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Technical Paper

Development and Validation of a Reduced Chemical Kinetic Mechanism of Dimethyl Carbonate and Ethylene Carbonate

2024-04-09
2024-01-2085
With the rapid development of electric vehicles, the demands for lithium-ion batteries and advanced battery technologies are growing. Today, lithium-ion batteries mainly use liquid electrolytes, containing organic compounds such as dimethyl carbonate and ethylene carbonate as solvents for the lithium salts. However, when thermal runaway occurs, the electrolyte decomposes, venting combustible gases that could readily be ignited when mixed with air and leading to pronounced heat release from the combustion of the mixture. So far, the chemical behavior of electrolytes during thermal runaway in lithium-ion batteries is not comprehensively understood. Well-validated compact chemical kinetic mechanisms of the electrolyte components are required to describe this process in CFD simulations. In this work, submechanisms of dimethyl carbonate and ethylene carbonate were developed and adopted in the Ansys Model Fuel Library (MFL).
Journal Article

Thermal Reduced Order Modeling for System Analysis of EV Battery

2023-04-11
2023-01-0931
The safety, performance, and operational life of power dense Lithium-ion batteries used in Hybrid and Electric Vehicles are dependent on the operating temperature. Modeling and simulation are essential tools used to accelerate the design process of optimal thermal management systems. However, high-fidelity 3D computational fluid dynamics (CFD) simulation of such systems is often difficult and computationally expensive. In this paper, we demonstrate a multi-part coupled system model for simulating the heating/cooling system of the traction battery at a module level. We have reduced computational time by employing reduced-order modeling (ROM) framework on separate 3D CFD models of the battery module and the cooling plate. The order of the thermal ROM has also been varied to study the trade-off between accuracy, fidelity, and complexity. The ROMs are bidirectionally coupled to an empirical battery model built from in-house test data.
Technical Paper

Effects of Wind Speed and Longitudinal Direction on Fire Patterns from a Vehicle Fire in a Compact Car

2017-03-28
2017-01-1353
This paper compares the material consumption and fire patterns which developed on four nearly identical compact sedans when each was burned for exactly the same amount of time, but with different wind speed and direction during the burns. This paper will also compare the effects of environmental exposure to the fire patterns on the vehicles. The burn demonstrations were completed at an outdoor facility in southeast Michigan on four late model compact sedans. The wind direction was controlled by placing the subject vehicle with either the front facing into the wind, or rear facing into the wind. Two of the burns were conducted when the average observed wind speed was 5-6kph and two of the burns were conducted at an average observed wind speed of 19kph.
Journal Article

A Linear Parameter Varying Combined with Divide-and-Conquer Approach to Thermal System Modeling of Battery Modules

2016-05-01
2015-01-9148
A linear parameter varying (LPV) reduced order model (ROM) is used to approximate the volume-averaged temperature of battery cells in one of the modules of the battery pack with varying mass flow rate of cooling fluid using uniform heat source as inputs. The ROM runs orders of magnitude faster than the original CFD model. To reduce the time it takes to generate training data, used in building LPV ROM, a divide-and-conquer approach is introduced. This is done by dividing the battery module into a series of mid-cell and end-cell units. A mid-cell unit is composed of a cooling channel sandwiched in between two half -cells. A half-cell has half as much heat capacity as a full-cell. An end-cell unit is composed of a cooling channel sandwiched in between full-cell and a half-cell. A mass flow rate distribution look-up-table is generated from a set of steady-state simulations obtained by running the full CFD model at different inlet manifold mass flow rate samples.
Journal Article

Impact of a Diesel High Pressure Common Rail Fuel System and Onboard Vehicle Storage on B20 Biodiesel Blend Stability

2016-04-05
2016-01-0885
Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.
Journal Article

Process Robustness of Laser Braze-Welded Al/Cu Connectors

2016-04-05
2016-01-1198
Laser welding of dissimilar metals such as Aluminum and Copper, which is required for Li-ion battery joining, is challenging due to the inevitable formation of the brittle and high electrical-resistant intermetallic compounds. Recent research has shown that by using a novel technology, called laser braze-welding, the Al-Cu intermetallics can be minimized to achieve superior mechanical and electrical joint performance. This paper investigates the robustness of the laser braze-welding process. Three product and process categories, i.e. choice of materials, joint configurations, and process conditions, are studied. It is found that in-process effects such as sample cleanness and shielding gas fluctuations have a minor influence on the process robustness. Furthermore, many pre-process effects, e.g. design changes such as multiple layers or anodized base material can be successfully welded by process adaption.
Technical Paper

Next Generation “Voltec” Charging System

2016-04-05
2016-01-1229
The electric vehicle on-board charger (OBC) is responsible for converting AC grid energy to DC energy to charge the battery pack. This paper describes the development of GM’s second generation OBC used in the 2016 Chevrolet Volt. The second generation OBC provides significant improvements in efficiency, size, and mass compared to the first generation. Reduced component count supports goals of improved reliability and lower cost. Complexity reduction of the hardware and diagnostic software was undertaken to eliminate potential failures.
Technical Paper

