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Technical Paper

Methane Conversion in Stoichiometric Natural Gas Engine Exhaust

2024-04-09
2024-01-2632
Stoichiometric natural gas (CNG) engines are an attractive solution for heavy-duty vehicles considering their inherent advantage in emitting lower CO2 emissions compared to their Diesel counterparts. Additionally, their aftertreatment system can be simpler and less costly as NOx reduction is handled simultaneously with CO/HC oxidation by a Three-Way Catalyst (TWC). The conversion of methane over a TWC shows a complex behavior, significantly different than non-methane hydrocarbons in stoichiometric gasoline engines. Its performance is maximized in a narrow A/F window and is strongly affected by the lean/rich cycling frequency. Experimental and simulation results indicate that lean-mode efficiency is governed by the palladium’s oxidation state while rich conversion is governed by the gradual formation of carbonaceous compounds which temporarily deactivate the active materials.
Technical Paper

The Potential of On-Board Data Monitoring for the Characterization of Real-World Vehicle Fuel and Energy Consumption and Emissions

2023-08-28
2023-24-0113
The upcoming Euro 7 regulation introduces the concept of continuous On-Board (emission) Monitoring (OBM), while On-Board Fuel/Energy Consumption Monitoring (OBFCM) is already an integral part of modern vehicles. The current work aims to assess whether on-board data could provide sufficient information to characterize real-world vehicle performance and emissions. Nine Euro 6d-ISC-FCM passenger cars were used, covering a wide range of powertrain technologies, from conventional gasoline and diesel to hybrid (HEV) and plug-in hybrid (PHEV) electric vehicles. Three vehicles were thoroughly tested in the laboratory and on the road, aiming at evaluating in detail the on-board data monitoring system. The evaluation concerned OBFCM device recordings of fuel consumed and distance travelled, as well as tailpipe NOx emissions and exhaust mass flow rate.
Technical Paper

On-Board Monitoring of Emissions in the Future Euro 7 Standard

2023-08-28
2023-24-0111
The proposed Euro 7 emission standard foresees that the emission behaviour of Euro 7 vehicles is monitored via an on-board monitoring (OBM) system. In Euro 7 vehicles, OBM systems will monitor the emissions of nitrogen oxides (NOX), ammonia (NH3) and particulate matter (PM) for every trip through a combination of measured and modelled data. Sensors employed to support on-board diagnostics (OBD) in current vehicles may be used to support OBM. According to the Euro 7 OBM concept presented in this paper, OBM will serve a dual purpose: the first is to warn the user of a vehicle about the need to perform repairs on the engine or the pollution control systems when these are needed. If these repairs are not performed in a timely manner, the OBM system will be able to ultimately prevent engine restart, akin to the existing low-reagent driver warning system in some compression ignition vehicles. The second purpose of OBM is to monitor the compliance of vehicle types with the emission limits.
Technical Paper

High Mileage Emission Deterioration Factors from Euro 6 Positive and Compression Ignition Vehicles

2022-08-30
2022-01-1028
The current European fleet of vehicles is ageing and lifetime mileages are rising proportionally. Consequently, a substantial fraction of the vehicle fleet is currently operating at mileages well beyond current durability legislation (≤ 160,000 km). Emissions inventories and models show substantial increases in emissions with increasing mileage, but knowledge of the effect of emissions control system deterioration at very high mileages is sparse. Emissions testing has been conducted on matched pairs (or more) of diesel and gasoline (and CNG) vehicles, of low and high mileage, supplementing the results with in-house data, in order to explore high mileage emission deterioration factors (DF). The study isolated, as far as possible, the effect of emissions deterioration with mileage, by using nominally identical vehicle models and controlling other variables.
Journal Article

A European Regulatory Perspective towards a Euro 7 Proposal

2022-06-14
2022-37-0032
The implementation of emission standards has brought significant reductions in vehicle emissions in the EU, but road transport is still a major source of air pollution. Future emission standards will aim at making road vehicles as clean as possible under a wide range of driving conditions and throughout their complete lifetime. The current paper presents the methodology followed by the Consortium for ultra LOw Vehicle Emissions (CLOVE) to support the preparation of the Euro 7 proposal. As a first step, the emission performance of the latest-technology vehicles under various driving conditions was evaluated. Towards this direction, an emissions database was developed, containing data from a wide range of tests, both within and beyond the current RDE boundaries.
Journal Article

