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The characterization of a turbulent diesel spray combustion process has been carried out in a divided chamber diesel system with optical accesses. Laser Doppler Anemometry, spectral extinction and flame intensity measurements have been performed from U.V., to visible from the start of injection to the end of combustion, at fixed air/fuel ratio and different engine speeds. Spatial distribution of fuel and vapor as well as the ignition location and soot distribution have been derived in order to study the mechanism of the air-fuel interaction and the combustion process. The analysis of results has shown that the high swirling motion transports the fuel towards the left part of the chamber and breaks up the jet into small droplets of different sizes and accelerates the fuel vaporization. Then, chemical and physical overlapped phases were observed during the ignition delay, contributing both to autoignition.

Conventional methods to measure gas concentrations and, in particular, NO are typically based on sampling by valve, sample treatment and subsequent analysis. These methods suffer low spatial and temporal resolution. The introduction of high energy lasers in combination with fast detection systems allowed to detect the NO distribution inside optically accessible Diesel engines. In this paper, a high spatial and temporal resolution in-situ technique based on ultraviolet - visible absorption spectroscopy is proposed. The characterization of the combustion process by the detection of gaseous compounds from the start of combustion until the exhaust phase was performed. In particular, this technique allows the simultaneous detection of NO and OH absolute concentrations inside an optically accessible Diesel combustion chamber.

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

An experimental evaluation of the impact of the diesel/biodiesel blends is presented in terms of engine performances and pollutant emission analysis. In-cylinder combustion evolution and injection law characterization were carried out on a single cylinder engine, on an optical single cylinder engine and on an injection test rig. Different diesel/biodiesel blends were tested at three operating points, representative of the NEDC cycle. Increasing the biodiesel percentage a reduction mainly in terms of smoke emission was observed. The engine performance as well as the other pollutant emissions were not substantially changed. Therefore this study confirms the benefits of the biodiesel use also on the current automotive engines, reducing simultaneously their environmental impact in terms of GHG and smoke emissions.

Non-intrusive diagnostic techniques based on broadband (190-550 nm) extinction and scattering spectroscopy were applied at undiluted exhaust Common- Rail (CR) diesel engine in real time. The influence of load and Exhaust Gas Recirculation (EGR) on soot mass concentration, size distribution of emitted particles and NO concentration was analyzed. NO concentration was evaluated by ""in-situ"" ultraviolet-visible absorption measurements and compared with those obtained by conventional analyzer. The extinction and scattering spectra were compared with those evaluated by the Lorenz-Mie model for spherical particles in order to retrieve the size, the number concentration of the emitted particles and particulate mass. The optical measurements showed that new generation diesel engines, in spite of a drastic reduction of the exhaust mass concentration, caused the emission in the atmosphere of high number concentration of carbonaceous nanoparticles.

The capabilities of the spectral extinction and scattering technique to follow the time history of the particulate concentration in the exhaust of a Diesel engine were evaluated. Simultaneous measurements of extinction and scattering coefficients from UV to visible were performed at 1.5 m downstream the exhaust valve. The measurements were triggered with the exhaust valve lift. The exhaust stroke was divided in three time windows of 1 ms in which the optical signals of 100 consecutive cycles were detected. The mean diameter, the concentration and the properties of soot particles were evaluated. The cyclic variation of measurements was also estimated.

Aim of this work is to develop a general purpose model for combustion and knocking prediction in SI engines, by coupling a thermo-fluid dynamic model for engine simulation with a general detailed kinetic scheme, including the low-temperature oxidation mechanism, for the prediction of the auto-ignition behavior of hydrocarbons. A quasi-D approach is used to describe the in-cylinder thermodynamic processes, applying the conservation of mass and energy over the cylinder volume, modeled as a single open system. The complex chemistry model has been embedded into the code, by using the same integration algorithm for the conservation equations and the reacting species, and taking into account their mutual interaction in the energy balance. A flame area evolution predictive approach is used to evaluate the turbulent flame front propagation as function of the engine operating parameters.

