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A methodological analysis of combustion parameters and pollutant emissions measuring procedures during transient operation of a D.I. T.C. light duty diesel engine was performed. Combustion process was characterized by ignition delay time, combustion pressure peak value and heat release law measurements during the transient ECE 15 schedule on a dynamic test bed with electronic simulation of inertia. The particulate emission was measured every 0.05 s by an I.R. optical method. In addition some correlations, based on pressure cycle and injection law evolution, were implemented in order to calculate instantaneous fuel delivery and transient NOx emission. Some activities were carried out in order to asses the limits of engine configurations ranking performed with steady state measurements of performances and emissions. Strong differences were detected between carbon emission during transient operations and the value obtained by interpolation from a steady state map.

The formation and oxidation of soot, light and heavy hydrocarbons, CO, CO2 and NOx in a D.I. diesel engine have been studied by means of direct fast sampling and chemical analysis of the combustion products collected during the combustion cycle. Particular attention has been paid to the histories of each fuel hydrocarbon class analyzing the chemical transformations that the paraffins, and monoaromatic and polyaromatic compounds, contained in a diesel fuel oil, undergo during the combustion cycle. This approach is able to give information on the origin of soot and heavy hydrocarbon emission from a diesel engine. The concentration of the heavy hydrocarbons decreases during the early stages of the combustion cycle and their profile corresponds roughly to the fuel disappearance rate because of the chemical similarity with the fuel compounds.