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Lithium-rich layered oxide, expressed as xLi2MnO3-(1-x) LiMO2 (M = Ni, Co, Mn, etc.), exhibits a high discharge capacity of 200 mAh/g or more and a high discharge voltage at a charge of 4.5 V or more. Some existing reports on cathode materials state that lithium-rich layered oxide is currently the most promising candidate as an active material for high-energy-density lithium-ion cells, but there are few reports on the degradation mechanism. Therefore, this study created a prototype cell using a lithium-rich layered cathode and a graphite anode, and analyzed the degradation mechanism due to charge and discharge. In order to investigate the causes of degradation, changes in the bulk structure and surface structure of the active material were analyzed using high-resolution X-ray diffraction (HRXRD), a transmission electron microscope (TEM), X-ray absorption fine structure (XAFS), and scanning electron microscope/energy dispersive X-ray spectroscopy (SEM-EDX).

Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.

The Integrated Motor Assist (IMA) Hybrid Electric Vehicle (HEV) technology used in Civic Hybrid or Insight is developed originally by Honda, and is mounted in a V6 Accord with the aim of enhancing fuel economy of a mid-size passenger car. The development goal was to realize a mid-size passenger car that provides acceleration performance superior to a V6 Accord and the fuel economy of a compact class vehicle. Various means are employed to achieve high torque and high efficiency simultaneously, including an Interior Permanent Magnet (IPM) type rotor, low-loss electrical steel sheets as the stator material, and high maximum energy product magnets. These technologies increase the maximum power of the newly developed motor by approximately 20%, the maximum torque by 26% and motor efficiency over all ranges by approximately 1% to 3% compared to the current Civic Hybrid motor. Consequently, the maximum motor power of 14 kW and maximum motor torque of 136 Nm are achieved.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.

A flexible-fuel system for small motorcycles has been developed that can utilize both gasoline, and ethanol as an alternative to fossil fuel. For practicality, we aimed to develop a system that uses a minimum of additional parts. As a method to make both ethanol and gasoline available with the system, a control algorithm that estimates the ethanol concentration by utilizing the output voltage of an OXYGEN SENSOR and selects the appropriate injection quantity is employed. Usually, in automotive flexible-fuel vehicles (FFV), sub-tanks are mounted to ensure engine startability in cold temperatures. However, in small motorcycles, limitations of mounting space must be addressed. In this system, by clarifying the control logic and determining the difficult cases for cold temperature starts due to high ethanol concentration, configuring the indicator to promote gasoline mixture when the start is difficult enabled the elimination of the sub-tanks.

The development of Li-ion battery performance in next ten years will encourage improving a power density of Electric Vehicles (EVs). A higher voltage system with a boost voltage converter is favorable for the EV system if the converter has large power in small size. For increasing the converter power density, interleaved topologies using close-coupled inductors are shown to be superior. The inductor set of 3-phase type is proved to be smaller in size and lose less power in comparison to that of 2-phase type for high powered EV system having a 200∼400 volt battery. The prototype 3- phase converter using IGBT with 15 kHz switching frequency achieved a power density of 21.4 kW/liter at 120 kW output on a boost ratio of 1.38 with 98.0% efficiency, which also achieved more than 97% efficiency in a frequent usage zone.

It is important in the application of bio-ethanol in homogeneous-charge compression ignition (HCCI) engines to investigate the HCCI combustion characteristics of ethanol. As the inhibitory mechanism of ethanol on HCCI combustion is a key factor, simulated chemical reactions are necessary. In this study, chemical reaction simulations in the combustion chamber of a rapid compression machine (RCM) were performed in order to investigate the inhibitory mechanism of ethanol on the HCCI combustion of heptane. The sensitivity analysis results suggested that the OH radical consumption reaction by ethanol that occurs would inhibit the cool flame reaction of heptane. Furthermore, visualization of HCCI combustion with the RCM was conducted using a quartz glass combustion chamber head and ICCD camera. As a result, the cool flame luminescence intensity of heptane was reduced by the addition of ethanol.

Compared to conventional hybrid electric vehicles, plug-in hybrid vehicles have a larger-capacity battery and an onboard charger. These devices are mounted in functionally optimal locations, so it is a challenge to provide a thermal management system that achieves a good balance between high cooling performance and low cost. The battery should be operated at required temperature to secure safety and durability at high temperatures, and to mitigate the decrease in output power and capacity. However, setting separate cooling systems suited for each device leads to both an increased cost and weight. Therefore, an integrated water cooling system was devised for the battery, charger, and DC-DC converter, and the cooling performance was verified through simulations and tests. A valve installed before the battery in the cooling circuit allows it to be bypassed when coolant temperature rises due the charger or low-speed engine operation, helping to preserve battery life.

