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Four broad boiling range materials, representative of current and future feedstocks for diesel fuel, were processed to two levels of sulfur and aromatic content. These materials were then distilled into six to eight fractions each. The resulting 63 fuels were then characterized physically and chemically, and tested in both a constant volume combustion apparatus and a single cylinder diesel engine. The data obtained from these analyses and tests have been analyzed graphically and statistically. The results of the initial statistical analysis, reported here, indicate that the ignition quality of a fuel is dependent not only on the overall aromatic content, but also on the composition of the material formed during hydroprocessing of the aromatics. The NOx emissions, however, are related mainly to the aromatic content of the fuel, and the structure of the aromatic material.

The U.S. Environmental Protection Agency (EPA) formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee in 1995. The goal of the HDEWG was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). A three-phase program was developed. This paper presents the results of the statistical analysis of the data collected in the Phase II program. Included is a description of the design of the fuel test matrix, and a listing of the regression equations developed to predict emissions as a function of fuel density, cetane number, monoaromatics, and polyaromatics. Also included is a description of selected analyses of the emissions from a smaller set of fuel data that allowed direct comparison of the effects of natural and boosted cetane number.