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A reduced kinetic reaction mechanism for the autoignition of dimethyl ether is presented in this paper. Dimethyl ether has proven to be one of the most attractive alternatives to traditional fossil fuels for compression ignition engines. It can either be produced from biomass or from fossil oil. For dimethyl ether, Fischer et al. (Int. J.Chem. Kinet. 32 ( 12 ) (2000) 713-740) proposed a detailed reaction mechanism consisting of 79 species and 351 elementary reactions. In the present work, this detailed mechanism is systematically reduced to 31 species and 49 reactions. The reduced mechanism is discussed in detail with special emphasis on the high temperature thermal decomposition of dimethyl ether and on the fuel specific depleting reactions, which produce the methoxymethyl radical. In addition, a reaction pathway analysis for low temperature combustion is applied, where hydroperoxy-methylformate is found to be the dominating parameter for the low temperature regime.

The technology used in hybrid vehicle concepts is significantly different from conventional vehicle technology with consequences also for the noise and vibration behavior. In conventional vehicles, certain noise phenomena are masked by the engine noise. In situations where the combustion engine is turned off in hybrid vehicle concepts, these noise components can become dominant and annoying. In hybrid concepts, the driving condition is often decoupled from the operation state of the combustion engine, which leads to unusual and unexpected acoustical behavior. New acoustic phenomena such as magnetic noise due to recuperation occur, caused by new components and driving conditions. The analysis of this recuperation noise by means of interior noise simulation shows, that it is not only induced by the powertrain radiation but also by the noise path via the powertrain mounts. The additional degrees of freedom of the hybrid drive train can also be used to improve the vibrational behavior.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.

Engine processes are subject to cyclic fluctuations, which a have direct effect on the operating and emission behavior of the engine. The fluctuations in direct injection gasoline engines are induced and superimposed by the flow and the injection. In stratified operation they can cause serious operating problems, such as misfiring. The current state of knowledge on the formation and causes of cyclic fluctuations is rather limited, which can be attributed to the complex nature of flow instabilities. The current investigation analyzes the cyclic fluctuations of the in-cylinder charge motion and the mixture formation in a direct injection gasoline engine using laser-optical diagnostics and numerical 3D-calculation. Optical measurement techniques and pressure indication are used to measure flow, mixture formation, and combustion processes of the individual cycles.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

For gasoline engines controlled autoignition provides the vision of enabling the fuel consumption benefit of stratified lean combustion systems without the drawback of additional NOx aftertreatment. In this study the potential of certain biofuels on this combustion system was assessed by single-cylinder engine investigations using the exhaust strategy "combustion chamber recirculation" (CCR). For the engine testing sweeps in the internal EGR rate with different injection strategies as well as load sweeps were performed. Of particular interest was to reveal fuel differences in the achievable maximal load as well as in the NOx emission behavior. Additionally, experiments with a shock tube and a rapid compression machine were conducted in order to determine the ignition delay times of the tested biofuels concerning controlled autoignition-relevant conditions.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

Due to experimental challenges, combustion of diesel-like jets has rarely been characterized by laser-based quantitative multiscalar measurements. In this work, recently developed laser diagnostics for combustion temperature and the concentrations of CO, O2, and NO are applied to a diesel-like jet, using a highly oxygenated fuel. The diagnostic is based on spontaneous Raman scattering (SRS) and laser-induced fluorescence (LIF) methods. Line imaging yields multiscalar profiles across the jet cross section. Measurements turn out to be particularly accurate, because near-stoichiometric combustion occurs in the central region of the jet. Thereby, experimental cross-influences by light attenuation and interfering emissions are greatly reduced compared to the combustion of conventional, sooting diesel fuel jets. This is achieved by fuel oxygenation and enhanced premixing.

