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Modern Passenger Car Motor Oils (PCMOs) are formulated to provide superior wear, oxidation, and deposit control under the most demanding driving conditions. In most PCMOs, zinc dialkyldithiophosphate (ZnDTP) has been the dominant antiwear and antioxidant agent for well over 50 years. Unfortunately, the phosphorus in ZnDTP may partially deactivate the exhaust emission catalyst. To ensure that the catalysts function for at least 120,000 miles, engine manufacturers are exploring phosphorus limitations for upcoming PCMO performance categories. This paper explores the antiwear film formation of low phosphorus engine oils using the Electrical Contact Resistance bench test. A prototype ILSAC GF-4 formulation blended with varying amounts and types of ZnDTP was tested at temperatures typical of operating engines. Secondary ZnDTP was found to produce the best films under the broadest temperature range.

Fleet customers demand reduced operating costs. This necessitates the development of engine oils which can provide maximum fuel economy and extended oil drains, while still maintaining engine durability. This is particularly important in diesel engines produced since October 1998. These engines use retarded timing to meet EPA's emission requirements and, as a consequence in some cases, generate high soot levels in the engine oil. Extended oil drains in 1995 Caterpillar 3406E and 1996 Detroit Diesel Series 60 engines found no statistical difference in fuel economy or wear between a synthetic SAE 5W-40 and an SAE 15W-40 using API Group II base stocks. Both oils had the same API CG-4/SJ quality level. Soot levels at oil drains of 40,000-50,000 miles (64,372 - 80,465 km) ranged from 0.5-1.2%.

In order to meet EPA's emission requirements for 1999 diesel engines, soot levels in the crankcase oil will increase significantly due to retarded timing to lower NOx. This study uses the Cummins M11 engine at soot levels up to 9% in the crankcase oil to demonstrate how oils can be formulated to prevent valve train wear, extend filter life, and maintain oil pumpability. The study includes the oil formulation development and the evaluation of API CG-4/SJ oils at 4.5% soot and API CH-4/SJ oils at 9% soot. In addition it includes X-Ray Photoelectron Spectroscopy (XPS) for surface film analysis and Surface Optical Profilometry and Scanning Electron Microscopy (SEM) of the valve train valve-bridges and rocker pads to determine the mechanism of failure. The oil's low temperature rheology as it affects oil pumpability is defined by Mini Rotary Viscometer (MRV TP-1), Scanning Brookfield Test (SBT), and Cold Cranking Simulator (CCS).