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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

A direct injection system in which fuel was injected through the cylinder wall was developed and detailed investigation was made for the purpose of reducing short-circuit of fuel in 2-stroke engines. As a result of dynamo tests using 430cc single cylinder engine, it was found that the injector was best attached at a location as close to TDC as possible on the rear transfer port side, and that the entire amount of fuel should be injected towards the piston top surface. Emissions were worsened if fuel was injected towards the exhaust port or spark plug. Although the higher injection pressure resulted in large emissions reduction effects, it did not have a significant effect on fuel consumption. When a butterfly exhaust valve, known to be effective against irregular combustion in the light load range, was applied, it was found to lead to further reductions in HC emission and fuel consumption while also improving combustion stability.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

Fuel efficiency and torque performance are two major challenges for highly downsized turbocharged engines. However, the inherent characteristics of the turbocharged SI engine such as negative PMEP, knock sensitivity and poor transient performance significantly limit its maximum potential. Conventional ways of improving the problems above normally concentrate solely on the engine side or turbocharger side leaving the exhaust manifold in between ignored. This paper investigates this neglected area by highlighting a novel means of gas exchange process. Divided Exhaust Period (DEP) is an alternative way of accomplishing the gas exchange process in turbocharged engines. The DEP concept engine features two exhaust valves but with separated function. The blow-down valve acts like a traditional turbocharged exhaust valve to evacuate the first portion of the exhaust gas to the turbine.

1 An all fiber-optic sensor has been developed to measure H2O mole fraction and gas temperature in an HCCI engine. This absorption-spectroscopy-based sensor utilizes a broad wavelength (1320 to 1380 nm) source (supercontinua generated by a microchip laser) and a series of fiber Bragg gratings (19 gratings centered on unique water absorption peaks) to track the formation and temperature of combustion water vapor. The spectral coverage of the system promises improved measurement accuracy over two-line diode-laser based systems. Meanwhile, the simplicity of the fiber Bragg grating chromatic dispersion approach significantly reduces the data reduction time and cost relative to previous supercontinuum-based sensors. The data provided by the system is expected to enhance studies of the chemical kinetics which govern HCCI ignition as well as HCCI modeling efforts.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.