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After-treatment sensors are used in the ECU feedback control to calibrate the engine operating parameters. Due to their contact with exhaust gases, especially NOx sensors are prone to soot deposition with a consequent decay of their performance. Several phenomena occur at the same time leading to sensor contamination: thermophoresis, unburnt hydrocarbons condensation and eddy diffusion of submicron particles. Conversely, soot combustion and shear forces may act in reducing soot deposition. This study proposes a predictive 3D-CFD model for the analysis of the development of soot deposition layer on the sensor surfaces. Alongside with the implementation of deposit and removal mechanisms, the effects on both thermal properties and shape of the surfaces are taken in account. The latter leads to obtain a more accurate and complete modelling of the phenomenon influencing the sensor overall performance.

Several predictive equations based on the chemical composition of gasoline have been shown to estimate the particulate emissions of light-duty, internal combustion engine (ICE) powered vehicles and are reviewed in this paper. Improvements to one of them, the PEISimDis equation are detailed herein. The PEISimDis predictive equation was developed by General Motor’s researchers in 2022 based on two laboratory gas chromatography (GC) analyses; Simulated Distillation (SimDis), ASTM D7096 and Detailed Hydrocarbon Analysis (DHA), ASTM D6730. The DHA method is a gas chromatography mass spectroscopy (GC/MS) methodology and provides the detailed speciation of the hundreds of hydrocarbon species within gasoline. A DHA’s aromatic species from carbon group seven through ten plus (C7 – C10+) can be used to calculate a Particulate Evaluation Index (PEI) of a gasoline, however this technique takes many hours to derive because of its long chromatography analysis time.

Presently, a main mobility sector objective is to reduce its impact on the global greenhouse gas emissions. While there are many techniques being explored, a promising approach to improve fuel economy is to reduce the required energy by using slipstream effects. This study analyzes the demanded engine power and mechanical energy used by heavy-duty trucks during platooning and non-platooning operation to determine the aerodynamic benefits of the slipstream. A series of platooning tests utilizing class 8 semi-trucks platooning via Cooperative Adaptive Cruise Control (CACC) are performed. Comparing the demanded engine power and mechanical energy used reveals the benefits of platooning on the aerodynamic drag while disregarding any potential negative side effects on the engine. However, energy savings were lower than expected in some cases.

Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.

There has been an increasing interest in exploring the potential to reduce energy consumption of future connected and automated vehicles. People have extensively studied various eco-driving implementations that leverage preview information provided by on-board sensors and connectivity, as well as the control authority enabled by automation. Quantitative real-world evaluation of eco-driving benefits is a challenging task. The standard regulatory driving cycles used for measuring exhaust emissions and fuel economy are not truly representative of real-world driving, nor for capturing how connectivity and automation might influence driving trajectories. To adequately consider real-world driving behavior and potential “off-cycle” impacts, this paper presents four collaborative evaluation methods: large-scale simulation, in-depth simulation, vehicle-in-the-loop testing, and vehicle road testing.

Evaporative cooling of the fuel-air charge by fuel evaporation is an important feature of direct-injection spark-ignition engines that improves fuel knock resistance and reduces pumping losses at intermediate load, but in some cases, may increase fine particle emissions. We have reported on experimental approaches for measuring both total heat of vaporization and examination of the evaporative heat effect as a function of fraction evaporated for gasolines and ethanol blends. In this paper, we extend this work to include other low-molecular-weight alcohols and present results on species evolution during fuel evaporation by coupling a mass spectrometer to our differential scanning calorimetry/thermogravimetric analysis instrument. The alcohols examined were methanol, ethanol, 1-propanol, isopropanol, 2-butanol, and isobutanol at 10 volume percent, 20 volume percent, and 30 volume percent.

A relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from direct injection spark ignition (DISI) vehicles. The fundamental cause of this observation is not well understood. One potential explanation is that increased evaporative cooling as a result of ethanol’s high HOV may slow evaporation and prevent sufficient reactant mixing resulting in the combustion of localized fuel rich regions within the cylinder. In addition, it is well known that ethanol when blended in gasoline forms positive azeotropes which can alter the liquid/vapor composition during the vaporization process. In fact, it was shown recently through a numerical study that these interactions can retain the aromatic species within the liquid phase impeding the in-cylinder mixing of these compounds, which would accentuate PM formation upon combustion.

Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.

In some studies, a relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from vehicles equipped with spark ignition engines. The fundamental cause of the PM increase seen for moderate ethanol concentrations is not well understood. Ethanol features a greater heat of vaporization (HOV) than gasoline and also influences vaporization by altering the liquid and vapor composition throughout the distillation process. A droplet vaporization model was developed to explore ethanol’s effect on the evaporation of aromatic compounds known to be PM precursors. The evolving droplet composition is modeled as a distillation process, with non-ideal interactions between oxygenates and hydrocarbons accounted for using UNIFAC group contribution theory. Predicted composition and distillation curves were validated by experiments.

Several high octane number oxygenates that could be derived from biomass were blended with gasoline and examined for performance properties and their impact on knock resistance and fine particle emissions in a single cylinder direct-injection spark-ignition engine. The oxygenates included ethanol, isobutanol, anisole, 4-methylanisole, 2-phenylethanol, 2,5-dimethyl furan, and 2,4-xylenol. These were blended into a summertime blendstock for oxygenate blending at levels ranging from 10 to 50 percent by volume. The base gasoline, its blends with p-xylene and p-cymene, and high-octane racing gasoline were tested as controls. Relevant gasoline properties including research octane number (RON), motor octane number, distillation curve, and vapor pressure were measured. Detailed hydrocarbon analysis was used to estimate heat of vaporization and particulate matter index (PMI). Experiments were conducted to measure knock-limited spark advance and particulate matter (PM) emissions.

A study and analysis of the relation of biodiesel chemical structures to the resulting soot characteristics and soot oxidative reactivity is presented. Soot samples generated from combustion of various methyl esters, alkanes, biodiesel and diesel fuels in laminar co-flow diffusion flames are analyzed to evaluate the impact of fuel-bound oxygen in fatty acid esters on soot oxidation behavior. Thermogravimetric analysis (TGA) of soot samples collected from diffusion flames show that chemical variations in biodiesel ester compounds have an impact on soot oxidative reactivity and soot characteristics in contrast to findings reported previously in the literature. Soot derived from methyl esters with shorter alkyl chains, such as methyl butyrate and methyl hexanoate, exhibit higher reactivity than those with longer carbon chain lengths, such as methyl oleate, which are more representative of biodiesel fuels.

The Leaner Lifted-Flame Combustion (LLFC) strategy offers a possible alternative to low temperature combustion or other globally lean, premixed operation strategies to reduce soot directly in the flame, while maintaining mixing-controlled combustion. Adjustments to fuel properties, especially fuel oxygenation, have been reported to have potentially beneficial effects for LLFC applications. Six fuels were selected or blended based on cetane number, oxygen content, molecular structure, and the presence of an aromatic hydrocarbon. The experiments compared different fuel blends made of n-hexadecane, n-dodecane, methyl decanoate, tri-propylene glycol monomethyl ether (TPGME), as well as m-xylene. Several optical diagnostics have been used simultaneously to monitor the ignition, combustion and soot formation/oxidation processes from spray flames in a constant-volume combustion vessel.

New emissions certification requirements for medium duty vehicles (MDV) meeting chassis dynamometer regulations in the 8,500 lb to 14,000 lb weight classes as well as heavy duty (HD) engine dynamometer certified applications in both the under 14,000 lb and over 14,000 lb weight classes employing large diameter exhaust pipes (up to 4″) have created new exhaust stream sampling concerns. Current On-Board-Diagnostic (OBD) dyno certified particulate matter (PM) requirements were/are 7x the standard for 2010-2012 applications with a planned phase in down to 3x the standard by 2017. Chassis certified applications undergo a similar reduction down to 1.75x the standard for 2017 model year (MY) applications. Failure detection of a Diesel Particulate Filter (DPF) at these low detection limits facilitates the need for a particulate matter sensor.

