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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

It has been long established fact that fuel economy is a key driving force of low viscosity gasoline engine oil research and development considered by the original equipment manufacturers (OEMs) and lubricant companies. The development of low viscosity gasoline engine oils should not only focus on fuel economy improvement, but also on the low speed pre-ignition (LSPI) prevention property. In previous LSPI prevention literatures, the necessity of applying Ca/Mg-based detergents system in the engine oil formulations was proposed. In this paper, we adopted a specific Group III base oil containing Ca-salicylate detergent, borated dispersant, Mo-DTC in the formulation and investigated the various effects of Mg-salicylate and Mg-sulfonate on the performance of engine oil. It was found that Mg-sulfonate showed a significant detrimental impact on silicone rubber compatibility while the influence from Mg-salicylate remains acceptable.

THIS paper deals with the road-test portion of the extensive efforts made during 1937 by the Cooperative Fuel Research Committee to get as precise a correlation as possible between the laboratory knock ratings of automobile fuels and their corresponding ratings in cars on the road. It is anticipated that the comprehensive results of car tests reported here, taken together with the results of the laboratory rating program reported in the companion paper, will serve as the basis of the continuing studies aimed at developing the best possible correlation between road and laboratory knock ratings. Work similar to that reported here has been conducted concurrently in England by the Institution of Petroleum Technologists, using British cars and fuels. An exchange of information between the British and American groups working on this problem is being made.

THE 1940 CFR Road Tests have developed new information that can be used for the development of fuels and engines. Application of the principles worked out in these tests is expected to result in a more efficient utilization of fuel antiknock properties and more effective engine design and adjustment to meet the requisites of current motor fuels. These tests indicate that the ASTM octane number alone, or even a road octane number as determined by methods heretofore widely used, does not give sufficient information for present needs relative to fuel behavior in service. Neither do test methods previously used provide sufficient information concerning the fuel requirements and knocking characteristics of engines. The new methods of approach which have been developed furnish needed information relative to the fuel and engine relationship that heretofore has been obscure, and indicate paths for future developments.

The cooperative road tests carried out during 1941 have added considerable information and experience to that already existing on the subject of road detonation testing. Extensive data were obtained on the fuel requirements of the 1940 and 1941 models of the three most popular cars. Corresponding data were obtained on the knocking characteristics of current gasolines representing the bulk of the sales volume in various parts of the United States. On account of large variations in octane-number requirement among different cars of the same make - due to differences in ignition timing, combustion-chamber deposit, and other causes - and on account of variations in commercial gasolines, it has been necessary to use statistical methods of analysis in the appraisal of fuel and engine relationships. These methods of analysis have been applied in a number of ways, and have proved very useful.

Background of the Pure Oil performance trials on six classes of automobiles is presented and the evolution of test requirements described. Three tests are run: the economy test to establish how far a vehicle can go over a prescribed course on one gallon of gasoline; the acceleration test which determines acceleration time from 25 to 70 mph in seconds; and the braking test where stopping distance in feet is measured for a stop from 60 mph. Each test is described from the point of view of rules, recording instruments, and penalties for infractions of rules. Test results are presented.

The recent introduction of lower compression ratio engines and the concurrent marketing of unleaded and low-lead content gasolines of generally lower octane number made it appropriate to investigate the interrelationships of engine performance and gasoline octane quality using the “new” engines and fuels. Programs were carried out to compare fuel economy and acceleration performance of eight matched pairs of 1970 and 1971 automobiles. In addition, octane requirements were obtained on 43 1971 cars with 3,000-12,000 deposit miles. A total of 146 unleaded, low-lead, and leaded regular gasolines obtained at service stations throughout the country were analyzed, and the road octane performance of these gasolines was determined using 1970 and 1971 cars designed for regular gasoline.

