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A homogeneous charge compression ignition (HCCI) engine has been run at different operating conditions with fuels of different RON and MON and different chemistries. The ignition quality of the fuel at a given operating condition is characterized by CA50, the crank angle at which the cumulative heat released reaches 50% of the maximum value for the cycle. It is found that CA50 might show no correlation with either RON or MON but correlates very well with the Octane Index, OI defined as OI = (1-K)RON + KMON = RON - KS, where K is a constant depending on the engine operating condition and S is the fuel sensitivity, (RON - MON). The higher the OI, the more the resistance to autoignition and the later is the heat release in the HCCI engine at a given condition.

The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

Predictive simulation models are needed in order to exploit the full benefits of 1-D engine simulation. Simulation model alterations such as cam phasing affect the gas composition and gas state in the cylinders and have an effect on the combustion. Modelling of these effects is particularly important when the engine is knock limited. A knock model, able to phase the combustion towards the knock limit, was previously developed by the authors. A major challenge in such knock models is to predict the pressure and temperature evolution in the end-gas accurately through an adequate combustion model. The Wiebe function is often used to model the combustion in SI engine simulations, owing to its ease of use and computational efficiency. The Wiebe function simply imposes a curve shape for the fuel burn rate and the parameters are easily determined from calculated heat release.

In Homogeneous Charge Compression Ignition (HCCI) engines heat release occurs by auto-ignition and hence the fuel auto-ignition quality is very important. The auto-ignition quality of Diesel fuels is conventionally described by the cetane number. Conventional Diesel fuels are involatile compared to gasoline fuels and mixture preparation becomes far more critical in assessing their behaviour in HCCI engines. This paper considers the relationship between auto-ignition behaviour of Diesel-like fuels in a single-cylinder HCCI engine and the fuel cetane number under different mixture preparation strategies. Three different fuel injection strategies were used in this study, port fuel injection (PFI), early direct-injection with colliding sprays and late direct-injected in the presence of EGR, akin to the Nissan MK concept. The fuels used were conventional Diesel fuels and model fuels with similar auto-ignition qualities.

A single cylinder Direct Injection Spark Ignition (DISI) engine with optical access has been used for combustion studies with both early injection and late injection for stratified charge operation. Cylinder pressure records have been used for combustion analysis that has been synchronised with the imaging. A high speed cine camera has been used for imaging combustion within a cycle, while a CCD camera has been used for imaging at fixed crank angles, so as to obtain information on cycle-by-cycle variations. The CCD images have also been analysed to give information on the quantity of soot present during combustion. Tests have been conducted with a reference unleaded gasoline (ULG), and pure fuel components: iso-octane (a representative alkane), and toluene (a representative aromatic). The results show diffusion-controlled combustion occurring in so-called homogeneous combustion with early injection.

In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).

GTL (Gas-To-Liquid) fuel is well known to improve tailpipe emissions when fuelling a conventional diesel vehicle, that is, one optimized to conventional fuel. This investigation assesses the additional potential for GTL fuel in a GTL-dedicated vehicle. This potential for GTL fuel was quantified in an EU 4 6-cylinder serial production engine. In the first stage, a comparison of engine performance was made of GTL fuel against conventional diesel, using identical engine calibrations. Next, adaptations enabled the full potential of GTL fuel within a dedicated calibration to be assessed. For this stage, two optimization goals were investigated: - Minimization of NOx emissions and - Minimization of fuel consumption. For each optimization the boundary condition was that emissions should be within the EU5 level. An additional constraint on the latter strategy required noise levels to remain within the baseline reference.

The growing availability of different biofuels and synthetic fuels is leading to increased diversity of automotive fuels. Understanding how fuel properties affect combustion and how engine calibration strategies can compensate for variations in fuel composition is crucial for ensuring proper engine operation in this world of increased fuel diversity. This study looks at the ability to compensate for wide changes in cetane quality. Four different fuels with variations in cetane number, volatility and composition have been tested in a single cylinder engine and compared to diesel fuel. The selected operating conditions represent the entire engine map of a passenger car diesel engine. In part load the effects were investigated for conventional and premixed Diesel combustion. The results show that part load operation is especially relevant for the detection and compensation of varying fuel properties and that, depending on engine load, different control strategies have to be applied.

More stringent emissions standards along with higher fuel economy demands have obliged auto makers to develop technical solutions that exploit synergistic features from gasoline and diesel engines. To minimize NOx and soot trade-off, diesel powertrain has been developed to adopt increasingly complex and expensive technology such as extremely high pressure fuel injection systems, low pressure EGR, and variable valve timing. These attempts are associated with promoting Partially Premixed Charge Compression Ignition (PPC-CI) combustion via increasing mixing time and ignition delay. Alternatively, PPC-CI combustion can be achieved easier by using fuels with higher resistance to auto-ignition than conventional diesel fuel. Previous work has demonstrated the possibility of reducing the cost of future diesel after-treatment systems by using gasoline-like fuels.

Recent research [21] has shown that the compression ignition concept where very low cetane fuels (RON between 70 and 85) are run in compression ignition (CI) mode has several advantages. The engine will be at least as efficient and clean as the current diesel engines but will have a less complicated after-treatment system. The optimum fuel will be less processed and therefore simpler to make compared to current gasoline or diesel fuels. Naphtha, which is a product of the initial distillation of petroleum, is one such fuel. It provides a path to mitigate the global demand imbalance between heavier and lighter fuels that is otherwise projected. Since naphtha requires much less processing in the refinery than either gasoline or diesel [23], there is an additional benefit in terms of well-to-wheel CO2 emissions and overall energy consumed. Partially premixed charge compression ignition combustion with such a low cetane fuel has usually been investigated with a diesel engine base.

Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.

Previous work has showed that it may be advantageous to use fuels of lower cetane numbers compared to today's diesel fuels in compression ignition engines. The benefits come from the longer ignition delays that these fuels have. There is more time available for the fuel and air to mix before combustion starts which is favourable for achieving low emissions of NOx and smoke though premixing usually leads to higher emissions of CO and unburned hydrocarbons. In the present work, operation of a single-cylinder light-duty compression ignition engine on four different fuels of different octane numbers, in the gasoline boiling range, is compared to running on a diesel fuel. The gasoline fuels have research octane numbers (RON) of 91, 84, 78, and 72. These are compared at a low load/low speed condition (4 bar IMEP / 1200 rpm) in SOI sweeps as well as at a higher load and speeds (10 bar IMEP / 2000 and 3000 rpm) in EGR sweeps.

Conventional fossil fuels will constitute the majority of automotive fuels for the foreseeable future but will have to adapt to changes in engine technology. Unconventional transport fuels such as biofuels, gas-to-liquid fuels, compressed natural gas, and liquid petroleum gas will also play a role. Hydrogen might be a viable transport fuel if it overcomes barriers in production, transport, storage, and safety and/or if fuel cells become viable. This book opens by considering these issues and then introduces practical transport fuels. A chapter on engine deposits follows, which is an important practical topic about how fuels affect engines that is not usually considered in other books. The next three chapters discuss auto-ignition phenomena in engines. The auto-ignition resistance of fuels is the most important fuel property since it limits the efficiency of spark ignition engines and determines the performance of compression ignition engines.

This paper is the second of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This second study focuses on drive cycle simulations and Life Cycle Assessment (LCA) for vehicles equipped with Octane-on-Demand combustion. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. The experimental engine calibration maps developed in the previous study are first provided as inputs to a drive cycle simulation tool. This is used to quantify the total fuel consumption, octane requirement and tank-to-wheel CO2 emissions for a light-duty vehicle equipped with two alternative powertrain configurations. The properties of the lower octane fuel are shown to affect the vehicle fuel consumption and CO2 emissions significantly.

This paper is the first of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This first study focuses on the application of so-called Octane-on-Demand combustion, whereby the fuel anti-knock quality is customized to match the real-time requirements of an otherwise conventional spark-ignition engine. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. Experimental engine calibration maps are first developed to quantify the minimum amount of methanol that must be added to each lower octane fuel in order to reproduce the baseline engine performance attained on a market gasoline (RON 95). The properties of the lower octane fuel are shown to affect the engine performance significantly.

Conventional diesel-fuelled Partially Premixed Compression Ignition (PPCI) engines have been investigated by many researchers previously. However, the ease of ignition and difficulty of vaporization of diesel fuel make it imperfect for PPCI combustion. In this study, dieseline (blending of diesel and gasoline) was looked into as the Partially Premixed Compression Ignition fuel for its combination of two fuel properties, ignition-delay-increasing characteristics and higher volatility, which make it more suitable for PPCI combustion compared to neat diesel. A series of tests were carried out on a Euro IV light-duty common-rail diesel engine, and different engine modes, from low speed/load to middle speed/load were all tested, under which fuel blend ratios, EGR rates, injection timings and quantities were varied. The emissions, fuel consumption and combustion stability of this dieseline-fuelled PPCI combustion were all investigated.

An earlier paper has shown the ability to predict the phasing of knock onset in a gasoline PFI engine using a simple ignition delay equation for an appropriate surrogate fuel made up of toluene and PRF (TPRF). The applicability of this approach is confirmed in this paper in a different engine using five different fuels of differing RON, sensitivity, and composition - including ethanol blends. An Arrhenius type equation with a pressure correction for ignition delay can be found from interpolation of previously published data for any gasoline if its RON and sensitivity are known. Then, if the pressure and temperature in the unburned gas can be estimated or measured, the Livengood-Wu integral can be estimated as a function of crank angle to predict the occurrence of knock. Experiments in a single cylinder DISI engine over a wide operating range confirm that this simple approach can predict knock very accurately.

Most studies on knock ignore the stochastic nature of knock and focus on the onset of knock which is determined by chemical kinetics. This paper focuses on knock intensity (KI) which is determined by the evolution of the pressure wave following knock onset in a hot spot and highlights the stochastic processes involved. KI is defined in this study as the maximum peak-to-peak pressure fluctuation that follows the onset of knock. It depends on ξ = (a/ua) where ua is the speed of the autoignition front and a is the speed of sound. When ua is small, KI can be related to the product of a parameter Z, which depends on Pko, the pressure at knock onset and the square of (∂x/∂T), which is the inverse of the gradient of temperature with distance in the hot spot. Both Z and (∂x/∂T) were calculated using measured KI and Pko for hundreds of individual knocking cycles for different fuels.

The objective of this paper is to present a simulation model for controlling combustion phasing in order to avoid knock in turbocharged SI engines. An empirically based knock model was integrated in a one-dimensional simulation tool. The empirical knock model was optimized and validated against engine tests for a variety of speeds and λ. This model can be used to optimize control strategies as well as design of new engine concepts. The model is able to predict knock onset with an accuracy of a few crank angle degrees. The phasing of the combustion provides information about optimal engine operating conditions.