Application of CAEBAT Full Field Approach for a Liquid-Cooled Automotive Battery Pack

2016-04-05
2016-01-1217
The Computer-Aided Engineering of Automotive Batteries (CAEBAT) Phase 1 project is a U.S. Department of Energy-funded, multi-year project which is aimed at developing a complete CAE tool set for the automotive battery pack design. This paper reports the application of the full field approach of the CAEBAT which is developed by the General Motors-led industry team, for a 24-cell liquid-cooled prototype battery pack. It also summarizes the verification of the approach by comparing the simulation results with the measurement data. The simulation results using the Full Field Approach are found to have a very good agreement with the measurement data.
Technical Paper

The GM RWD PHEV Propulsion System for the Cadillac CT6 Luxury Sedan

2016-04-05
2016-01-1159
This paper describes the capabilities of a new two-motor plug-in hybrid-electric propulsion system developed for rear wheel drive. The PHEV system comprises a 2.0L turbocharged 4-cylinder direct-injected gasoline engine with the new hybrid transmission [1], a new traction power inverter module, a liquid-cooled lithium-ion battery pack, and on-board battery charger and 12V power converter module. The capability and features of the system components are described, and component performance and vehicle data are reported. The resulting propulsion system provides an excellent combination of electric-only driving, acceleration, and fuel economy.
Journal Article

Development of Hybrid-Electric Propulsion System for 2016 Chevrolet Malibu

2016-04-05
2016-01-1169
GM has developed an all-new gasoline-electric hybrid powertrain for the model year 2016 Chevrolet Malibu Hybrid vehicle, which was designed to achieve excellent fuel economy, performance, and drive quality. The powertrain shares the transmission architecture with the 2016 Chevrolet Volt extended range electric vehicle, but includes changes to optimize the system for engine driven charge sustaining operation in the range of conditions represented by the US EPA 5 cycle fuel economy tests. In this paper, we describe the Malibu Hybrid propulsion system features and components, including the battery pack, transaxle, electric motors and power electronics, engine, and thermal system. The modifications between the Volt and Malibu Hybrid propulsion systems are discussed and explained as resulting from the differences between the primarily electric and gasoline powered applications.
Journal Article

Issues with T50 and T90 as Match Criteria for Ethanol-Gasoline Blends

2014-11-01
2014-01-9080
Modification of gasoline blendstock composition in preparing ethanol-gasoline blends has a significant impact on vehicle exhaust emissions. In “splash” blending the blendstock is fixed, ethanol-gasoline blend compositions are clearly defined, and effects on emissions are relatively straightforward to interpret. In “match” blending the blendstock composition is modified for each ethanol-gasoline blend to match one or more fuel properties. The effects on emissions depend on which fuel properties are matched and what modifications are made, making trends difficult to interpret. The purpose of this paper is to illustrate that exclusive use of a match blending approach has fundamental flaws. For typical gasolines without ethanol, the distillation profile is a smooth, roughly linear relationship of temperature vs. percent fuel distilled.
Journal Article

Electrical Architecture Optimization and Selection - Cost Minimization via Wire Routing and Wire Sizing

2014-04-01
2014-01-0320
In this paper, we propose algorithms for cost minimization of physical wires that are used to connect electronic devices in the vehicle. The wiring cost is one of the most important drivers of electrical architecture selection. Our algorithms perform wire routing from a source device to a destination device through harnesses, by selecting the optimized wire size. In addition, we provide optimized splice allocation with limited constraints. Based on the algorithms, we develop a tool which is integrated into an off-the-shelf optimization and workflow system-level design tool. The algorithms and the tool provide an efficient, flexible, scalable, and maintainable approach for cost analysis and architecture selection.
Technical Paper

Review of 2013 U.S. Retail Biodiesel Blends Quality Survey

2014-04-01
2014-01-1379
Biodiesel is a domestic, renewable fuel for diesel engines and is made from agricultural co-products such as soybean oil, rapeseed oil, palm oil and other natural oils. Biodiesel is a cleaner burning fuel that is biodegradable and non-toxic compared to petroleum diesel. Biodiesel has become a major alternative fuel for automotive applications and is critical for lowering US dependence on foreign oil and attain energy security. Vehicle manufacturers have developed new vehicle and diesel engine technologies compatible with B6-B20 biodiesel blends meeting ASTM D7467 specifications. Field warranty and validation tests have shown significant concerns with use of poor quality biodiesel fuels including fuel system deposits, engine oil deterioration, and efficiency loss of the after treatment system. Maintaining good quality of biodiesel is critical for success as a commercial fuel.
Technical Paper

