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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

The new 2GR-FKS / FXS engines were developed to achieve stringent fuel economy and emission targets and respond to recent innovations in the field. The major parts of the 2GR-FKS/FXS engines were re-designed based on the well-received dynamic performance and fuel economy aspects of the 2GR-FE engine. The aims of this development were as follows. 1 Best-in-class power performance 2 Environmental performance that maximizes thermal efficiency and complies with fuel economy and emission regulations in each country by a wide margin 3 Engine response typical of V6 engines through drastic weight reduction of moving parts To achieve these conflicting aims, the developed engines use a modified version of the D-4S fuel injection system, which enables selective use of direct and port injection, in addition to advanced technologies such as variable valve technology (VVT) with a mid-position lock system and an exhaust port cooling system.

Periodic increases of PN, PM, and regulated gases associated with DPF regeneration from a heavy-duty truck equipped with a diesel particulate filter (DPF; non-SCR truck) and from a heavy-duty diesel engine equipped with a DPF and a urea-SCR (SCR engine) were investigated. Both met Japanese 2009 regulations. From both exhausts, PN emissions two orders of magnitude higher than the European legislation limit were observed in the regeneration cycle, and these emissions gradually decreased in subsequent cycles. This can be explained by the relation between the filtering efficiency and the amount of loaded soot in the DPF. No emissions particular to regeneration, such as soot fragments, were observed. In some cases, higher PN emissions were observed from the SCR engine. This may be because of the difference in DPF performance, but there is a possibility that some particles were produced in the urea-SCR system.

It is important to reduce the diffusion polarization for achieving higher performance in direct methanol fuel cells (DMFC). The previous research has shown the performance improvement by applying a metal foam type porous stainless steel made by a metal-plating method to the separator flow field of a DMFC. This porous flow field enabled DMFC to operate with higher power output than conventional straight groove type separator especially at higher current densities. Diffusion polarization was especially reduced by the porous flow field. This current paper experimentally analyzes the effect of a new type porous flow field that is made of a sintered spherical metal powder. The results show that the sintered metal powder flow field exhibits higher effect in performance improvement of DMFC than the metal foam type porous flow field used in the previous research.

Reduction of exhaust emissions and BSFC was studied for high pressure, wide range, and high EGR rates in a Super-clean Diesel six-cylinder heavy duty engine. The GVW 25-ton vehicle has 10.52 L engine displacement, with maximum power of 300 kW and maximum torque of 1842 Nm. The engine is equipped with high-pressure fuel injection of a 200 MPa level common-rail system. A variable geometry turbocharger (VGT) was newly designed. The maximum pressure ratio of the compressor is about twice that of the previous design: 2.5. Additionally, wide range and a high EGR rate are achieved by high pressure-loop EGR (HP-EGR) and low pressure-loop EGR (LP-EGR) with described VGT and high-pressure fuel injection. The HP-EGR can reduce NOx concentrations in the exhaust pipe, but the high EGR rate worsens smoke. The HP-EGR system layout has an important shortcoming: it has great differences of the intake EGR gas amount into each cylinder, worsens smoke.

The use of biomass fuels for vehicles has been a focus of attention all over the world in terms of prevention of global warming, effective utilization of resources and local revitalization. For the purpose of beneficial use of unused biomass resources, the movement of the use of bioethanol and biodiesel made from them has spread in Japan. In Japan, biodiesel is mainly made from waste cooking oil collected by local communities or governments, and in terms of local production for local consumption, it is used as neat fuel (100% biofuel) or mixed with diesel fuel in high concentration for the vehicles. On the other hand, extremely low emission level must be kept for not only gasoline vehicles but also diesel vehicles in the post new long-term regulation implemented from 2009 in Japan.

Lean NOx trap (LNT) and Urea-SCR system are effective aftertreatment systems as NOx reduction device in diesel engines. On the other hand, DPF has already been developed as PM reduction device and it has been used in various vehicles. LNT can absorb and reduce NOx emission in wide range exhaust temperatures, from 150°C to 400°C, and the size of LNT component can be compact in comparison with Urea-SCR system because LNT uses the diesel fuel as a reducing agent and it is needless to install the reducing agent tank in the vehicle. In this study, authors have shown that the NOx conversion rate of LNT is high in the case of extremely low NOx concentration from the engine. Also, the effects of LNT and DPF were examined using the Super Clean Diesel (SCD) Engine, which has low NOx level before aftertreatment and has been finished as Japanese national project.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