Two different optical techniques for detection, sizing and counting nanoparticles were applied to undiluted exhaust from 16 v–1900 cc Common Rail diesel engine upstream and downstream a Catalyzed Diesel Particulate Filter (CDPF): Broadband Ultraviolet–Visible Extinction and Scattering Spectroscopy (BUVESS) and Laser Induced Incandescence (LII). They are powerful “in situ” and non-intrusive techniques; they are able to measure mass concentration and size of particles, considering their chemical properties. BUVESS overcomes the intrinsic limitations of single wavelength techniques because it takes advantage of data at several wavelengths to retrieve primary particle size distribution. LII measures mean size of primary particles with a large dynamic range, not limited by aggregate size and by complex retrieving procedure.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

A 0.5 liter optical HCCI engine firing a mixture of n-heptane (50%) and iso-octane (50%) with air/fuel ratio of 3 is studied using large eddy simulation (LES) and laser diagnostics. Formaldehyde and OH LIF and in-cylinder pressure were measured in the experiments to characterize the ignition process. The LES made use of a detailed chemical kinetic mechanism that consists of 233 species and 2019 reactions. The auto-ignition simulation is coupled with LES by the use of a renormalized reaction progress variable. Systematic LES study on the effect of initial temperature inhomogeneity and turbulence intensity has been carried out to delineate their effect on the ignition process. It was shown that the charge under the present experimental condition would not be ignited without initial temperature inhomogeneity. Increasing temperature inhomogeneity leads to earlier ignition whereas increasing turbulence intensity would retard the ignition.

In this work, a boosted single-cylinder spark ignition port-fuel injection optical engine was used for the experimental activity. Firstly, it was equipped with a four-valve head of a commercial turbocharged multi-cylinder engine. Then a prototype engine head with flush installed intake valves was tested. The effect of the different head geometry was evaluated in closed intake valves fuel injection condition. High spatial resolution cycle-resolved digital imaging was used to characterise the flame propagation. Moreover, the presence of diffusion-controlled flames near the valves and on the cylinder walls was investigated. These flames induced the formation of unburned hydrocarbons and soot particles. The spatial distribution and temporal evolution of soot were evaluated by the two colour pyrometry. The prototype configuration showed higher combustion process efficiency than the standard one inducing a little increase in performance and a slight reduction in carbon oxides emissions.

The present paper reports the results of an experimental investigation carried out on a four-stroke single- cylinder D.I. diesel engine (100 x 95mm bore x stroke) with the aim to evaluate the effects of a four-lobe square combustion chamber on the gaseous and particulate emissions. Fluid-dynamic behaviour of the axisymmetric toroidal and four-lobe square chambers was investigated by Laser Doppler Anemometry. Engine tests at 2000 and 3000 rpm for different start of combustion (SOC) and A/F ratio are reported. Particulate, HC and NOx emission index measured under different operating conditions are given. In addition, the volatile content of the particulates produced from the two chambers at various engine operative conditions was measured by thermogravimetric analysis (TGA). Finally, the catalytic activity of a metal-oxide-based catalyst in the combustion of particulate was also evaluated by TGA.

The growing demands on fuel economy and always stricter limitations on pollutant emissions has increased the interest in the ignition phenomena to guarantee successful flame development for all the spark ignition (SI) engine operating conditions. The initial size and the growth of the flame have a strong influence on the further development of the combustion process. In particular, for the new FIAT generation of turbocharged SI engines, the first times of spark ignition combustion are not yet fully understood. This is mainly due to the missing knowledge concerning the detailed physical and chemical processes taking place during the all set of the flame propagation. These processes often occur simultaneously, making difficult the interpretation of measurements. In the present paper, flame dynamic was followed by UV-visible emission imaging in an optical SI engine.

The influence of fuel composition on mixture formation and first stage of combustion, occurring in a small high swirl combustion chamber of an IDI Diesel engine, was analyzed from measurements of spectral extinction and flame emissivity. Measurements were carried out in an optically accessible combustion chamber in which an air swirling flow is forced from the main chamber through a tangential passage. A conventional injection system was used to inject Tetradecane, N-heptane and Diesel fuel. The distribution of liquid and vapor and the interaction of the jet with air swirl were detected by UV-visible extinction measurements. The autoignition phase was characterized by UV-visible chemiluminescence measurements. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with time until reaching a maximum characteristic length, slightly dependent on the fuel.

