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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

A fast time-scale 1-D dynamic diesel particulate filter model capable of resolving the pressure pulsations due to individual cylinder firing events is presented. The purpose of this model is to investigate changes in the firing frequency component of the pulsating exhaust flow at different particulate loadings. Experimental validation data and simulation results clearly show that the magnitude and phase of the firing frequency components are directly correlated to the mass of particulate stored in a diesel particulate filter. This dynamic pressure signal information may prove particularly useful for monitoring particulate load during vehicle operation.

Diesel engines, especially CR (Common Rail) DI (Direct Injection) TCI (Turbo Charged Inter-cooled), share a wide acceptance in the passenger car market due to the enormous torque and flexibility at low engine speed. A pre - condition for the use of a diesel engine in a motorcycle is that the disadvantages like combustion noise and visible smoke are reduced or eliminated. Moreover the fuel economy and performance characteristics of a diesel engine are dedicated to be used in a touring or large displacement motorcycle. The AVL engine concept is the first high performance diesel engine to be specially designed for motorcycles in terms of packaging and styling. To compensate for the limited engine speed range a gearbox with a wide ratio spread is required. This leads to a manual transmission with at least 6 gears or an automatic transmission. For the AVL concept an AMT (Automated Manual Transmission) was selected.

Advanced Vehicle Technologies (AVT), a Ballarat Australia based company, has developed the World's first diesel to 100% LPG conversion for heavy haul trucks. There is no diesel required or utilized on the trucks. The engine is converted with minimal changes into a spark ignition engine with equivalent power and torque of the diesel. The patented technology is now deployed in 2 Mercedes Actros trucks. The power output in engine dynamometer testing exceeds that of the diesel (in excess of 370 kW power and 2700 Nm torque). In on-road application the power curve is matched to the diesel specifications to avoid potential downstream power-train stress. Testing at the Department of Transport Energy & Infrastructure, Regency Park, SA have shown the Euro 3 truck converted to LPG is between Euro 4 and Euro 5 NOx levels, CO2 levels 10% better than diesel on DT80 test and about even with diesel on CUEDC tests.

Nine identical 40-ft. transit buses were operated on B20 and diesel for a period of two years - five of the buses operated exclusively on B20 (20% biodiesel blend) and the other four on petroleum diesel. The buses were model year 2000 Orion V equipped with Cummins ISM engines, and all operated on the same bus route. Each bus accumulated about 100,000 miles over the course of the study. B20 buses were compared to the petroleum diesel buses in terms of fuel economy, vehicle maintenance cost, road calls, and emissions. There was no difference between the on-road average fuel economy of the two groups (4.41 mpg) based on the in-use data, however laboratory testing revealed a nearly 2% reduction in fuel economy for the B20 vehicles. Engine and fuel system related maintenance costs were nearly identical for the two groups until the final month of the study.

Because of the size and weight of the various components going into the machine, new approaches were used to solve the practical limitations of manufacturing facilities, shipping clearances, and erection procedures. Although the general appearance of the machine is similar to previous units, there are a number of new design features incorporated in the unit. This paper will be limited to the major design considerations as follows: adaption to stripping two seams of coal simultaneously; dipper with two doors; computerized hydraulic steering maintaining Ackerman correction; double end drive crawlers and belt tensioning; and electrical innovations.

The challenge for the diesel engines today is to reduce harmful emissions, such as particulate matter (PM) and Nitrogen oxides (NOx), and enhance the fuel efficiency and power, which are its main advantages. To meet this challenge, DENSO has developed an advanced common rail system (CRS) that uses piezo actuated fuel injectors capable of delivering up to five injection events per combustion cycle at 180MPa, currently the world's highest commercially available diesel fuel injection pressure. The DENSO piezo injector incorporates an internally developed piezoelectric element that energizes quicker than its solenoid counterpart, thereby reducing the transition time for the start and end of the fuel injection event. The piezoelectric element and unique passage structure of the DENSO injector combine to provide a highly reliable and responsive fuel injection event.

General Motors Powertrain Division has developed the next generation big block V8 engine for introduction in the 1996 model year. In addition to meeting tighter emission and on-board diagnostic legislation, this engine evolved to meet both customer requirements and competitive challenges. Starting with the proven dependability of the time tested big block V8, goals were set to substantially increase the power, torque, fuel economy and overall pleaseability of GM's large load capacity gasoline engine. The need for this new engine to meet packaging requirements in many vehicle platforms, both truck and OEM, as well as a requirement for minimal additional heat rejection over the engine being replaced, placed additional constraints on the design.