Within a public founded project test cell investigations were undertaken to identify parameters which predominantly influence the development of critical deposits in injection nozzles. A medium-duty diesel engine was operated in two different coking cycles with a zinc-free lubricant. One of the cycles is dominated by rated power, while the second includes a wide area of the operation range. During the experiments the temperatures at the nozzle tip, the geometries of the nozzle orifice and fuel properties were varied. For a detailed analysis of the deposits methods of electron microscopy were deployed. In the course of the project optical access to all areas in the nozzle was achieved. The experiments were evaluated by means of the monitoring of power output and fuel flow at rated power. The usage of a SEM (scanning electron microscope) and a TEM (transmission electron microscope) revealed images of the deposits with a magnification of up to 160 000.

Dielectric barrier discharge (DBD) offers the advantage to excite and dissociate molecules in the exhaust gas stream. Those dissociated and excited species are oxidizing or reducing harmful exhaust gas components. The advantage of a plasma chemical system in comparison to a catalytic measure for exhaust gas treatment is the instantaneous activity at ambient temperature from the starting of the engine. The investigations reviewed in this paper are dealing with the plasma chemical oxidation of hydrocarbons in the exhaust gas stream during cold start conditions. The article concerns the design and development of a plasma-system in order to decrease the hydrocarbon emissions from engine start till catalyst light off. Vehicle results in the New European Driving Cycle show a hydrocarbon conversion of more than 42% in the first 11 seconds from engine start. In this period nearly all types of hydrocarbon were reduced.

In order to reduce engine out CO2 emissions, it is a main subject to find new alternative fuels from renewable sources. For identifying the specification of an optimized fuel for engine combustion, it is essential to understand the details of combustion and pollutant formation. For obtaining a better understanding of the flame behavior, dynamic structure large eddy simulations are a method of choice. In the investigation presented in this paper, an n-heptane spray flame is simulated under engine relevant conditions starting at a pressure of 50 bar and a temperature of 800 K. Measurements are conducted at a high-pressure vessel with the same conditions. Liquid penetration length is measured with Mie-Scatterlight, gaseous penetration length with Shadowgraphy and lift-off length as well as ignition delay with OH*-Radiation. In addition to these global high-speed measurement techniques, detailed spectroscopic laser measurements are conducted at the n-heptane flame.

One of the challenges faced when using Li-ion batteries in electric vehicles is to keep the cell temperatures below a given threshold. Mathematical modeling would indeed be an efficient tool to test virtually this requirement and accelerate the battery product lifecycle. Moreover, temperature predicting models could potentially be used on-board to decrease the limitations associated with sensor based temperature feedbacks. Accordingly, we present a complete modeling procedure which was used to calculate the cell temperatures during a given electric vehicle trip. The procedure includes a simple vehicle dynamics model, an equivalent circuit battery model, and a 3D finite element thermal model. Model parameters were identified from measurements taken during constant current and pulse current discharge tests. The cell temperatures corresponding to an actual electric vehicle trip were calculated and compared with measured values.

The presented paper deals with the set-up and performance of a newly developed control system as well as with achieved engine results. This control system is able to control the entire cylinder pressure trace by using a flexible rate shaping injector and iterative learning control (ILC). Standard thermodynamic cycles, like isobaric and Seiliger cycles, and a newly suggested class of cycles are generated and analyzed on a single cylinder engine. With this control system an extremely flexible tool for optimization of combustion processes is available to exploit the full potential of injection rate- shaping on diesel engines.

In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this paper, several fuels were selected which can be produced out of biomass or with hydrogen which is generated directly via electrolysis with electricity from renewable sources. All fuels are compared to conventional diesel fuel and two diesel surrogates. It is well known that there can be a large effect of fuel properties on mixture formation and combustion, which may result in a completely different engine performance compared to the operation with conventional diesel fuels. Mixture formation and ignition behavior can also largely affect the pollutant formation. The knowledge of the combustion behavior is also important to design new engine geometries or implement new calibrations for an existing engine. The fuel properties of the investigated fuels comprise a large range, for example in case of the derived cetane number, from below 30 up to 100.