Measuring Automotive Exhaust Particles Down to 10 nm

2020-09-15
2020-01-2209
The latest generation of internal combustion engines may emit significant levels of sub-23 nm particles. The main objective of the Horizon 2020 “DownToTen” project was to develop a robust methodology and provide policy recommendations towards the particle number (PN) emissions measurements in the sub-23 nm region. In order to achieve this target, a new portable exhaust particle sampling system (PEPS) was developed, being capable of measuring exhaust particles down to at least 10 nm under real-world conditions. The main design target was to build a system that is compatible with current PMP requirements and is characterized by minimized losses in the sub-23 nm region, high robustness against artefacts and high flexibility in terms of different PN modes investigation, i.e. non-volatile, volatile and secondary particles.
Technical Paper

A Methodology for Monitoring On-Road CO2 Emissions Compliance in Passenger Vehicles

2020-06-30
2020-37-0034
The European Union road transport CO2 emissions regulation foresees mandatory targets for passenger vehicles. However, several studies have shown that there is a divergence between official and real-world values that could range up to 40% compared to the NEDC reference value. The introduction of the Worldwide Harmonized Test Protocol (WLTP) limited this divergence, but it is uncertain whether it can adequately address the problem, particularly considering future evolutions of vehicle technology. In order to address this issue, the recent EU CO2-standards regulation introduces the monitoring of on-road fuel consumption and subsequently CO2 emissions by utilizing On-Board Fuel Consumption Meters (OBFCM). In the near future, all vehicles should provide instantaneous and lifetime-cumulative fuel consumption signals at the diagnostics port. Currently, the fuel consumption signal is not always available.
Technical Paper

A Novel 1D Co-Simulation Framework for the Prediction of Tailpipe Emissions under Different IC Engine Operating Conditions

2019-09-09
2019-24-0147
The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.
Technical Paper

Emissions Optimization Potential of a Diesel Engine Running on HVO: A Combined Experimental and Simulation Investigation

2019-09-09
2019-24-0039
The present work investigates a number of recalibration possibilities of a common rail turbocharged diesel engine, aiming at the improvement of its emissions performance and fuel consumption (FC), with Hydrotreated Vegetable Oil (HVO). Initially, steady-state experimental data with nominal engine settings revealed HVO benefits as a drop-in fuel. Under these conditions, pure HVO results in lower engine-out PM emissions, lower CO2 emissions, and lower mass-based FC, while the respective NOx emissions present a mixed trend. In mid loads and speeds NOx emissions of HVO are lower while at higher loads and speeds are slightly higher compared to conventional diesel. At a second step, a combustion model was developed, in order to investigate the possible re-adjustments of IT (Injection Timing) and EGR (Exhaust Gas Recirculation) settings in order to exploit HVO’s properties for further reduction of emissions and FC.
Technical Paper

Description of a Novel Concentric Rotary Engine

2018-04-03
2018-01-0365
The present work presents the concept of a new rotary engine, and provides first investigations for its implementation in the energy sector. The main focus of this work is to provide a theoretical description of the engine and its differences from the state-of-the-art technologies. Its innovative principle consists of concentric operation, with two pistons of different rotation radius and the addition of a third intermediate chamber between the compression and combustion chamber. A description of the engine’s physical model is provided, followed by an analysis of the selected specific geometrical features. Additionally, a thermodynamic analysis clarifies the operational advantage compared to the existing cycles and, finally, a numerical investigation on the engine’s bulk performance is provided to quantify the anticipated results of the theoretical analysis.
Journal Article

A New Miniaturized Sensor for Ultra-Fast On-Board Soot Concentration Measurements

2017-03-28
2017-01-1008
In this article we present a design of a new miniaturized sensor with the capacity to measure exhaust particle concentrations on board vehicles and engines. The sensor is characterized by ultra-fast response time, high sensitivity, and a wide dynamic range. In addition, the physical dimensions of the sensor enable its placement along the exhaust line. The concentration response and temporal performance of a prototype sensor are discussed and characterized with aerosol laboratory test measurements. The sensor performance was also tested with actual engine exhaust in both chassis and engine dynamometer measurements. These measurements demonstrate that the sensor has the potential to meet and even exceed any requirements around the world in terms of on-board diagnostic (OBD) sensitivity and frequency of monitoring.
Technical Paper

Development of a Template Model and Simulation Approach for Quantifying the Effect of WLTP Introduction on Light Duty Vehicle CO2 Emissions and Fuel Consumption

