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Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.

Vehicle designers make use of vehicle performance programs such as RAPTOR™ to predict the performance of concept vehicles over ranges of industry standard drive cycles. However, the accuracy of such predictions may be greatly influenced by factors requiring more specialist simulation capabilities. For example, fuel economy prediction will be heavily influenced by the performance of the engine cooling system and its impact on the vehicle's aerodynamic drag, and the load from the air-conditioning system. To improve the predictions, specialist simulation capabilities need to be applied to these aspects, and brought together with the vehicle performance calculations through co-simulation. This paper describes the approach used to enable this cosimulation and the benefits achieved by the vehicle designer.

This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.

Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.

This paper is the fourth in a series describing work sponsored by the Bureau of Mines to reduce diesel particulate and gaseous emissions through fuel modification. A stabilized water microemulsion fuel developed in previous work was tested in a Caterpillar 3304 NA four-cylinder engine with compression ratio and injection timing and rate optimized for this fuel to demonstrate the emissions reductions achieved. It was tested in both standard and optimum configurations with both baseline DF-2 and optimized microemulsion fuels. Gaseous and particulate data are presented from steady-state tests using a computer-operated mini-dilution tunnel and from transient tests using a total exhaust dilution tunnel. The optimized engine-fuel combination was effective in reducing particulates and oxides of nitrogen in steady-state tests. However, the standard engine-fuel combination provided the lowest particulate and NOx emissions in transient tests.

The introduction of the continuously variable transmission (CVT) by General Motors required the introduction of a test to evaluate fluid for the ECOTEC VTi transmission. With assistance from Van Doorne's Transmissie (VDT), the belt and sheave supplier for the transmission, a rig was constructed to test fluids in a transmission-like environment without the variability of in-vehicle testing. The test schedule includes testing for fluid friction coefficient, shear stability, and wear rating and is currently subject to further work aimed at confirming repeatability and discrimination. Once confirmed, the new procedure will become part of the DEX-CVT® specification for the new service fluids for the VT20/25E transmissions.

The ASTM Sequence VE test evaluates lubricant performance for controlling sludge deposits and minimizing overhead camshaft lobe wear. ILSAC asked JAMA to develop a new valve train wear replacement test since the Sequence VE test engine hardware will become obsolete in the year 2000. JAMA submitted the JASO specification M 328-951) KA24E valve train wear test. This first report presents the results of technical studies conducted when JASO M 328-95 was reviewed and the ASTM standardized version of the KA24E test (the Sequence IVA) was proposed. The cam wear mechanism was studied with the goal of improving reproducibility and repeatability. Engine torque was specified to stabilize the NOx concentration in blow-by, which improved test precision. Additionally, the specifications for induction air humidity and temperature, oil temperature control, and test fuel composition were modified when the ASTM version of the KA24E test was proposed.

Emission performance of a late model vehicle equipped with an electrically-heated catalytic converter (EHC) system was evaluated after extended vehicle soak periods that ranged from 30 to 180 minutes. As soak periods lengthened, NMHC and CO emissions measured in hot transient driving cycles increased by 125 percent and 345 percent, respectively. These tests were baseline operations which had no resistance heating or secondary air injection to the converter system. Sources of increased NMHC and CO emissions as a function of vehicle soak time were both the converter system cool-down characteristics and engine restart calibration strategy. For soak periods of 30 and 60 minutes, EHC resistance heating without secondary air injection resulted in large improvements in NMHC and CO emission performance (i.e., 74 percent and 54 percent lower NMHC emissions versus no heat, no air operation after a 30- and 60-minute period, respectively).

A system for injection of diesel fuel and water with real-time control, or real-time water injection (RTWI), was developed and applied to a heavy-duty diesel engine. The RTWI system featured electronic unit pumps that delivered metered volumes of water to electronic unit injectors (EUI) modified to incorporate the water addition passages. The water and diesel mixed in the injector tip such that the initial portion of the injection contained mostly diesel fuel, while the balance of the injection was a water and diesel mixture. With this hardware, real-time cycle-by-cycle control of water mass was used to mitigate soot formation during diesel combustion. Using RTWI alone, NOx emissions were reduced by 42%. Using high-pressure-loop exhaust gas recirculation (EGR) and conventional diesel combustion with RTWI, the NOx was reduced by 82%.

