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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

(Paint) film as an alternative to spray applied paint has received growing attention in recent years. The potential for economic and environmental advantage and quality enhancement with this technology has been reported in several technical papers (Ref. 1, 3 and 4). The actual practice of film finishing, however, has received only limited notice. Film finishes have been applied to aluminum, stainless steel, PVC, and ABS. Starting in 1982, part applications include: wheel covers, door edge guards, window surrounds, roof drip moldings, lower windshield moldings, rocker panels, body side moldings, B pillars, and A pillars. Industry awareness and acceptance of film finishing as a viable alternative to spray applied paint is increasing. The two technologies are similar in many ways, yet distinctly different in other ways. They share a common goal: To yield a durable finish, economically and with superior visual impact. This paper reviews the unique aspects of film finishing.

To reduce the Body in White (BIW) mass, it is necessary to expand the application of Advanced High-Strength Steels (AHSS) to complex shaped parts. In order to apply AHSS to complex shaped parts with thinner gauge, high formability steel is required. However, higher strength steels tend to display lower elongations, compared with low/medium strength steels. Current AHSS are applied to limited parts for this reason. The new 1.2GPa material, with high formability, was developed to solve this issue. The mechanical property targets for the high elongation 1.2GPa material were achieved by precise metallurgical optimization. Many material aspects were studied, such as formability, weldabilty, impact strength, and delayed fracture. As the result of this development, 1.2GPa AHSS has been applied to a new vehicle launched in 2013.The application of this material was the 1st in the world, and achieved a 11kg mass reduction.

Flexibility, oil resistance, and the need for heat resistance to 150°C-plus temperatures have traditionally limited automotive design engineers to two options - thermoset rubber or heat-shielding conventional thermoplastic elastomers (TPE). Both of these options present limitations in part design, the ability to consolidate the number of components in a part of assembly, and on total cost. This paper presents a class of high-performance, flexible thermoplastic elastomers based on dynamically vulcanized polyacrylate (ACM) elastomer dispersed in a continuous matrix of polyamide (PA) thermoplastic. These materials are capable of sustained heat resistance to 150°C and short-term heat resistance to 175°C, without requiring heat shielding. Recent advancements in blow molding and functional testing of the PA//ACM TPEs for automotive air management (ducts) and underhood sealing applications will be shown.

The demand for improved fuel economy in both cars and trucks has emphasized the need for lighter weight components. The application of high strength steel to wheels, both rim and disc, represents a significant opportunity for the automotive industry. This paper discusses the Ranger HSLA wheel program that achieved a 9.7 lbs. per vehicle weight savings relative to a plain carbon steel wheel of the same design. It describes the Ranger wheel specifications, the material selection, the metallurgical considerations of applying HSLA to wheels, and HSLA arc and flash butt welding. The Ranger wheel design and the development of the manufacturing process is discussed, including design modifications to accommodate the lighter gage. The results demonstrate that wheels can be successfully manufactured from low sulfur 60XK HSLA steel in a conventional high volume process (stamped disc and rolled rim) to meet all wheel performance requirements and achieve a significant weight reduction.

This paper describes the Electronic Air Suspension (EAS) System developed by Ford Motor Company. Design trade-offs between load-carrying capacity necessary with conventional steel spring suspension systems and riding comfort are avoided when today's microcomputer technology is combined with a leveling air spring suspension. An electric air compressor with regenerative air dryer, three electronic “Hall Effect” height sensors, four air springs with integral solenoids, and a control module with a single chip microcomputer are the key EAS System components discussed.

As part of the 1997 Propane Vehicle Challenge, a team of twelve UTEP students converted a 1996 Dodge Grand Caravan with a 3.3 L V6 engine to dedicated Liquefied Petroleum Gas (LPG) operation according to the 1997 Propane Vehicle Challenge (PVC) competition rules (16). The 1997 UTEP team developed an LPG liquid phase port fuel injection (LPP-FI) system for the minivan. The UTEP design strategy combines simplicity and sound engineering practices with the effective use of heat resistant materials to maintain the LPG in the liquid phase at temperatures encountered in the fuel delivery system. The team identified two options for fuel storage with in-tank fuel pumps. The competition vehicle incorporates a five-manifold eight inch diameter Sleegers Engineering LPG tank fitted with a Walbro LPTS in-tank pump system, providing a calculated range of 310 city miles and 438 highway miles.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

