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Low Temperature Combustion (LTC) is an emerging technology that offers an alternative to conventional spark and compression ignition. A highly discussed LTC mode is homogeneous charge compression ignition (HCCI), which consists in a combustion of a highly diluted well-mixed charge at the end of compression stroke, when the charge reaches the auto-ignition state. Since HCCI is an LTC mode, it can result in low NOX emissions with an indicated efficiency comparable to a diesel engine. Otherwise, there are some challenges to overcome such as achieving high loads without knocking and combustion timing control. Several methods to control the combustion had been investigated, between them, the injection of water may be useful to extend HCCI knock free operation and to enable combustion phasing control. This work investigated the influence of water injection in the intake of an ethanol HCCI cylinder from a converted diesel generator set.