The composition of natural gas delivered through the pipeline varies with time and location around the USA. These variations are known to affect engine performance and emissions through changes in fuel metering characteristics and knock resistance of the fuel. High output, low emissions natural gas engines are being developed that take advantage of the high knock resistance of natural gas. These optimized engines are operated close to knock-limited power where changes in fuel knock resistance can cause operational problems. Octane tests were conducted on natural gas blend fuels using a CFR octane rating engine. Two relationships between motor octane number and fuel composition were established. A correlation for motor octane number versus the reactive hydrogen-carbon ratio was developed, and octane weighting factors, which used the molar composition of the fuel to predict motor octane number, were also found.

The continuing trend toward “cleaner” distillate fuels has prompted concerns about the lubricity characteristics of current and future distillates. Since many U.S. Navy ships utilize seawater-compensated fuel tanks to maintain the ship's trim, the Navy performed a detailed study in order to better understand the relationship between fuel water content and lubricity characteristics. The lubricity test methods, modified for this study, were ASTM D 6078 (SLBOCLE), D 6079 (HFRR), and D 5001 (BOCLE). The results indicated that, with few exceptions, there was generally no evidence of a correlation between the water content of the fuels and the corresponding lubricity measurements as determined by the laboratory tests.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

To characterize exhaust emissions from water-cooled 2-stroke outboard motors (the predominant type), four new motors were tested on dynamometer stands. The engines ranged from 4-65 hp in size, and operating conditions were chosen along lines of simulated boat loading. All the measurements were taken at steady-state conditions. Emission concentrations were measured in raw exhaust gas and after the gases had been bubbled through water in a specially constructed tank. Constituents measured included hydrocarbons, CO, CO2, NO, NOx, O2, light hydrocarbons, and aldehydes. Emissions of sulfur oxides (SOx) were estimated on the basis of fuel consumed, and all the exhaust emissions data were used with available information on population and usage of motors to estimate exhaust emission factors and national exhaust emissions impact.

Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

Increased in-cylinder hydrogen levels have been shown to improve burn durations, combustion stability, HC emissions and knock resistance which can directly translate into enhanced engine efficiency. External fuel reformation can also be used to increase the hydrogen yield. During the High-Efficiency, Dilute Gasoline Engine (HEDGE) consortium at Southwest Research Institute (SwRI), the potential of increased hydrogen production in a dedicated-exhaust gas recirculation (D-EGR) engine was evaluated exploiting the water gas shift (WGS) and steam reformation (SR) reactions. It was found that neither approach could produce sustained hydrogen enrichment in a real exhaust environment, even while utilizing a lean-rich switching regeneration strategy. Platinum group metal (PGM) and Ni WGS catalysts were tested with a focus on hydrogen production and catalyst durability.

The effect of humidity on the lean misfire limit and emissions from a lean burn, natural gas engine is described in this paper, along with a description of a practical humidity compensation method for incorporation into an electronic control system. Experiments to determine the effects of humidity on the lean limit and emissions are described. Humidity increases were shown to decrease the rate of combustion, reduce NOx emissions, and increase the levels of unburned hydrocarbon (HC) and carbon monoxide (CO) emissions. Data and calculations are also presented which demonstrate that increases in humidity will cause enleanment in a typical closed loop control system utilizing a universal exhaust gas oxygen (UEGO) sensor. A prototype system for humidity sensing and subsequent compensation based on these findings was implemented, and the system was found, through additional testing, to compensate for humidity very effectively.

A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.

This paper describes the development of a generic test cell software designed to overcome many vehicle-component testing difficulties by introducing modern, real-time control and simulation capabilities directly to laboratory test environments. Successfully demonstrated in a transmission test cell system, this software eliminated the need for internal combustion engines (ICE) and test-track vehicles. It incorporated the control of an advanced AC induction motor that electrically simulated the ICE and a DC dynamometer that electrically replicated vehicle loads. Engine behaviors controlled by the software included not only the average crankshaft torque production but also engine inertia and firing pulses, particularly during shifts. Vehicle loads included rolling resistance, aerodynamic drag, grade, and more importantly, vehicle inertia corresponding to sport utility, light truck, or passenger cars.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.

Small engines may require soundproofing to eliminate one or more of the following effects: hearing loss, speech interference, community annoyance, detectability, and psychological disorientation. Detectability criteria are frequently associated with military applications and may require the use of a soundproof enclosure in addition to other engine treatments. Acoustical noise sources are conveniently classed as either aerodynamic or mechanical. Aerodynamic sources are predominant on small engines. Treatment of exhaust noise by individual components, e.g., muffler, is inadequate; a system approach, through the use of an electro-acoustic analog computer, has proved to be a much more satisfactory procedure.