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The supercritical CO2 power cycle system for waste heat recovery (WHR) of internal combustion engine (ICE) has widely been concerned as a research hotspot. And the expander is a key component in the supercritical CO2 power system. Rolling rotor expander has the following advantages: compact size, light weight, less moving parts, high stability and long service life, which qualify it a very suitable choice for engine’s waste heat recovery system. For a self-designed rolling rotor expander using supercritical CO2 as its working fluid, FLUENT software was used to simulate its internal flow field in this study, obtaining the changes of the internal pressure field and turbulent kinetic energy. The causes of local vortex in the expansion process were analyzed. Under different working conditions of the expander, the change of internal pressure and the distribution of P-V curve were observed, and the work capacity under different inlet pressure was analyzed.