Repeatabilities of PM measurements on a heavy-duty diesel engine equipped with a diesel particulate filter (DPF) using a filter weighing method and a number counting method with a full flow dilution system and a partial flow system were evaluated. The filter method with partial flow exhibited the best repeatability. However, a good correlation between the full flow and the partial flow number counting results suggests that the fluctuations observed using the number counting method were caused by changes in the engine exhaust. Applying a strict preconditioning procedure should improve the repeatability of the number counting method because this method is more sensitive than the filter weighing method. In addition, the effects of the specifications for the number counting method were evaluated. The results indicate that the hose length from the tip of the sampling probe to the inlet of the number counting system had a negligible effect.

The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.

Unregulated emissions from a DI diesel engine with ultra-high EGR low temperature combustion were analyzed using Fourier transform infrared (FTIR) spectroscopy and the reduction characteristics of both regulated and unregulated emissions by two exhaust catalysts were investigated. With ultra-high EGR suppressing the in-cylinder soot and Nox formation as well as with the exhaust catalysts removing the engine-out THC and CO emissions, clean diesel operation in terms of ultra-low regulated emissions (Nox, PM, THC, and CO) is established in an operating range up to 50% load. To realize smokeless low temperature combustion at higher loads, EGR has to be increased to a rate with the overall (average) excess air ratio less than the stoichiometric ratio.

A variable valve timing (VVT) mechanism has been applied in a high-speed direct injection (HSDI) diesel engine. The effective compression ratio (εeff) was lowered by means of late intake valve closing (LIVC), while keeping the expansion ratio constant. Premixed charge compression ignition (PCCI) combustion, adopting the Miller-cycle, was experimentally realized and numerically analyzed. Significant improvements of NOx and soot emissions were achieved for a wide range of engine speeds and loads, frequently used in a transient mode test. The operating range of the Miller-PCCI combustion has been expanded up to an IMEP of 1.30 MPa.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

Supersonic jet / resonance enhanced multi-photon ionization (Jet-REMPI) technique was focused on the analyzing method for gas mixture like exhaust gas from automobiles. In this method, when the mass number and wavelength of excitation laser are determined adequately, the target compound can be monitored selectively. We developed a new analyzer utilizing REMPI method. Using this analyzer, real-time monitoring of exhaust gas from a motorcycle and diesel vehicles was conducted. As a result of real-time monitoring test of the vehicles, concentrations of aromatic compounds like benzene toluene etc. were quantified and real-time changes of their concentrations were observed.

In order to discuss future technical issues for urea SCR (selective catalytic reduction) system, it is necessary to assess various technical possibilities that would be applied to urea SCR systems which is capable of complying with future emission level requirements, for example Japanese 2009 emission regulation. In this paper, three measures (enhanced insulation on a DOC (diesel oxidation catalyst), aggressive urea solution injection and idling stop) are installed on a urea SCR system of a commercial engine system in order to achieve further NOx (nitrogen oxide) reductions. With combination of these three measures, NOx is drastically reduced to the levels lower than 0.7 g/kWh, which is a NOx limit value of the Japanese 2009 emission regulation. NH3 (ammonia) and HCN (hydro cyanide) are also measured as unregulated harmful components.

The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.

The chemical mechanism responsible for controlling ignition timing by using additives in HCCI has been investigated. Dimethyl ether (DME) and methanol were used as the main fuel and the additive, respectively. Fuel consumption and intermediate formation in the first stage (cool ignition) were measured with crank angle resolved pulse-valve sampling and exhaust gas analysis, where HCHO, HCOOH, CO, H2O2 and other species were detected as the intermediate. The effect of methanol addition retarding ignition is represented by an analytical model in which the growth rate of the chain reaction is reduced by the methanol addition.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

Palm oil has the important advantage of productivity compared to other vegetable oils such as rapeseed oil and soybean oil. However, the cold flow performance of palm oil methyl ester (PME) is poorer than other vegetable oil based biodiesel fuels. Previous research by the authors has shown that ethanol blending into PME improves the cold flow performance and considerably reduces smoke emission. The reduced smoke may be expected to allow an expansion in the EGR limit and lead to reduced NOx. This paper experimentally analyses the influence of EGR on smoke and NOx emissions from the diesel combustion with PME/ethanol blended fuel. The mechanisms in the smoke reduction are also analyzed.