This paper describes new 2 stroke fuel injected spark ignition outboard motor equipped with unique oxygen sensor feed back control system to assure constantly optimized air/fuel ratio. First, the general concept and the engineering target of commercial model are explained, and then the design and arrangement of oxygen sensor feedback fuel injection control system are described. Common automotive oxygen sensor is utilized in this system, and it is devised to overcome the problems inherent in 2-stroke engines. This paper also describes the controlled combustion system that enhances consistent and stable performance, and improves fuel efficiency. Applying these technologies, 40% less fuel consumption in cruise range was demonstrated by the comparative test with conventional fuel injected 2-stroke model.

A theoretical model is presented for predicting springback of wide sheet metal subjected to 2D-stretch-bending operation. The material is assumed to be normal anisotropic with n-th power hardening law, σ = Fεn. Two types of stretch-bending experiment, bending with simultaneous stretching and stretch-bending followed by consecutive re-stretching, is conducted using AK sheet steel and sheet aluminum alloy A5182-O. The measured values of springback are in good agreement with analytical ones for a wide range of bending radii, stretching forces, and loading conditions. Furthermore, a calculation method for predicting springback configurations of 2D sheet metal parts with arbitrary cross-sections which include both stretch-bending and stretch-bending-unbending deformation is proposed.

This paper describes the engineering, manufacturing and integration necessary to produce the Corvette's first ever all-aluminum spaceframe (see Figure 1). The engineering and manufacturing of the spaceframe was a joint venture between General Motors and suppliers ALCOA (Aluminum Company of America) and Dana Corporation. ALCOA led the initial design of the spaceframe; Dana Corp led the manufacturing; General Motors' Engineering and Manufacturing groups led the integration of the assembly. The aluminum spaceframe design is modeled after the baseline steel structure of the Corvette coupe. The aluminum spaceframe reduces 140 lbs from the steel baseline and enters the plant at 285 lbs. This frame allows the 2006 Corvette Z06 to enter the market at a 3100 lbs curb weight. Aluminum casting, extruding, stamping, hydroforming, laser welding, Metal Inert Gas (MIG) welding, Self Pierce Riveting (SPR), and full spaceframe machining make up the main technologies used to produce this spaceframe.

Aircraft potable (drinking) water systems haven’t changed significantly in the last half-century. These systems consist of cylindrical water tanks pressurized by bleed air from the jet engines, with insulated stainless steel distribution lines. What has changed recently is the increase in the possibility of aircraft picking up contaminated drinking water at foreign and domestic stops. Customer awareness of these problems has also changed - to the point where having reliable drinking water is now a competitive issue among airlines. Old style potable water systems that are used on modern aircraft are high maintenance and exacerbate the growth of microbes because the water is static much of the time. The integrity of some pressurized water tanks are also a concern after years of use. Cost-effective mechanical and biological solutions exist that can significantly reduce the amount of chemicals added and provide good potable water.

Weight reduction of automobiles is key technology in order to improve fuel economy and driving performance. Concerning of the motorcycle engine, weight reduction is also the fundamental and important technologies. Cylinder is one of the main parts of engine and the wear characteristics of the cylinder liner are largely related to the engine performance. Gray iron liners squeezed in aluminum cylinder block have been widely used. This is due to the excellent resistance to abrasion of gray iron. In order to realize light all aluminum cylinder, the good abrasion resistant method is necessary to develop to be applied with inner surface of liners. We have developed the new Rapid Composite Plating System for the motorcycle engine cylinders. This system made it possible to adopt all aluminum cylinders without cast iron liners to new type of engine.

Examining the noise reduction of a motorcycle, the requirement of an effective method of reducing a drive chain noise has been a pending issue similarly to noise originating from an engine or exhaust system, etc. Through this study, it became clear that the mechanism of chain noise could be classified into two; low frequency noise originated from cordal action according to the degree of chain engagement and high frequency noise generated by impact when a chain roller hits sprocket bottom. An improvement of urethane resin damper shape, mounted on a drive side sprocket, was effective for noise reduction of the former while our development of a chain drive that combined an additional urethane resin roller with an iron roller worked well for the latter. The new chain system that combined this new idea has been proven to be capable of reducing the chain noise to half compared with a conventional system.

