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In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock performance. The experiments were performed using a single-cylinder engine for 6 fuel types including gasoline blends which have difference in RON varying between 90.4 and 100.2. The results showed that adding olefin content to the premium gasoline provided unfavorable effect on auto-ignition as the auto-ignition happened at unburned gas temperature of 808 K which was 52 K lower at excess air of 2.0. Thus, it reduced anti-knock performance.

Computational Fluid Dynamics (CFD) simulation is widely used in the development and validation of automotive engine performance. In engine simulation, spray breakup submodels are important because spray atomization has a significant influence on mixture formation and the combustion process. However, no breakup models have been developed for the fuel spray with plate-type multi-hole nozzle installed in port fuel injection spark ignition (SI) engines. Therefore, the purpose of this study is to simulate spray formation in port fuel injection precisely. The authors proposed the heterogeneous sheet breakup model for gasoline spray injected from plate type multi-hole nozzle. The novel breakup model was developed by clarifying the phenomenological mechanism of the spray atomization process. In this paper, this model was improved in dispersion characteristics and evaluated by the comparison of the model calculation results with experimental data.

The purpose of this study is to reduce cooling loss in gas engines using hydrogen. In this report, the effect of different hydrogen-CNG supply methods on combustion and exhaust characteristics of SI engine were investigated. As a result, the 13A-port-injection caused sharp heat release at hydrogen addition ratio (RH) of 20 %, with a maximum brake thermal efficiency of 27.5 %. Also, the hydrogen-port-injection promotes combustion above RH=40 % and reduces cooling loss, resulting in a maximum brake thermal efficiency of 31.0 % at RH=80 %, 1.8 pt higher than that of the 13A-port-injection.

In recent years, internal combustion engine using hydrogen gas, has attracted attention as one solution to the problem of global warming. Hydrogen gas has excellent combustion characteristics such as wide limits of inflammability and fast burning velocity because of high diffusion rate. Therefore, it has been made to obtain stable ignition and combustion by adding hydrogen with lean mixture in spark ignition engines using hydrocarbon fuels and to be attempted efficient operation by engine researchers. The purpose of this study is to reduce cooling loss in a gas engine using hydrogen gas and hydrogen Mixer system (Mixer) engine was remodeled to hydrogen Port Injection (PI) system engine. In this report, the heterogeneity of hydrogen mixture is clarified by comparing the combustion characteristics of the Mixer and the PI, and the effect of the difference in hydrogen supply systems on cooling loss is system. Ignition delay of the PI system is shorter than that of the Mixer.

Research on alternative fuels is necessary to reduce CO2 emissions. Hydrotreated Vegetable Oil (HVO) of light fuel physically improves spray and combustion characteristics. Fatty Acid Methyl Ester (FAME) is an oxygenated fuel and its combustion characteristics are chemically improved, although its spray characteristics such as penetration and atomization are deteriorated. The purpose of this study is to understand the effects of blending HVO, which has carbon neutral (CN) characteristics, with FAME, which also has CN characteristics, on spray and combustion characteristics, and to further improve emission such as THC and Smoke. This report presents the effect of the combination of improved spray characteristics and oxygenated fuel on emissions. Spray characteristics such as penetration, spray angle and spray volume were investigated by shadowgraph photography.

Bio-hydro fined diesel (BHD) oil is known as a second generation oil made from bio hydro finning process. Biodiesel in the first generation is made from transesterification process and it has several disadvantages such as high density and increased the viscosity that can cause operational problems because can make some deposits in the engine. To overcome this, the second generation process of biodiesel has been modified from the first generation oil. BHD is made from the waste cooking oil by using the hydro finning process without the trans-esterification process. The results of BHD oil has nearly the same with diesel oil. BHD oil has low viscosity and high oxidation stability. Therefore, BHD oil can be used in the diesel engine without making any modifications in the engine. In this study, the comparison of performance and emissions characteristics from BHD oil, waste cooking oil, and diesel oil are investigated.

The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

A fuel design concept for an HCCI engine based on chemical kinetics to optimize the heat release profile and achieve robust ignition was proposed, and applied to the design of the optimal methane-based blend. Ignition process chemistry of each single-component of natural gas, methane, ethane, propane, n-butane and isobutane, was analyzed using detailed chemical kinetic computations. Ethane exhibits low ignitability, close to that of methane, when the initial temperature is below 800 K, but higher ignitability, close to those of propane, n-butane and isobutane, when the initial temperature is above 1100 K. Furthermore, ethane shows a higher heat release rate during the late stage of the ignition process. If the early stage of an ignition process takes place during the compression stroke, this kind of heat release profile is desirable in an HCCI engine to reduce cycle-to-cycle variation during the expansion stroke.

Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

Detailed reaction path analyses of DME (dimethyl ether, CH3OCH3) and n-heptane (n-C7H16) were performed computationally with the “contribution matrix” showing the contribution ratios of important elementary reactions to formation or removal of every species or heat release at transient temperatures. It was found that the “H2O2 reaction loop” defined by the authors plays an important role in the initiation of thermal ignition. This is a reaction loop composed of four reactions, H2O2 + M → 2OH + M, OH + CH2O → HCO + H2O, HCO + O2 → HO2 + CO and 2HO2 → H2O2 + O2. The overall reaction is 2CH2O + O2 → 2H2O + 2CO + 473 kJ. This loop begins to be active, when the OH formation by H2O2 + M → 2OH + M becomes dominant against those by cool-flame reactions with NTC's (negative temperature coefficient) at about 950 K. The loop releases a significant amount of heat without consuming H2O2.

A single cylinder engine has been run with direct-injection premixed charge compression ignition (PCCI) operation. The operation is fueled with primary reference fuels for a wide variety of injection timing and equivalence ratio to investigate the effect of charge stratification and octane rating on PCCI combustion. The test results showed that although the change of the injection timing can gain the high combustion efficiency for a wide range of equivalence ratio, the combustion phasing where the high combustion efficiency is accomplished is not varied only by changing the injection timings. Therefore, the only change of injection timings does not improve the thermal efficiency which is influenced by the combustion phasing. On the other hand, at the fixed compression ratio, inlet air temperature and so on, the octane rating is useful in altering the combustion phasing.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

In this study, characteristics of the development and auto-ignition/combustion of hydrogen jets were investigated in a constant-volume vessel. The authors focused on the effects of the jet developing process and thermodynamic states of the ambient gas on auto-ignition delays of hydrogen jets. The results show that the ambient gas temperature and nozzle-hole diameter are significantly effective parameters. By contrast, it is clarified that the ambient gas oxygen concentration has a weak effect on the auto-ignition/combustion of hydrogen jets. Consequently, it is supposed that the mixture formation process is capable of improving the auto-ignition/combustion of hydrogen jets.

In an SI engine with direct injection of gasoline (DGI), many small droplets disperse in premixed gas in the cylinder. In a CI engine, diesel spray is injected a cylinder, thus, the situation at the spray periphery is almost the same as that of DGI SI engine. From the standpoint it is useful for understanding the combustion phenomena in both engines to experiment the combined combustion of premixed gas where many small droplets exist. This paper describes this kind of combustion and it seems to be able to apply the results to the simulation of combustion in these engines.