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On-board hydrogen generation technology using a fuel reforming catalyst is an effective way to improve the fuel efficiency of automotive internal combustion engines. The main issue to be addressed in developing such a catalyst is to suppress catalyst deterioration caused by carbon deposition on the catalyst surface due to sulfur adsorption. Enhancing the hydrocarbon and water activation capabilities of the catalyst is important in improving catalyst durability. It was found that the use of a rare earth element is effective in improving the water activation capability of the catalyst. Controlling the hydrocarbon activation capability of the catalyst for a good balance with water activation was also found to be effective in improving catalyst durability.

Diesel exhaust contains a lower level of hydrocarbons, which serve as the reductant for the NOx catalyst, than gasoline engine exhaust. An investigation was made of several methods for maximizing the performance of NOx catalysts for direct-injection diesel engines. First, the catalysts were given an HC adsorption capability and then their characteristics were tailored to the HC species contained in diesel exhaust. This HC adsorption capability is designed to achieve better utilization of the HC species in diesel exhaust as a reductant. Second, catalyst performance was examined under passive and active conditions. Excellent catalyst performance was obtained under a passive condition, because at high engine loads, NOx catalysts with an HC adsorption capability can utilize HCs adsorbed under low engine load conditions to reduce NOx.