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Incomplete-combustion and misfire are the hurdles in internal combustion engines to run on ultra-lean mixture, whereas high thermal efficiency has been achieved at lean mixture. The burning characteristics of n-heptane with 0% and 30% hydrogen additions were studied at 393K-453K and 100kPa-300kPa up to near lean burn limits, λ=0.8-2.0. The flame appeared in spherical shape only by 37-mJ ignition energy (IE) at λ=0.8-1.5, while further lean mixture, ≥1.6, could be ignited only by 3000-mJ with the distorted flame shape. The flame buoyed in the mixture when burning velocity calculated by kinetic mechanism was equal or less than 19.83 cm/s at the initial conditions of λ=1.8, 393K and 100kPa. The thermal instability under impact of initial pressure and temperature was higher at lean mixture than at stoichiometric mixture.