Hydrogen has been proposed as a possible fuel for automotive applications. This paper reports an experimental investigation of hydrogen as HCCI engine fuel. The aim of the experimental study is to investigate the possibility to run an HCCI engine on an extremely fast burning fuel such as hydrogen as well as to study the efficiency, the combustion phasing and the formation of emissions. The experiments were conducted on a single-cylinder research engine with a displacement volume of 1.6 litres and pancake combustion chamber geometry. Variation of lambda, engine speed, compression ratio and intake temperature were parts of the experimental setting. The engine was operated in Homogenous Charge Compression Ignition (HCCI) mode and as comparison also in Spark Ignition (SI) mode. Hydrogen was found to be a possible fuel for an HCCI engine. The heat release rate was extremely high and the interval of possible start of combustion crank angles was found to be narrow.

The optimization of diesel engine performance and emissions can be achieved through a better understanding of the in-cylinder combustion process. Advanced non-intrusive optical techniques are providing new tools for investigating the thermo-fluid dynamics processes as well as they are contributing to develop predictive models for DI diesel combustion. High-speed images of spray and flame evolution as well as UV-visible chemiluminescence measurements were carried out in an optical 0.5-liter, single-cylinder, four-stroke, direct- injection diesel engine equipped with a prototype four valves cylinder head and a fully flexible CR injection system. In order to evaluate the effect of different injection strategies on the combustion process, measurements were performed varying injection parameters. The ignition location and time were individuated by combustion visualization and detection of radical species, obtained by chemiluminescence measurements.

Proton Exchange Membrane (PEM) Fuel Cell (FC) presents itself as a promising technology in view of zero-tailpipe emission vehicles. In addition, the constant development of renewable energy sources will lead to an increase in green hydrogen availability, and thus completely eliminate emissions for devices that use H2 as an energy vector. However, PEM FCs are still far from being fully developed as a technology: thermal and water management are the main issues that researchers are studying through experiments and Computational Fluid Dynamics (CFD) simulations. For the numerical approach, H2O removal models often consider a simplified flat surface, but the microgeometry of the Gas Diffusion Layer (GDL) has a leading role in determining the critical dimension for droplet detachment and how much resistance the surface poses to water sliding. The aim of this paper is to investigate the influence of droplets number on a GDL.

For the simultaneous evaluation of the influence on engine knock of both chemical conditions and global operating parameters, a combined tool was developed. Thus, a two-zone kinetic model for SI engine combustion calculation (Ignition) was implemented into an engine cycle simulation commercial code. The combined model predictions are compared with experimental data from a single-cylinder test engine. This shows that the model can accurately predict the knock onset and in-cylinder pressure and temperature for different lambda conditions, with and without EGR. The influence of nitric oxide amount from residual gas in relation with knock is further investigated. The created numerical tool represents a useful support for experimental measurements, reducing the number of tests required to assess the proper engine control strategies.

Quantitative measurements of the soot volume fraction and diameter performed by spectroscopic techniques within the combustion chamber of a diesel engine are employed to aid multidimensional simulation of the soot formation and oxidation processes. By changing the start of fuel injection, two different operating conditions are considered, which are characterized by different relative importance of the premixed to the diffusive stage of the combustion process. Both the reduced models by Hiroyasu et al., and the one by Nagle and Strikland- Constable are employed within the numerical simulation. The reason of the peculiar over-prediction of soot concentration of the latter model is discussed and related to the need of furnishing coherent values of the soot particle density and mean diameter.

Multidimensional simulation of the soot formation process in a diesel engine is realised exploiting quantitative measurements of the soot volume fraction and diameter obtained by optical techniques. Broadband extinction and scattering measurements are performed on an optically accessible 4-stroke engine where a forced air motion allows a strong prevalence of the premixed stage of combustion with respect to the non-premixed one. Two semi-empirical models for soot formation are tested in the numerical simulation, which is performed using a customized version of the KIVA-3 code. The need of furnishing coherent values of the soot particles density and mean diameter to the one of the two models requiring this kind of information, is highlighted and demonstrated to be crucial in avoiding over-prediction of the soot concentration.