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The thermal cracking and polyaromatic hydrocarbon (PAH) formation processes of dimethyl ether (DME), ethanol, and ethane were investigated with chemical kinetics to determine the soot formation mechanism of oxygenated fuels. The modeling analyzed three processes, an isothermal constant pressure condition, a temperature rising condition under a constant pressure, and an unsteady condition approximating diesel combustion. With the same mole number of oxygen atoms, the DME rich mixtures form much carbon monoxide and methane and very little non-methane HC and PAH, in comparison with ethanol or ethane mixtures. This suggests that the existence of the C-C bond promotes the formation of PAH and soot.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

Remarkable progress has been made in recent years on pressure measuring techniques and apparatuses, yet they seem not necessarily successful in achieving accurate pressure diagrams at the high frequency range. The primary cause of difficulty lies in the occurrence of undesirable vibrations in the connecting passages which diminishes the accuracy of pressure diagrams. In order to prevent such vibration, the authors have attempted to increase the natural frequency in the connecting passages by enclosing heat resisting silicon oil, to analyse the frequency characteristics of the passages, and to ensure the propriety of the analysis through comparison with experiments. As a result, it is proved that the natural frequency of the silicon oil enclosed passage increases twice as high as that of the passage filled with working gas.