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Technical Paper

The DOE/NREL Environmental Science Program

2001-05-14
2001-01-2069
This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.
Technical Paper

Chemical Speciation of Exhaust Emissions from Trucks and Buses Fueled on Ultra-Low Sulfur Diesel and CNG

2002-03-04
2002-01-0432
A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Performance of a High Speed Engine with Dual Fuel Capability

1994-03-01
940517
Concern over dwindling oil supplies has led to the adoption of alternate fuels to power fleet vehicles. However, during the interim period when alternate fuel supply stations are few and far between, dual fuel engines prove a necessity. In the light duty arena, these engines are typically gasoline engines modified to accommodate compressed natural gas (CNG) as an alternate fuel, but they are seldom optimized with both fuels in mind. A Saturn 1.9 liter 4 cylinder dual overhead cam engine was selected as a base for developing an optimized gasoline/CNG powerplant. Baseline data on power and steady state emissions (CO2, CO, NOx, HC) were found using the standard Saturn controller. In addition to monitoring standard sensor measurements, real-time pressure traces were taken for up to 256 cycles using a modified head with embedded PCB piezoelectric pressure transducers.
Technical Paper

Turbocharging a Bi-Fuel Engine for Performance Equivalent to Gasoline

1994-10-01
942003
A bi-fuel engine capable of operating either on compressed natural gas (CNG) or gasoline is being developed for the transition to alternative fuel usage. A Saturn 1.9 liter 4-cylinder engine was selected as a base powerplant. A control system that allows closed-loop optimization of both fuel delivery and spark timing was developed. Stock performance and emissions of the engine, as well as performance and emissions with the new controller on gasoline and CNG, have been documented. CNG operation in an engine designed for gasoline results in power loss because of the lower volumetric efficiency with gaseous fuel use, yet such an engine does not take advantage of the higher knock resistance of CNG. It is the goal of this research to use the knock resistance of CNG to recover the associated power loss. The two methods considered for this include turbocharging with a variable boost wastegate and raising the compression ratio while employing variable valve timing.
Technical Paper

A Controller for a Spark Ignition Engine with Bi-Fuel Capability

1994-10-01
942004
A bi-fuel engine with the ability to run optimally on both compressed natural gas (CNG) and gasoline is being developed. Such bi-fuel automotive engines are necessary to bridge the gap between gasoline and natural gas as an alternative fuel while natural gas fueling stations are not yet common enough to make a dedicated natural gas vehicle practical. As an example of modern progressive engine design, a Saturn 1.9 liter 4-cylinder dual overhead cam (DOHC) engine has been selected as a base powerplant for this development. Many previous natural gas conversions have made compromises in engine control strategies, including mapped open-loop methods, or resorting to translating the signals to or from the original controller. The engine control system described here, however, employs adaptive closed-loop control, optimizing fuel delivery and spark timing for both fuels.
Technical Paper

Exhaust Emissions and Combustion Stability in a Bi-Fuel Spark Ignition Engine

1995-02-01
950468
A Saturn 1.9 liter engine has been converted for operation on either compressed natural gas or gasoline. A bi-fuel controller (BFC) that uses closed-loop control methods for both fuel delivery and spark advance has been developed. The performance and emissions during operation on each fuel have been investigated with the BFC, as well as the performance and emissions with the stock original equipment manufacturer (OEM) controller using gasoline. In-cylinder pressure was measured at a rate of 1024 points per revolution with piezoelectric pressure transducers flush-mounted in the cylinder head. The in-cylinder pressure was used in real time for ignition timing control purposes, and was stored by a data acquisition system for the investigation of engine stability and differences in the combustion properties of the fuels.
Technical Paper

The Design of a Bi-Fuel Engine Which Avoids the Penalties Associated with Natural Gas Operation

1995-02-01
950679
An alternative fuel that has demonstrated considerable potential in reducing emissions and crude oil dependence is compressed natural gas (CNG). A dedicated CNG vehicle suffers from the lack of an adequate number of fueling stations and the poor range limited by CNG storage technology. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. Although many such bi-fuel vehicles are in existence, historically they have employed older engine designs and made compromises in engine control parameters that can degrade performance relative to gasoline and increase emissions. A modern production engine, a 1992 Saturn 1.9 liter 16 valve powerplant, is being optimized for operation on each fuel to realize the full potential of CNG in a bi-fuel system. CNG operation in an engine designed for gasoline typically suffers from reduced power, due in part to displacement of air by gaseous fuel.
Technical Paper

Effect of Fuel Composition on the Operation of a Lean Burn Natural Gas Engine

1995-10-01
952560
With the implementation of a closed loop fuel control system, operation of lean-burn natural gas engines can be optimized in terms of reducing emissions while maximizing efficiency. Such a system would compensate for variations in fuel composition, but also would correct for variations in volumetric efficiency due to immediate engine history and long-term engine component wear. Present day engine controllers perform well when they are operated with the same gas composition for which they were calibrated, but because fuel composition varies geographically as well as seasonally, some method of compensation is required. A closed loop control system on a medium-duty lean-burn engine will enhance performance by maintaining the desired air-fuel ratio to eliminate any unwanted rich or lean excursions (relative to the desired air-fuel ratio) that produce excess engine-out emissions. Such a system can also guard against internal engine damage due to overheating and/or engine knock.
Technical Paper

NOX Decomposition in Natural Gas, Diesel and Gasoline Engines for Selective NOX Recirculation