A single-cylinder Direct Injection Spark Ignition (DISI) engine with optical access was used to investigate the effects of ethanol/gasoline blends on in-cylinder formation of particulate matter (PM) and fuel spray characteristics. Indolene was used as a baseline fuel and two blends of 50% and 85% ethanol (by volume, balance indolene) were investigated. Time resolved thermal radiation (incandescence/natural luminosity) of soot particles and fuel spray characteristics were recorded using a high speed camera. The images were analyzed to quantify soot formation in units of relative image intensity as a function of important engine operating conditions, including ethanol concentration in the fuel, fuel injection timing (250, 300 and 320° bTDC), and coolant temperature (25°C and 90°C). Spatially-integrated incandescence was used as a metric to quantify the level of in-cylinder PM formed at the different operating conditions.

Two different implementations of Partial Flow Dilution (PFD) methodology designed for gravimetric particulate matter (PM) sampling are evaluated for applicability to light-duty chassis emissions testing. Filter PM measurements were collected and compared to constant volume sampler (CVS) full dilution tunnel PM filter measurements and other real-time PM measurement technologies, using gasoline vehicles generating a range of 0.1 to 10.0 mg/mile PM. Exhaust samples were collected for each phase of the Federal Test Procedure (FTP-75) with a fourth filter sample collected for the US06 supplemental cycle. Both PFDs satisfactorily met proportionality criteria for conventional combustion engines, but some improvements are needed for hybrid electric vehicles (HEVs). The PM mass collected scaled linearly with the CVS tunnel samples, with slopes of 1.03 and 0.74 for the two PFDs.

The use of exhaust gas recirculation (EGR) in internal combustion engines has significant impacts on combustion and emissions. EGR can be used to reduce in-cylinder NOx production, reduce emitted particulate matter, and enable advanced forms of combustion. To maximize the benefits of EGR, the exhaust gases are often cooled with on-engine liquid to gas heat exchangers. A common problem with this approach is the build-up of a fouling layer inside the heat exchanger due to thermophoresis and condensation, reducing the effectiveness of the heat exchanger in lowering gas temperatures. Literature has shown the effectiveness to initially drop rapidly and then approach steady state after a variable amount of time. The asymptotic behavior of the effectiveness has not been well explained. A range of theories have been proposed including fouling layer removal, changing fouling layer properties, and cessation of thermophoresis.

Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution.

A study has been conducted to measure the particle number emissions from a current-generation 1.6-liter, Euro IV-compliant turbo-charged Gasoline Direct Injection (GDI) passenger car engine. A fast-response particle size spectrometer was used along with a PMP-compliant particulate measurement system to measure the effect of various engine parameters on the particulate emissions during the New European Drive Cycle (NEDC). Overall particle number is shown along with further analysis of the transient particle emissions. The cold start clearly affects particle formation with approximately 50% of the cumulative particle number being emitted within 200 seconds of the start. Even beyond 200 seconds, the particle number emissions fall as the test progresses and are generally consistent with increases in engine coolant temperature indicating that cold engine fuel preparation issues are contributing to the particle number count.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

This study investigates the effect of diesel particulate filters (DPF) on the performance of exhaust gas recirculation (EGR) coolers. EGR coolers were tested with and without the use of a DPF and their measured performances were compared. The exhaust gas was filtered using a Ni-Fe-Cr-Al metallic foam wall flow diesel particulate filter. The DPFs used in this investigation had very low Space Velocity (SV) characteristics in order to minimize the effect of filtration on the pressure drop. Two different measurement methods were employed to determine particulate matter (PM) emission levels at locations before and after the DPF. The first method involved the collection of PM on quartz filters followed by thermal analysis of the filters to monitor the removal of soot, semi-volatile organics, and sulfate across the DPF. The second method measured the time resolved PM mass in the exhaust with a Dekati Mass Monitor.