-4 diesel engine. In this engine bench test, diesel fuel as the reductant was injected directly into the exhaust gas stream and the hydrogen was supplied from a hydrogen bomb. The engine was operated at 2,500 rpm and BMEP 4 bar. The engine-out NOX was around 180 ppm-200 ppm. H₂/NOX and HC₁/NOX ratios were 5, 10, 20, and 3, 6, 9, respectively. The HC-SCR inlet exhaust gas temperatures were around 215°C, 245°C, and 275°C. The catalyst volumes used in this test were 2.5L and 5L for both fresh and aged catalysts.
Technical Paper

Low Temperature Active Regeneration of Soot Using Hydrogen in a Multi-Channel Catalyzed DPF

2010-04-12
2010-01-0562
Diesel particulate filter (DPF) systems are being used to reduce the particulate matter emissions of diesel vehicles. The DPF should be regenerated after certain driving hours or distance to eliminate soot in the filter. The most widely used method is active regeneration with oxygen at 550~650°C. Fuel penalty occurs when the exhaust gas temperature is increased. The low temperature oxidation technique is needed to reduce fuel consumption. In this study, we found that hydrogen could be used to decrease the PM oxidation temperature significantly on a catalyzed DPF (CDPF). The oxidation characteristics of PM with hydrogen supplied to CDPF were studied using a partial flow system. The partial flow system was used to control temperature and a flow rate independently. The CDPF was coated with Pt/Al₂O₃ 25g/ft₃, and a multi-channel CDPF (MC CDPF) with a square cross section of 1.65 cm width and length of 10 cm was used.
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