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It has been shown within the catalyst industry that the emission performance with higher cell density technology and therefore with higher specific geometric area is improved. The focus of this study was to compare the overall performance of high cell density catalysts, up to 1600cpsi, using a MY 2001 production vehicle with a 4.7ltr.V8 engine. The substrates were configured to be on the edge of the design capability. The goal was to develop cost optimized systems with similar emission and back pressure performance, which meet physical and production requirements. This paper will present the results of a preliminary computer simulation study and the final emission testing of a production vehicle. For the pre-evaluation a numerical simulation model was used to compare the light-off performance of different substrate designs in the cold start portion of the FTP test cycle.

Recent internal research performed at SwRI examined an emissions control mechanism that we have labeled, ‘phased A/F perturbation.’ The suggested mechanism of phased perturbation involves independently controlling the fuel delivered to each bank of a dual bank engine, which allows the two banks to have an adjustable, relative A/F perturbation phase-shift from one another. Exhaust from the two banks can be combined to achieve a near-stoichiometric mixture prior to entering a single underbody catalyst. Since both rich and lean exhaust species would be present simultaneously, a highly reactive mixture would continuously enter the catalyst. In that work, it was found that A/F phasing produced as significant an effect on conversion efficiency as perturbation amplitude and frequency, i.e. A/F phasing was identified as a third dimension for optimization of exhaust gas composition as it enters the catalyst.