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The current legislation does not take into account the limitation of sub 23 nm particles from engine. Nevertheless, the Common Rail Diesel engine emits a large number of nanoparticle, solid and volatiles, that are very dangerous for human health. In this contest, the challenge of the “dieper EU project” is to apply advanced technologies for exhaust after-treatment to existing diesel engines and to optimize the characteristics of a new generation of engines with regards to emissions, fuel consumption and drivability. Aim of the present paper is to provide useful information for the development of the after-treatment system that will have to fulfill Euro6 further steps. In order to characterize the chemical and physical nature of Particulate Matter emitted from Euro 6b Medium Duty diesel engine, the pollutants were collected and analyzed: from engine-out, downstream of the particulate filter (DPF), and at the exit of a selective catalytic reactor (SCR).

This work regards the study of the effect of the fuel properties on the diesel engine emissions of particulate separated in soluble organic fraction (SOF) and soot. A Euro-4 engine was used operating at two engine conditions: 1500 rpm speed − 8% of maximum load and 2300 rpm − 13%. Model hydrocarbon fuels containing 100% of n-alkanes and iso-alkanes were used for studying the effect of cetane number. The effect of fuel composition on soot and SOF emissions was studied at a fixed cetane number (52) by using six fuels formulated with 90 vol% of model alkanes and iso-alkanes and 10 vol% of different components as alkylbenzenes, naphthenes (decaline), diaromatics (methylnaphthalene), fatty acid methyl esters (FAME) and highly paraffinic refinery streams (Fischer-Tropsch GtL and high-pressure Hydro cracking).