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The experiments were performed with two types of test engines, '72 model year type and '94 model year type engine, using both of conventional diesel fuel and synthetic diesel fuel, which has simple hydrocarbon components and no aromatics or sulfur content. SOF is extracted from the particulate sample exhausted out from the engines, then GC and GC-MS analyses were carried out. By comparing the results obtained, the role of high boiling point components in diesel fuel on SOF emission were observed. Further, by adding an artificially sulfur-containing compound and pyrene, which is a four ring polynuclear-aromatic-hydrocarbon (PAH), into the synthetic fuel, the effect of PAH content in fuel on PAH emission in SOF and the increase of SOF with increased sulfur content in fuel, were observed.

The Thermogravimetry SOF measurement method is developed as simple and time-saving method. It is experimentally revealed that this method is useful for SOF measurement and the method has potential to distinguish SOF component. The oxidation catalysts can effectively reduce particulate matter under actual driving conditions. Sulfate formation suppressing oxidation catalyst reduces high molecular number paraffins. However, it is important for further development of oxidation catalyst to improve the oxidation ability of polar hydrocarbons included in SOF. The oxidation catalysts can effectively reduce CO, HC emissions under actual driving conditions. This is caused by the temperature rise of oxidation catalysts during accelerations.

Particulate matter (PM) and polynuclear aromatic hydrocarbons (PAH) were measured under steady state engine operating conditions in the exhaust of a DI diesel engine that meets the Japanese 1994 heavy-duty vehicle standards. In this study, to examine and discuss the effects of pyrene and sulfur contents in fuels on PM and PAH emissions, experiments were performed using both ordinary diesel fuel and a specified fuel having simple hydrocarbon components and very few aromatics. In the experiments, pyrene and sulfur contents in the fuels were changed by the addition of reagents to the fuel. The following conclusions were obtained. (1) From the experiments using ordinary JIS No. 2 diesel fuel with a pyrene reagent added to yield 400ppm pyrene, it was found that pyrene addition brings about an increase in soluble organic fraction (SOF) under low load engine operating conditions.