The efficient operation of powertrain test benches in research and development is strongly influenced by the state of “health” of the functional test object. Hence, the use of Early Damage Detection Systems (EDDS) with Unit Under Test (UUT) monitoring is becoming increasingly popular. An EDDS should primarily avoid total loss of the test object and ensure that damaged parts are not completely destroyed, and can still be inspected. Therefore, any abnormality from the standard test object behavior, such as an exceeding of predefined limits, must be recognized at an early testing time, and must lead to a shutdown of the test bench operation. With sensors mounted on the test object, it is possible to isolate the damage cause in the event of its detection. Advanced EDDS configurations also optimize the predefined limits by learning new shutdown values according to the test object behavior within a very short time.

Modeling thermal systems in Battery Electric Vehicles (BEVs) is crucial for enhancing energy efficiency through predictive control strategies, thereby extending vehicle range. A major obstacle in this modeling is the often limited availability of detailed system information. This research introduces a methodology using neural networks for system identification, a powerful technique capable of approximating the physical behavior of thermal systems with minimal data requirements. By employing black-box models, this approach supports the creation of optimization-based operational strategies, such as Model Predictive Control (MPC) and Reinforcement Learning-based Control (RL). The system identification process is executed using MATLAB Simulink, with virtual training data produced by validated Simulink models to establish the method's feasibility. The neural networks utilized for system identification are implemented in MATLAB code.

An improved plasma reactor has been designed, built and evaluated. It is characterized by a reduced power per area ratio, relative to previous designs, and includes several improvements to run the whole system safely in a car. The new reactor design includes a concentric inner high voltage electrode, a grounded outer electrode, a shielded high-voltage and high temperature resistant electrical connection. A generator controller has been developed for better control of operating conditions as required during the engine cold start phase. The new generator/reactor system was installed in the exhaust pipe of a gasoline direct injection engine. HC emissions could be reduced up to 30 % in the first 40 seconds of a cold start test. In addition to HC treatment the dielectric barrier discharge has also been investigated as a method for regenerating a diesel particulate trap.

Cyclic fluctuations of the in-cylinder processes in a Direct Injection Spark Ignition (DISI) engine may strongly affect the engine operation causing misfires or variations in the indicated mean effective pressure (imep). Particularly misfires prevent compliance with current or future exhaust emission legislations. Nevertheless, the origin of cyclic fluctuations is not well understood since fluctuations of in-cylinder air flow, fuel injection and wall interaction have to be considered. This paper focusses on a detailed experimental analysis of the origin of cyclic fluctuations in a DISI engine with an air guided combustion process by means of advanced Laser Induced Exciplex Fluorescence (LIEF) measurements. It reveals that cycle-to-cycle variations primarily originate from the air/fuel ratio at the spark plug.

Hybrid and electric vehicles present a promising trade-off between the necessary reductions in emissions and fuel consumption, the improvement in driving pleasure and performance of today's and tomorrow's vehicles. These hybrid vehicles rely primarily on electronics for the control and the coordination of the different sub-systems or components. The number and complexity of the functions distributed over many control units is increasing in these vehicles. Functional safety, defined as absence of unacceptable risk due to the hazards caused by mal-function in the electric or electronic systems is becoming a key factor in the development of modern vehicles such as electric and hybrid vehicles. This important increase in functional safety-related issues has raised the need for the automotive industry to develop its own functional safety standard, ISO 26262.

The requirement of reducing worldwide CO₂ emissions and engine pollutants are demanding an increased use of bio-fuels. Ethanol with its established production technology can contribute to this goal. However, due to its resistive auto-ignition behavior the use of ethanol-based fuels is limited to the spark-ignited gasoline combustion process. For application to the compression-ignited diesel combustion process advanced ignition systems are required. In general, ethanol offers a significant potential to improve the soot emission behavior of the diesel engine due to its oxygen content and its enhanced evaporation behavior. In this contribution the ignition behavior of ethanol and mixtures with high ethanol content is investigated in combination with advanced ignition systems with ceramic glow-plugs under diesel engine relevant thermodynamic conditions in a high pressure and temperature vessel.