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The residual gas in SI engines is one of important factors on emission and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and there are deeply related with combustion stability, especially at Idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. A model for predicting the residual gas fraction has been formulated in this paper. The model accounts for the contribution due to the back flow of exhaust gas to the cylinder during valve overlap and it includes in-cylinder pressure prediction model during valve overlap. The model is derived from the one dimension flow process during overlap period and a simple ideal cycle model.

Modeling of unburned hydrocarbon oxidation in an SI engine was performed in engine condition using modified one-step oxidation model. The new one-step equation was developed by modifying the Arrhenius reaction rate coefficients of the conventional one-step model. The modified model was well matched with the results of detailed chemical reaction mechanism in terms of 90 % oxidation time of the fuel. In this modification, the effect of pressure and intermediate species in the burnt gas on the oxidation rate investigated and included in developed one-step model. The effect of pressure was also investigated and included as an additional multiplying factor in the reaction equation. To simulate the oxidation process of piston crevice hydrocarbons, a computational mesh was constructed with fine mesh density at the piston crevice region and the number of cell layers in cylinder was controlled according to the motion of piston.

Conventional combustion models are suitable for predicting flame propagation for a wrinkled flamelet configuration. But they cannot predict the burned gas composition. This causes the overestimation of burned gas temperature and pressure. A modified method of combustion simulation was established to calculate the chemical composition and to investigate their ultimate fate in the burned gas region. In this work, the secondary products of combustion process, like CO and H2, were considered as well as the primary products like CO2 and H2O. A 3-dimensional CFD program was used to simulate the turbulent combustion and a zero dimensional equilibrium code was used to predict the chemical composition of burned gas. With this simple connection, more reasonable temperature and pressure approaching the real phenomena were predicted without additional time costs.