2015-09-06
2015-24-2391
The paper describes the development of a modelling approach to simulate the effect of the new Worldwide harmonized Light duty Test Procedure (WLTP) on the certified CO2 emissions of light duty vehicles. The European fleet has been divided into a number of segments based on specific vehicle characteristics and technologies. Representative vehicles for each segment were selected. A test protocol has been developed in order to generate the necessary data for the validation of the vehicle simulation models. In order to minimize the sources of uncertainty and the effects of flexibilities, a reference “template model” was developed to be used in the study. Subsequently, vehicle models were developed using AVL Cruise simulation software based on the above mentioned template model. The various components and sub-modules of the models, as well as their input parameters, have been defined with the support of the respective OEMs.
Technical Paper

Experimental Investigation of Cyclic Variability on Combustion and Emissions of a High-Speed SI Engine

2015-04-14
2015-01-0742
Cyclic combustion variability (CCV) is an undesirable characteristic of spark ignition (SI) engines, and originates from variations in gas motion and turbulence, as well as from differences in mixture composition and homogeneity in each cycle. In this work, the cycle to cycle variability on combustion and emissions is experimentally investigated on a high-speed, port fuel injected, spark ignition engine. Fast response analyzers were placed at the exhaust manifold, directly downstream of the exhaust valve of one cylinder, for the determination of the cycle-resolved carbon monoxide (CO) and nitric oxide (NO) emissions. A piezoelectric transducer, integrated in the spark-plug, was also used for cylinder pressure measurement. The impact of engine operating parameters, namely engine speed, load, equivalence ratio and ignition timing on combustion and emissions variability, was evaluated.
Technical Paper

Evaluating Particulate Emissions from a Flexible Fuel Vehicle with Direct Injection when Operated on Ethanol and Iso-butanol Blends

2014-10-13
2014-01-2768
The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.
Journal Article

Impact of FAME Content on the Regeneration Frequency of Diesel Particulate Filters (DPFs)

2014-04-01
2014-01-1605
Modern diesel vehicles utilize two technologies, one fuel based and one hardware based, that have been motivated by recent European legislation: diesel fuel blends containing Fatty Acid Methyl Esters (FAME) and Diesel Particulate Filters (DPF). Oxygenates, like FAME, are known to reduce PM formation in the combustion chamber and reduce the amount of soot that must be filtered from the engine exhaust by the DPF. This effect is also expected to lengthen the time between DPF regenerations and reduce the fuel consumption penalty that is associated with soot loading and regeneration. This study investigated the effect of FAME content, up to 50% v/v (B50), in diesel fuel on the DPF regeneration frequency by repeatedly running a Euro 5 multi-cylinder bench engine over the European regulatory cycle (NEDC) until a specified soot loading limit had been reached.
Technical Paper

SCR System Optimization and Control Supported by Simulation Tools

2013-04-08
2013-01-1075
The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.
Technical Paper

The Effect of a Particle Oxidation Catalyst (POC®) on Particle Emissions of a GDI Car during Transient Engine Operation

2013-04-08
2013-01-0839
Particle emissions have been generally associated to diesel engines. However, spark-ignition direct injection (SI-DI) engines have been observed to produce notable amounts of particulate matter as well. The upcoming Euro 6 legislation for passenger cars (effective in 2014, stricter limit in 2017) will further limit the particulate emissions from SI engines by introducing a particle number emission (PN) limit, and it is not probable that the SI-DI engines are able to meet this limit without resorting to additional aftertreatment systems. In this study, the solid particle emissions of a SI-DI passenger car with and without an installed Particle Oxidation Catalyst (POC®) were studied over the New European Driving Cycle (NEDC) on a chassis dynamometer and over real transient acceleration situations on road. It was observed that a considerable portion of particle number emissions occurred during the transient acceleration phases of the cycle.
Technical Paper

Applications of Multi-layer Catalyst Modeling in deNOx and DPF Systems

2010-04-12
2010-01-0893
Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.
Technical Paper

Catalytic Activity in the Regeneration of the Ceramic Diesel Particulate Trap

1992-02-01
920362
The rare occurrence during city driving of the exhaust temperature levels required for ceramic trap regeneration without catalytic aid, seems to be the main reason of delay in wide application of the trap. The use of catalysts seems to be more or less necessary. Study of the catalytic activity during trap regeneration had not been very effective so far. This holds equally true for the case of catalyzed trap as for the case of catalytic fuel additives. The lack of a satisfactory theory for the explanation and prediction of catalytic activity, directed international research and development towards the quest of the optimum catalyst, which could support a very simple and low-cost regeneration system. The new approach to the explanation of catalytic activity presented in this paper, denies the above assumption.
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