2005-05-11
2005-01-2144
Selective NOX Recirculation (SNR) involves three main steps in NOX reduction. The first step adsorbs NOX from the exhaust stream, followed by periodic desorption from the aftertreatment medium. The final step passes the desorbed NOX gas into the intake air stream and feeds into the engine. A percentage of the NOX is expected to be decomposed during the combustion process. The motivation for this research was to clarify the reduction of NOX from large stationary engines. The objective of this paper is to report the NOX decomposition phenomenon during the combustion process from three test engines. The results will be used to develop an optimal system for the conversion of NOX with a NOX adsorbtion system. A 1993 Cummins L10G natural gas engine, a 1992 Detroit Diesel series 60 engine and a 13hp Honda gasoline engine were used in the experiments. Commercially available nitric oxide (NO) was injected into the engine intake to mimic the NOX stream from the desorption process.
Technical Paper

Assessment of NOx Destruction in Diesel Engines by Injecting NO in the Intake Manifold

2005-04-11
2005-01-0370
Emissions from diesel engines, particularly NOx and TPM emissions are harmful to the environment. Reduction of NOx emissions from diesel engines is of increasing concern. In 1998, a novel approach called Selective NOx Recirculation (SNR) was used to reduce NOx emissions in diesel engines. The SNR concept relies on two major parts, one to collect the NOx emissions from the exhaust by an adsorber, and another to decompose NOx using the in-cylinder combustion process by injecting the collected NOx emissions into the intake manifold at an elevated concentration. This paper deals with the destruction rates during the combustion process. A 1992 DDC series 60, 350 hp, 12.7 liter engine was connected to a 500 hp DC dynamometer. A full-scale dilution tunnel and analyzers capable of measuring continuous NOx, CO2, CO, HC, and PM in the exhaust were used.
Technical Paper

Nitric Oxide Conversion in a Spark Ignited Natural Gas Engine

2005-04-11
2005-01-0234
Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.
Technical Paper

EC-Diesel Technology Validation Program Interim Report

2000-06-19
2000-01-1854
ARCO has developed diesel fuel called Emission Control Diesel (EC-D) that results in substantially lower exhaust emissions compared to a typical California diesel fuel. EC-D has ultra-low sulfur content, low aromatics, and has a high cetane number. EC-D is produced from typical crude oil using a conventional refining process. Initial engine laboratory tests and vehicle tests indicated that EC-D reduced regulated emissions while maintaining fuel economy, compared to a typical California diesel fuel. Ultra-low sulfur diesel fuels such as EC-D may enable the widespread use of passive catalyzed particulate filters for both new and existing diesel engines. The use of catalyzed particulate filters could allow large reductions of particulate matter emitted from vehicles. A one-year technology validation program is being run to evaluate EC-D and catalyzed particulate filters using diesel vehicles operating in Southern California.
Technical Paper

Operation of a Compression Ignition Engine with a HEUI Injection System on Natural Gas with Diesel Pilot Injection

1999-10-25
1999-01-3522
Dual fuel engines employing pilot diesel injection to ignite premixed natural gas provide an opportunity for liquid petroleum fuel replacement and for reduced emissions of oxides of nitrogen (NOx) and particulate matter (PM). A Navistar T444E turbocharged V8 engine was converted to operate in dual fuel mode by metering the compressed natural gas (CNG) with an IMPCO Technologies, Inc. regulator and electronic valve while retaining the stock Navistar Hydraulically-Actuated Electronically-Controlled Unit Injection (HEUI) system for diesel pilot injection. A dedicated controller was designed and constructed to allow manual control of diesel fuel injection pulsewidth (FIPW), diesel injection advance (ADV), hydraulic injection control pressure (ICP) and natural gas mass flow. The controller employed two Microchip, Inc. PIC-based microcontrollers: one to perform initialization of a Silicon Systems, Inc. 67F867 engine interface peripheral, and the other to perform the runtime algorithms.
Technical Paper

Numerical Simulation of a Two-Stroke Linear Engine-Alternator Combination

1999-03-01
1999-01-0921
Series hybrid electric vehicles (HEVs) require power-plants that can generate electrical energy without specifically requiring rotary input shaft motion. A small-bore working prototype of a two-stroke spark ignited linear engine-alternator combination has been designed, constructed and tested and has been found to produce as much as 316W of electrical energy. This engine consists of two opposed pistons (of 36 mm diameter) linked by a connecting rod with a permanent magnet alternator arranged on the reciprocating shaft. This paper presents the numerical modeling of the operation of the linear engine. The piston motion of the linear engine is not mechanically defined: it rather results from the balance of the in-cylinder pressures, inertia, friction, and the load applied to the shaft by the alternator, along with history effects from the previous cycle. The engine computational model combines dynamic and thermodynamic analyses.
Technical Paper

Neural Network-Based Diesel Engine Emissions Prediction Using In-Cylinder Combustion Pressure

1999-05-03
1999-01-1532
This paper explores the feasibility of using in-cylinder pressure-based variables to predict gaseous exhaust emissions levels from a Navistar T444 direct injection diesel engine through the use of neural networks. The networks were trained using in-cylinder pressure derived variables generated at steady state conditions over a wide speed and load test matrix. The networks were then validated on previously “unseen” real-time data obtained from the Federal Test Procedure cycle through the use of a high speed digital signal processor data acquisition system. Once fully trained, the DSP-based system developed in this work allows the real-time prediction of NOX and CO2 emissions from this engine on a cycle-by-cycle basis without requiring emissions measurement.
Technical Paper

The DOE/NREL Environmental Science & Health Effects Program - An Overview

1999-04-27
1999-01-2249
This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.
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