A Complete Li-Ion Battery Simulation Model

2014-04-01
2014-01-1842
Due to growing interest in hybrid and electric vehicles, li-ion battery modeling is receiving a lot of attention from designers and researchers. This paper presents a complete model for a li-ion battery pack. It starts from the Newman electrochemistry model to create the battery performance curves. Such information is then used for cell level battery equivalent circuit model (ECM) parameter identification. 28 cell ECMs are connected to create the module ECM. Four module ECMs are connected through a busbar model to create the pack ECM. The busbar model is a reduced order model (ROM) extracted from electromagnetic finite element analysis (FEA) results, taking into account the parasitic effects. Battery thermal performance is simulated first by computational fluid dynamics (CFD). Then, a thermal linear and time-invariant (LTI) ROM is created out of CFD solution. The thermal LTI ROM is then two-way coupled with the battery pack ECM to form a complete battery pack model.
Technical Paper

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors and Fuel Detergents on Powertrain Intake Valve Deposits

2014-04-01
2014-01-1383
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution systems used for transportation of fuel from refineries. They are also used to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of the types of inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and to show how variation in concentration of components of CIs and detergents impact intake valve deposit formation.
Journal Article

Application of POD plus LTI ROM to Battery Thermal Modeling: SISO Case

2014-04-01
2014-01-1843
The thermal behavior of a fluid-cooled battery can be modeled using computational fluid dynamics (CFD). Depending on the size and complexity of the battery module and the available computing hardware, the simulation can take days or weeks to run. This work introduces a reduced-order model that combines proper orthogonal decomposition, capturing the variation of the temperature field in the spatial domain, and linear time-invariant system techniques exploiting the linear relationship between the resulting proper orthogonal decomposition coefficients and the uniform heat source considered here as the input to the system. After completing an initial CFD run to establish the reduction, the reduced-order model runs much faster than the CFD model. This work will focus on thermal modeling of a single prismatic battery cell with one adjacent cooling channel. The extension to the multiple input multiple output case such as a battery module will be discussed in another paper.
Technical Paper

Simulating Rechargeable Lithium-Ion Battery Using VHDL-AMS

2012-04-16
2012-01-0665
A commonly used physics based electrochemisty model for a lithium-ion battery cell was first proposed by professor Newman in 1993. The model consists of a tightly coupled set of partial differential equations. Due to the tight coupling between the equations and the 2d implementation due to the particle modeling, and thus called pseudo-2d in literature, numerically obtaining a solution turns out to be challenging even for a lot of commercial softwares. In this paper, the VHDL-AMS language is used to solve the set of equations. VHDL-AMS allows the user to focus on the physical modeling rather than numerically solving the governing equations. In using VHDL-AMS, the user only needs to specify the governing equations after spatial discretization. A simulation environment, which supports VHDL-AMS, can then be used to solve the governing equations and also provides both pre- and post- processing tools.
Technical Paper

A State Space Thermal Model for HEV/EV Battery Modeling

2011-04-12
2011-01-1364
Battery thermal management for high power applications such as electrical/hybrid vehicles is crucial. Modeling is an indispensable tool to help engineers design better battery cooling systems. While Computational Fluid Dynamics (CFD) has been used quite successfully for battery thermal management, CFD models can be too large and too slow for repeated transient thermal analysis especially for a battery module or pack. An accurate but much smaller battery thermal model using a state space representation is proposed. The parameters in the state space model are extracted from CFD results. The state space model is then shown to provide identical results as those from CFD under transient power inputs. While a CFD model may take hours to run depending on the size of the problem, the corresponding state space model runs in seconds.
Technical Paper

Power Capability Testing of a Lithium-ion Battery Using Hardware in the Loop

2010-04-12
2010-01-1073
The energy storage system (ESS) is the key enabler to hybrid electric vehicles (HEVs) that offer improved fuel economy and reduced vehicle emissions. The power capability of a battery has significant impact on the fuel economy of HEVs. This paper presents the power capability testing of a lithium-ion battery with a conventional metal oxide cathode using the hardware in the loop (HIL) at a wide range of charge/discharge conditions and at different temperatures. The achieved test results provide critical data of battery power characteristics and effectively accelerate the development of battery power prediction algorithm.
Technical Paper

Signal Age Fault Detection in Distributed Embedded Automotive Systems

2010-04-12
2010-01-0205
More and more advanced features such as adaptive cruise control and collision avoidance are being adopted in road vehicles and these features are usually implemented as distributed systems across multiple ECU nodes that are connected by communication busses. In order to tolerate transient faults affecting a safety critical signal transmitted via bus in such distributed systems, the last used value or a default safe value for a safety critical signal is usually used among different ECU nodes on the bus for a pre-defined time interval before taking some other fault mitigation actions such as disabling a feature. Thus it becomes very important to monitor a signal's age and detect any signal age fault, where a signal age fault is defined as the use of an older or default signal value for longer than or equal to the pre-defined time interval.
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