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A high pressure capable, free piston rapid compression expansion machine (RCEM) has been used to investigate the autoignition, or Homogeneous Charge Compression Ignition (HCCI) behavior of a wide range of fuels. Thermal efficiencies and emissions characteristics were reported previously, but the heat release rates (HRR) and mass fractions burned (χ) seen under the experimental conditions were not specifically determined. This work investigates the characteristic heat losses in this device for use in determination of the HRR and χ. The heat flux is derived from surface temperature thermocouple data; a spatially-uniform, global convection model is correlated to this. Data from lean n-pentane and n-hexane in air mixtures were used to calibrate the model. The RCEM-calibrated model was compared to similar models that were calibrated to IC engines operating on HCCI, and to predictions from the CFD code KIVA3V.

Knock integrals and corresponding ignition delay (τ) correlations are often used in model-based control algorithms in order to predict ignition timing for kinetically modulated combustion regimes such as HCCI and PCCI. They can also be used to estimate knock-inception during conventional SI operation. The purpose of this study is to investigate the performance of various τ correlations proposed in the literature, including those developed based on fundamental data from shock tubes and rapid compression machines, those based on predictions from isochoric simulations using detailed chemical kinetic mechanisms, and those deduced from data of operating engines. A 0D engine simulation framework is used to compare the correlation performance where evaluations are based on the temperatures required at intake valve closure (TIVC) in order to achieve a fixed CA50 point over a range of conditions.

Simulation of chemical kinetic processes in combustion engine environments has become ubiquitous towards the understanding of combustion phenomenology, the evaluation of controlling parameters, and the design of configurations and/or control strategies. Such calculations are not free from error however, and the interpretation of simulation results must be considered within the context of uncertainties in the chemical kinetic model. Uncertainties arise due to structural issues (e.g., included/missing reaction pathways), as well as inaccurate descriptions of kinetic rate parameters and thermochemistry. In fundamental apparatuses like rapid compression machines and shock tubes, computed constant-volume ignition delay times for simple, single-component fuels can have variations on the order of factors of 2-4.