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Catalytic emission control systems are installed on nearly all automobiles and heavy-duty trucks produced today to reduce exhaust emissions for the vehicles to meet government regulations. Current systems can achieve very high efficiencies in reducing tailpipe emissions once the catalytic components reach their operating temperatures. They are, however, relatively ineffective at temperatures below their operating temperature windows, especially during the cold start period of the vehicles. With the increasingly stringent government regulations, reducing the emissions during the cold start period before the catalytic components reach their operating temperatures is becoming a major challenge. For cold start HC control, HC traps based on zeolites have been investigated and commercialized for certain applications. For cold start NOx control, especially in lean burn engine exhaust, NOx storage and release catalysts have been evaluated.

Selective catalytic reduction (SCR) of NOx by NH3 is under intensive development as a technology to enable diesel engines to meet stringent NOx emission regulations. Cu/zeolite SCR catalysts are leading candidates because of their ability to catalyze NOx reduction at the low temperatures encountered on many diesel vehicles. However, both engine evaluation and laboratory studies indicated that commonly available Cu/zeolite SCR catalysts did not have sufficient thermal stability to maintain performance during the full useful life of a vehicle (with steady-state NOx conversion decreasing ~ 10% over 64 hours of hydrothermal aging at 670 °C). Characterization of aged Cu/zeolite catalysts revealed that the loss of zeolite acidity was the main deactivation mechanism; while the zeolite support maintained its framework structure and surface area after aging. Improvement of the hydrothermal stability of the acid sites resulted in a new generation of SCR catalysts.

The modern Diesel engine is one of the most versatile power sources available for mobile applications. The high fuel economy and power of the Diesel engine has long made it the choice for heavy-duty applications worldwide. Over the coming years, global emissions legislation applied to heavy-duty Diesel (HDD) engines will become more and more stringent, necessitating the use of advanced emissions control technologies. In particular, the coming exhaust gas emissions legislation focuses on particulate matter (PM) emissions and emissions of nitrogen oxides (NOx). A filtration device can control PM emissions, and a possible technology for the abatement of NOx emissions involves NOx absorber catalysts. This paper describes investigations into the activity and system behaviour of a prototype HDD exhaust system based on NOx absorber technology. The system consists of a “single leg” containing NOx absorber catalyst that is bypassed during rich regeneration of the NOx absorbers.