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SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

For the simultaneous evaluation of the influence on engine knock of both chemical conditions and global operating parameters, a combined tool was developed. Thus, a two-zone kinetic model for SI engine combustion calculation (Ignition) was implemented into an engine cycle simulation commercial code. The combined model predictions are compared with experimental data from a single-cylinder test engine. This shows that the model can accurately predict the knock onset and in-cylinder pressure and temperature for different lambda conditions, with and without EGR. The influence of nitric oxide amount from residual gas in relation with knock is further investigated. The created numerical tool represents a useful support for experimental measurements, reducing the number of tests required to assess the proper engine control strategies.