General Motors Powertrain Group (GMPTG) has developed an all new small block V8 engine, designated LS1, for introduction into the 1997 Corvette. This engine was designed to meet both customer requirements and competitive challenges while also meeting the ever increasing legislated requirements of emissions and fuel economy. This 5.7L V8 provides increased power and torque while delivering higher fuel economy. In addition, improvements in both QRD and NVH characteristics were made while meeting packaging constraints and achieving significant mass reductions.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The present work focuses on the simulation of the hydrodynamics, transient filtration/loading and catalytic/NO2-assisted regeneration of Diesel after-treatment systems. A 1D unsteady model for compressible and reacting flows for the numerical simulation of the behavior of Diesel Oxidation Catalysts (DOCs) and Diesel Particulate Filters (DPFs) has been developed. The numerical model is able to keep track of the amount of soot in the flow; the increasing of back-pressure through the exhaust system (mainly due to the Diesel Particulate Filter) can be predicted by the calculation of the permeability variation of the porous wall, as the soot particles goes inside the DPF. A sub-model for the regeneration of the collected soot has been developed: the collected particulate is oxidized by the Oxygen (O2) and by the Nitrogen Dioxide (NO2).

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

Although in-cylinder optical diagnostics have provided significant understanding of conventional diesel combustion, most alternative combustion strategies have not yet been explored to the same extent. In an effort to build the knowledge base for alternative low-temperature combustion strategies, this paper presents a comparison of three alternative low-temperature combustion strategies to two high-temperature conventional diesel combustion conditions. The baseline conditions, representative of conventional high-temperature diesel combustion, have either a short or a long ignition delay. The other three conditions are representative of some alternative combustion strategies, employing significant charge-gas dilution along with either early or late fuel injection, or a combination of both (double-injection).

In order to investigate the soot formation process in a diesel spray flame, simultaneous imaging of soot precursor and soot particles in a transient spray flame achieved in a rapid compression machine was conducted by laser-induced fluorescence (LIF) and by laser-induced incandescence (LII) techniques. The 3rd harmonic (355nm) and the fundamental (1064nm) laser pulses from an Nd:YAG laser, between which a delay of 44ns was imposed by 13.3m of optical path difference, were used to excite LIF from soot precursor and LII from soot particles in the spray flame. The LIF and the LII were separately imaged by two image-intensified CCD cameras with identical detection wavelength of 400nm and bandwidth of 80nm. The LIF from soot precursor was mainly located in the central region of the spray flame between 40 and 55mm (270 to 370 times nozzle orifice diameter d0) from the nozzle orifice. The LII from soot particles was observed to surround the soot precursor LIF region and to extend downstream.

The two-dimensional distribution of a soot cloud in an unsteady spray flame in a rapid compression machine(RCM) was visualized using the laser sheet scattering technique. A 40 mm x 50 mm cross section on the flame axis was illuminated by a thin laser sheet from a single pulsed Nd:YAG laser(wavelength 532 nm). Scattered light from soot particles was taken by a CCD camera via a high speed gated image intensifier. The temporal variation of the scattered light images were presented with the injection pressure as a parameter. The results showed that scattered light was intense near the periphery of the flame tip and that the scattered light becomes weaker significantly and disappears fast after the end of injection as injection pressure is increased. This technique was also applied to the visualization of the two-dimensional distribution of liquid droplets in the non-evaporating spray to correlate it with the soot concentration distribution.

After the first appearance of LED rear lamps, which employed mainly two-dimensional arrays of LEDs, the request of stylists and OEMs to have three-dimensional LED alignment has increased strongly. Development of more powerful LEDs and new packaging and assembly technologies now allows for a three-dimensional assembly of the LEDs, giving an impression of depth and enabling the LEDs to follow even extreme curvatures. This gives great customer satisfaction in terms of styling, but the disadvantage is that the cost for the three-dimensional LED alignment increases significantly. To counteract this development, we have developed a light guide technology approach (so-called 2.5 D) to combine a cost efficient LED assembly process with the flexibility of a 3 D arrangement of the light sources. Thus, we can use standard planar FR4 (Flame Resistant 4) LED printed circuit boards with arbitrary LEDs and do not depend on a certain assembly technology.

Today turbo-diesel powertrains offering low fuel consumption and good low-end torque comprise a significant fraction of the light-duty vehicle market in Europe. Global CO₂ regulation and customer fuel prices are expected to continue providing pressure for powertrain fuel efficiency. However, regulated emissions for NO and particulate matter have the potential to further expand the incremental cost of diesel powertrain applications. Vehicle segments with the most cost sensitivity like compacts under 1400 kg weight look for alternatives to meet the CO₂ challenge but maintain an attractive customer offering. In this paper the concepts of downsizing and downspeeding gasoline engines are explored while meeting performance needs through increased BMEP to maintain good driveability and vehicle launch dynamics. A critical enabler for the solution is adoption of gasoline direct injection (GDi) fuel systems.

Until recently, the application of the detailed chemistry approach as a predictive tool for engine modeling has been sort of a “taboo” for different reasons, mainly because of an exaggerated rigor to the chemistry/turbulence interaction modeling. In terms of this ideology, if the interaction cannot be simulated properly, the detailed chemistry approach makes no sense. The novelty of the proposed methodology is the coupling of a generalized partially stirred reactor, PaSR, model with the high efficiency numerics to treat detailed oxidation kinetics of hydrocarbon fuels. In terms of this approach, chemical processes are assumed to proceed in two successive steps: the reaction follows after the micro-mixing is completed on a sub-grid scale.