The study of 10% ethanol blended gasoline (E10 gasoline) utilization has been conducted in the Japan Auto-Oil Program (JATOP). In order to clarify the impact of E10 gasoline on vehicle performances, exhaust emissions, evaporative emissions, driveability and material compatibility have been investigated by using domestic gasoline vehicles including mini motor vehicles which are particular to Japan. The test results reveal that E10 gasoline has no impact on exhaust emissions, engine startup time and acceleration period under the hot start condition, but a slight deterioration is observed in some test cases under the cold start condition using E10 gasolines with 50% distillation temperature (T50) level set to the upper limit of Japanese Industrial Standards (JIS) K 2202. Regarding evaporative emissions, the tested vehicles shows no remarkable increase in the hot soak loss (HSL), diurnal breathing loss (DBL) and running loss (RL) testing with E10 gasolines.

Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.

Various plant-derived alternative fuels have been proposed in recent years as ways to curb the global warming that occurs from the CO2 that is emitted by internal combustion engines. One such fuel is bioethanol. In Brazil, flexible fuel vehicles (FFV) are used that can run on blends from 100% hydrous ethanol (E100) to gasoline containing 22% ethanol (E22). This research addresses the optimal specifications of a FFV engine. FFV engines use E100 and E22 in any ratio. E100 has a very high RON of approximately 110, while that of E22 is low at approximately 95. The researchers considered these characteristics when selecting a compression ratio capable of providing good performance at any ethanol blend ratio. Additionally, ethanol is a single-component fuel without low-boiling-point components, so it has poor combustion at low temperatures. In general, FFV engines are often built with one intake valve to enhance product usability at low temperatures.

Recently, the use of ethanol blended fuel is growing worldwide. Therefore, there is increasing needs for addressing issues relating to ethanol blended fuel use in gasoline engine fuel supply systems. In this paper, we focused on one of such issues, which is the reduced life of a multi-layered fuel filter used at inlet side of a fuel pump when it is used with ethanol blended fuel. In this study, we clarified that ethanol blended fuel tends to disperse dust particles contained in fuel to a greater extent than gasoline, and that it has a mechanism to accelerate clogging by concentrating the clogging only on the finest layer of the multi-layered filter. Also, in the process of clarifying this principle, we confirmed that dust particles dispersed by ethanol are coagulated when passing through the filter layers.

The idea to monitor the combustion in an internal combustion engine and using the obtained data to control combustion in the engine has been around for some time now. There are two well-known methods, although in the capacity of lab experiments, which had been developed under this principle. One features the analysis of combustion pressure and the other features the analysis of ionic currents detected in the combustion gas. Although highly precise analysis can be achieved by the former, there are problems in the installation of sensors for detecting combustion pressure, also in the durability and cost of such sensors. As for the latter, there are also problems in installing sensors for detecting the ionic currents and the reliability of obtained data from such sensors is still questionable.

Bio-ethanol is used worldwide in fuel mixtures such as E10 gasoline. In this study, an onboard fuel system employing a pervaporation membrane was investigated to separate E10 into high-octane-number fuel (high-concentration ethanol fuel) and low-octane-number fuel (low-concentration ethanol fuel). The optimal operation conditions and size of the membrane unit for the separation system were determined in consideration of the separation rate and vehicle installation. This system can supply separated ethanol with sufficient speed and quantity to improve engine performance under practical driving conditions. In addition, the study was conducted to confirm that separated fuels have properties sufficient for use in automobiles. This separation rate enabled 5-cycle-mode driving without temporary shortage of permeated fuel.

Bio-ethanol is used in many areas of the world as ethanol blended gasoline at low concentrations such as “E10 gasoline”. In this study, a method was examined to effectively use this small amount of ethanol within ethanol blended gasoline to improve thermal efficiency and high-load performance in a high-compression-ratio engine. Ethanol blended gasoline was separated into high-concentration ethanol fuel and gasoline using a fuel separation system employing a membrane. High-ethanol-concentration fuel was selectively used at high-load conditions to suppress knocking. In this system, a method to decrease ethanol consumption is necessary to cover the wide range of engine operation. Lower ethanol consumption could be achieved by Miller-cycle operation because decrease of the effective compression ratio suppresses knocking. However, high-load operation was limited due to the decrease in intake air volume with Miller-cycle operation.

Bio-ethanol is one of the candidates for automotive alternative fuels. For reduction of carbon dioxide emissions, it is important to investigate its optimum combustion procedure. This study has explored effect of ethanol fuels on HCCI-SI hybrid combustion using dual fuel injection (DFI). Steady and transient characteristics of the HCCI-SI hybrid combustion were evaluated using a single cylinder engine and a four-cylinder engine equipped with two port injectors and a direct injector. The experimental results indicated that DFI has the potential for optimizing ignition timing of HCCI combustion and for suppressing knock in SI combustion under fixed compression ratio. The HCCI-SI hybrid combustion using DFI achieved increasing efficiency compared to conventional SI combustion.