A gasoline Road Octane study was conducted by the Coordinating Research Council (CRC) to evaluate the effects of heavy aromatics (C9 and heavier) and ethanol content on Road Octane performance independent of Research Octane Number (RON) and Motor Octane Number (MON). Maximum-throttle and part-throttle Road ON’s were found to be well predicted by equations containing only RON and MON terms. Heavier aromatics were found to have a small adverse effect on both maximum-throttle and part-throttle Road ON independent of its direct effects on RON and MON. The all-car data did not show a significant ethanol-content effect, but eight of the thirty-seven cars did show significant effects for ethanol content.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The introduction of more stringent standards for engine emissions requires a steady development of exhaust gas aftertreatment in addition to an optimized cylinder combustion. The reduction of the cold start phase can help significantly to lower cycle emissions. With the goal of optimizing the overall emission performance this study presents a comprehensive simulation approach. A well established 1D gas dynamics and engine simulation model is extended by three key features. These are models for combustion and pollutant production in the cylinder, models for the pollutant conversion in a catalyst, and a general species transport model. This allows to consider an arbitrary number of chemical species and reactions in the entire system.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.

The paper presents a combined experimental and numerical investigation of a small unit displacement two-stroke SI engine operated with gasoline and Natural Gas (CNG). A detailed multi-cycle 3D-CFD analysis of the scavenging process is at first performed in order to accurately characterize the engine behavior in terms of scavenging patterns and efficiency. Detailed CFD analyses are used to accurately model the complex set of physical and chemical processes and to properly estimate the fluid-dynamic behavior of the engine, where boundary conditions are provided by a in-house developed 1D model of the whole engine. It is in fact widely recognized that for two-stroke crankcase scavenged, carbureted engines the scavenging patterns (fuel short-circuiting, residual gas distribution, pointwise lambda field, etc.) plays a fundamental role on both of engine performance and tailpipe emissions.

The paper presents a 1D-3D numerical model to simulate the scavenging and combustion processes in a small-size spark-ignition two-stroke engine. The engine is crankcase scavenged and can be operated with both gasoline and Natural Gas (NG). The analysis is performed with a modified version of the KIVA3V code, coupled to an in-house developed 1D model. A time-step based, two-way coupled procedure is fully described and validated against a reference test. Then, a 1D-3D simulation of the whole two-stroke engine is carried out in different operating conditions, for both gasoline and NG fuelling. Results are compared with experimental data including instantaneous pressure signals in the crankcase, in the cylinder and in the exhaust pipe. The procedure allows to characterize the scavenging process and quantify the fresh mixture short-circuiting, as well as to analyze the development of the NG combustion process for a diluted mixture, typically occurring in a two-stroke engine.

2-Butanone (C4H8O) is a promising alternative fuel candidate as a pure as well as a blend component for substitution in standard gasoline fuels. It can be produced by the dehydrogenation of 2-butanol. To describe 2-butanone's basic combustion behaviour, it is important to investigate key physical properties such as the laminar burning velocity. The laminar burning velocity serves on the one hand side as a parameter to validate detailed chemical kinetic models. On the other hand, especially for engine simulations, various combustion models have been introduced, which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. Hence, well validated models for the prediction of laminar burning velocities are needed. New experimental laminar burning velocity data, acquired in a high pressure spherical combustion vessel, are presented for 1 atm and 5 bar at temperatures of 373 K and 423 K.

Controlled Auto Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), is one of the most promising combustion technologies to reduce the fuel consumption and NOx emissions. Currently, CAI combustion is constrained at part load operation conditions because of misfire at low load and knocking combustion at high load, and the lack of effective means to control the combustion process. Extending its operating range including high load boundary towards full load and low load boundary towards idle in order to allow the CAI engine to meet the demand of whole vehicle driving cycles, has become one of the key issues facing the industrialisation of CAI/HCCI technology. Furthermore, this combustion mode should be compatible with different fuels, and can switch back to conventional spark ignition operation when necessary. In this paper, the CAI operation is demonstrated on a 2-stroke gasoline direct injection (GDI) engine equipped with a poppet valve train.