Developing lightweight, stiff and crash-resistant vehicle body structures requires a balance between part geometry and material properties. High strength materials suitable for crash resistance impose geometry limitations on depth of draw, radii and wall angles that reduce geometric efficiency. The introduction of 3rd generation Advanced High Strength Steels (AHSS) can potentially change the relationship between strength and geometry and enable simultaneous improvements in both. This paper will demonstrate applicability of 3rd generation AHSS with higher strength and ductility to replace the 780 MPa Dual Phase steel in a sill reinforcement on the current Jeep Cherokee. The focus will be on formability, beginning with virtual simulation and continuing through a demonstration run on the current production stamping tools and press.

This paper discusses five different methods for measuring the gas stream temperature from a burner using a hydrocarbon fuel, air, and oxygen. Tests were made with a single shielded BeO probe, a bare wire iridium -- 60% rhodium/iridium couple, a tantalum triple shielded platinum -- 10% rhodium/platinum thermocouple, the sodium line reversed technique, and a watercooled total enthalpy probe. The most serviceable system proved to be the bare wire iridium -- 60% rhodium/iridium couple, particularly for carrying out stream surveys where relative, rather than true temperatures, are of primary concern. More study is needed to establish a system for determining the true stream temperature.

The 42-Volt electrical system is being introduced in automobiles to provide the extra power needed for various electromagnetic devices. These paper discuses the opportunity offered by the 42Volt for powder metal parts and the challenges. Major opportunities are in motors. A brief discussion of motors and the performance requirements for the magnetic core material used is included. Brushless motor design can benefit the most from insulated iron powder compacts because of the design simplicity of powder metal parts and three dimensional flux capability which is most beneficial in rotating devices.(P/M stands for powder metallurgy and not permanent magnets)

Titanium alloy for forging and pure titanium material for exhaust systems have been developed. The forging alloy will be applied to production of lightweight motorcycle frames and the pure titanium will be applied to improve engine performance. The materials have been made inexpensive by the use of off-grade sponge that includes many impurities for production of titanium ingot. Stable characteristics have been obtained by controlling oxygen equivalent after setting the volume of tolerable impurities by considering mechanical properties and production engineering. In spite of low-cost, the material provides the same design strength compared to conventional material, and enables parts production with existing equipment. A review of manufacturing and surface treatment processes indicated a reduction in the price of titanium parts produced with this new material.

Engines are assigned big subjects such as low emission and low fuel consumption as well as higher output (higher efficiency) in the latest trend of environmental protection. In order to meet these requirements, Air/Fuel ratio of recent high performance engines is being arranged leaner than that of conventional engines. As a result exhaust valve seat inserts used in these engines have problems of their wear resistance because of high exhaust gas temperature. By analyzing wear mechanism under the lean burn conditions, authors developed material for exhaust valve seat inserts which show superior wear resistance under high operating temperature. For the purpose to enhance heat resistance, authors added alloy steel powder for matrix powder and used hard particles which have good diffusion with matrix. The developed material does not include Ni and Co powders for cost saving and has superior machinability.

Crankshafts of motorcycles require high strength, high reliability and low manufacturing cost. Recently, a reduction of Pb content in the free-cutting steel, which is harmful substance, is required. In order to satisfy such requirements, we started the development of Pb-free free-cutting steel which simultaneously enabled the omission of the normalizing process. For the omission of normalizing process, we adjusted the content of Carbon, Manganese and Nitrogen of the steel. This developed steel can obtain adequate hardness and fine microstructure by air-cooling after forging. Pb-free free-cutting steel was developed based on Calcium-sulfur free-cutting steel. Pb free-cutting steel is excellent in cutting chips frangibility in lathe process. We thought that it was necessary that cutting chips frangibility of developed steel was equal to Pb free-cutting steel. It was found that cutting chips frangibility depend on a non-metallic inclusion's composition, shape and dispersion.