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This empirical work investigates the impacts of thermodynamic parameters, such as pressure and temperature, and fuel properties, such as fuel Cetane number and aromatic contents on ignition delay in diesel engines. Systematic tests are conducted on a single-cylinder research engine to evaluate the ignition delay changes due to the fuel property differences at low, medium and high engine loads under different EGR dilution ratios. The test fuels offer a range of Cetane numbers from 28 to 54.2 and aromatic contents volume ratios from 19.4% to 46.6%. The experimental results of ignition delays are used to derive an ignition delay model modified from Arrhenius’ expression. Following the same format of Arrhenius’ equation, the model incorporates the pressure and temperature effects, and further includes the impacts of intake oxygen concentration, fuel Cetane number and aromatic contents volume ratio on the ignition delay.

Empirical and analytical investigations are conducted to evaluate the thermal response of exhaust pipe plenums at different levels of exhaust gas recirculation and through a variety of fuel delivery strategies. The effectiveness of different combustion control techniques is evaluated for moderating the engine-out exhaust temperature. Comparison of the external fuel injection with in-cylinder post injection for enabling aftertreatment is provided which indicates the stronger temperature raising potential of the external fuel injection. This research attempts to quantify the thermal response of the exhaust pipe plenums and its effects on the gas temperature at the inlet of the aftertreatment devices. The measurement and modeling of the dynamic thermal response in this research intend to improve the performance of diesel aftertreatment devices.

Advanced combustion engines, as power sources, dominate all aspects of the transportation sector. Stringent emission and fuel efficiency standards have promoted the research interest in advanced combustion strategies and alternative fuels. Owing to the comparable energy density to the existing fossil fuels and renewable production, alcohol and ether fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. Furthermore, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. However, lean-burn or EGR dilution can introduce combustion inefficiencies in the form of excessive hydrocarbon, carbonyl species and carbon monoxide emissions.

Diesel fueling and exhaust flow strategies are investigated to control the substrate temperatures of diesel aftertreatment systems. The fueling control includes the common-rail post injection and the external supplemental fuel injection. The post injection pulses are further specified at the early, mid, or late stages of the engine expansion stroke. In comparison, the external fueling rates are moderated under various engine loads to evaluate the thermal impact. Additionally, the active-flow control schemes are implemented to improve the overall energy efficiency of the system. In parallel with the empirical work, the dynamic temperature characteristics of the exhaust system are simulated one-dimensionally with in-house and external codes. The dynamic thermal control, measurement, and modeling of this research intend to improve the performance of diesel particulate filters and diesel NOx absorbers.

Ammonia is a potential alternative fuel that was indeed put into use in Belgium in World War II due to the extreme shortage of diesel. It has a high heating value per unit volume (1.16 × 107 kJ/m3) and its combustion products can be as or more environment-friendly compared to conventional hydrocarbon fuels. This study examined the combustion characteristics of premixed ammonia-air mixtures at atmospheric and elevated conditions which are encountered in SI engine operation. The laminar burning velocity, flame temperature and species distribution were determined using the Lindstedt mechanism in CHEMKIN. A freely propagating flame was assumed to facilitate the investigation. The predicted laminar burning velocity and the flammability limits were compared with experimental values.

The heat rejection process of CO2 air conditioning system takes place in the supercritical region, where pressure is independent of temperature. It has been demonstrated that at any particular ambient temperature, the system efficiency varies nonlinearly with the working pressure. The optimum high pressure was thereby tracked and derived in this study, which corresponds to the best system performance. The system simulation was conducted over typical working pressures. The simulation results suggested that for a specific compressor speed, the gas cooler outlet temperature or the ambient temperature could be used to adjust the high pressure to achieve the maximum COP.

Increasingly stringent emission standards have promoted the interest in alternate fuel sources. Because of the comparable energy density to the existing fossil fuels and renewable production, alcohol fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. In this research, the combustion characteristics of neat n-butanol are analyzed under spark ignition operation using a single cylinder SI engine. The fuel is injected into the intake manifold using a port-fuel injector. Two modes of charge dilution were used in this investigation to test the limits of stable engine operation, namely lean burn using excess fresh air and exhaust gas recirculation (EGR). The in-cylinder pressure measurement and subsequently, heat release analysis are used to investigate the combustion characteristics of the fuel under low load SI engine operation.

Empirical work has been conducted with an EGR fuel reformer configured in a flow reversal and central fueling embedment to improve the fuel dispersion quality and the reforming energy efficiency. Comprehensive comparison analyses are made between the unidirectional flow and the periodic reversal flow embodiments of similar substrate size and properties; and between the inlet and central heating schemes. With a unidirectional EGR reformer, a large amount of supplemental heating is commonly required prior to reforming. The central-fueling and flow-reversal embedment in this study is shown to significantly reduce the supplemental heating energy. The EGR cooler loading for the two strategies is also analyzed. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions.

An experimental investigation of low temperature combustion (LTC) cycles is conducted with diesel and ethanol fuels on a high compression ratio (18.2:1), common-rail diesel engine. Two LTC modes are studied; near-TDC injection of diesel with up to 60% exhaust gas recirculation (EGR), and port injected ethanol ignited by direct injection of diesel with moderate EGR (30-45%). Indicated mean effective pressures up to 10 bar in the diesel LTC mode and 17.6 bar in the dual-fuel LTC mode have been realized. While the NOx and smoke emissions are significantly reduced, a thermal efficiency penalty is observed from the test results. In this work, the efficiency penalty is attributed to increased HC and CO emissions and a non-conventional heat release pattern. The influence of heat release phasing, duration, and shape, on the indicated performance is explained with the help of parametric engine cycle simulations.

The effects of the addition of small amounts of molecular and atomic hydrogen/oxygen on laminar burning velocity, pollutant concentrations, and adiabatic flame temperatures of premixed, laminar, freely propagating iso-octane flames are investigated using CHEMKIN kinetic simulation package and a chemical kinetic mechanism at different equivalence ratios. It is shown that hydrogen/oxygen additives increase the laminar burning velocities. Increased hydroxyl (OH) concentrations resulted in reduced carbon monoxide (CO) emissions in every stoichiometric ratios investigated. Additives also increased the adiabatic flame temperature of iso-octane/air combustion, thereby causing increased NOx concentrations for all additives at all stoichiometries.

The pressure wave actions were investigated in the exhaust system of a single cylinder diesel engine through both experimental and simulation methods. The characteristics of the exhaust pressure waves under different engine operating conditions, such as engine load and exhaust backpressure, were examined. The results showed that the strength of the exhaust pressure wave was affected by both the in-cylinder pressure and the exhaust backpressure in the exhaust system during the period when the exhaust valves were open. The exhaust gas flow velocity was also estimated by the one dimensional simulation tool AVL BOOST™. The results suggested that the velocity of the exhaust gas fluctuated during the engine cycle, and followed trends similar to the exhaust pressure wave. The transient gas flow velocity was high when there was a strong compression wave, and it was reduced when the pressure fluctuations in the exhaust manifold were small.

Flame stretch arises due to strain and change in flame curvature and is extremely important in spark ignition (SI) engine combustion. It can significantly alter the flame speed and hence, the burning duration. This, in turn, can have serious influence on engine performance and exhaust emission. A good understanding of stretch effect can thus lead to improved fuel efficiency, reduced cyclic variations, and better emission control for SI engines. In this study, we analyzed initial temperature and pressure effects on the stretched flame speed of a laminar, premixed, freely propagating, spherical methane-air flame in accordance with the Markstein theory, which postulates a linear relationship between stretched and unstretched flame speed. The unstretched flame speed was computed using CHEMKIN GUI 4.0.1 with GRI Mech 3.0 reaction mechanism. Analytical expressions relating stretched and unstretched flame speed were employed to derive the stretched flame speed.

The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.