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Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.

Urea SCR technology is the most promising technique to reduce NOx emissions from heavy duty diesel engines. 32.5wt% aqueous urea solution is widely used as ammonia storage species for the urea SCR process. The thermolysis and hydrolysis of urea produces reducing agent ammonia and reduces NOx emissions to nitrogen and water. However, the application of urea SCR technology has many challenges at low temperature conditions, such as deposits formation in the exhaust pipe, lack deNOx performance at low temperature and freezing below -12°C. For preventing deposits formation, aqueous urea solution is hardly injected into exhaust gas stream at temperature below 200°C. The aqueous urea solution used as reducing agent precursor is the main obstacle for achieving high deNOx performances at low temperature conditions. This paper presents a solid SCR technology for control NOx emissions from heavy duty diesel engines.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement.

It is found that biodiesel has a great potential to reduce the nitrogen oxides (NOx) and soot emissions simultaneously in low temperature combustion (LTC) mode. The objective of this study is to investigate the combustion and emission characteristics of 20% biodiesel blend diesel fuel (B20) under several exhaust gas recirculation (EGR) conditions for LTC application. An experimental investigation of B20 was conducted on a four-stroke common rail direct injection diesel engine at 2000rpm and 25% load condition. The EGR ratio was adjusted from 10% to 66%, and the injection pressure was tuned from 100MPa to 140MPa. The result showed that B20 generated less soot emission than conventional diesel with increasing EGR ratio, especially when the EGR ratio was beyond 30%. Soot emission increased with increasing EGR ratio up to 50% EGR, after which there is a steep decrease in particular matter (PM).

NOx are the only harmful emissions of hydrogen internal combustion engine. EGR is one of the effective methods to reduce NOx. The traditional EGR is not suitable for hydrogen internal combustion engine. Therefore, the study of influence of hot EGR on hydrogen internal combustion engine is important. A 2.0L hydrogen internal combustion engine with hot EGR system model is employed to optimize the diameter and position of hot EGR based on a simulation analysis. The result shows that both of the combustion temperature and NOx increase as EGR increases due to the rise of intake temperature for low load condition, for heavy load, with the increase of EGR rate, NOx emissions decreases slightly before the mixture equivalence ratio comes to 1and then dropped significantly after the mixture equivalence ratio greater than 1. Unburned hydrogen in TWC has the effect of reducing NOx after catalysts decrease largely.

The NOx conversion efficiency of vanadium-based SCR catalyst is lower under low temperature. Utilizing an exhaust analyzer, the effects of electrically heated catalyst on the performance of vanadium-based SCR catalyst under low temperature was studied on the engine test bench. The inlet temperature of SCR catalyst without the electrically heated catalyst were in the range of 150°C∼270°C under various steady engine modes, and the NSR (Normalized Stoichiometric Ratio) was set as 0.4,0.6,0.8,1.0. The results showed that under the space velocity of 20000h−1, with the application of the electrically heated catalyst, the inlet temperature of SCR increased about 19.9°C on average and the NOx conversion efficiency improved about 8.0%. The NOx conversion efficiency increased 1.7%∼8.6% at the temperatures of 150°C∼174°C, and 1.0%∼15.9% at the temperatures of 186°C∼270°C.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).

U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

A new diesel engine, called the 6.7L Power Stroke® V-8 Turbo Diesel and code named "Scorpion" was designed and developed by Ford Motor Company for the full-size pickup truck and light commercial vehicle markets. A high pressure Exhaust Gas Recirculation (EGR) layout in combination with a Variable Geometry Turbine (VGT) is used to deliver cooled EGR for in-cylinder NOx reduction. The cylinder-to-cylinder variation of EGR and swirl ratio is tightly controlled by the careful design of the EGR mixer and intake system flow path to reduce variability of cylinder-out PM and NOx emissions. 3D-CFD studies were used to quickly screen several EGR mixer designs based on mixing efficiency and pressure drop considerations. To optimize the intake system, 1D-3D co-simulation methodology with AVL-FIRE and AVL-BOOST has been used to assess the cylinder-to-cylinder EGR distribution and dynamic swirl.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

The objective of this research project was to compare B20 (20% biodiesel fuel) and ultra-low-sulfur (ULSD) diesel-fueled buses in terms of fuel economy, vehicle maintenance, engine performance, component wear, and lube oil performance. We examined 15 model year (MY) 2002 Gillig 40-foot transit buses equipped with MY 2002 Cummins ISM engines. The engines met 2004 U.S. emission standards and employed exhaust gas recirculation (EGR). For 18 months, eight of these buses operated exclusively on B20 and seven operated exclusively on ULSD. The B20 and ULSD study groups operated from different depots of the St. Louis (Missouri) Metro, with bus routes matched for duty cycle parity. The B20- and ULSD-fueled buses exhibited comparable fuel economy, reliability (as measured by miles between road calls), and total maintenance costs. Engine and fuel system maintenance costs were also the same for the two groups after correcting for the higher average mileage of the B20 group.

Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

For the application of advanced clean combustion technologies, such as diesel HCCI/LTC, a compressor with high efficiency over a broad operation range is required to supply a high amount of EGR with minimum pumping loss. A compressor with high pitch of vaneless diffuser would substantially improve the flow range of the compressor, but it is at the cost of compressor efficiency, especially at low mass flow area where most of the city driving cycles resides. In present study, an ultra low solidity compressor vane diffuser was numerically investigated. It is well known that the flow leaving the impeller is highly distorted, unsteady and turbulent, especially at relative low mass flow rate and near the shroud side of the compressor. A conventional vaned diffuser with high stagger angle could help to improve the performance of the compressor at low end. However, adding diffuser vane to a compressor typically restricts the flow range at high end.

Testing to investigate biodiesel's impact on the performance of a zeolite-based selective catalytic reduction (SCR) system was conducted. The tests employed a 2004 compliant Cummins ISB with common rail fuel injection, EGR, and variable geometry turbo. This 5.9L, 300HP engine was retrofitted with a Johnson-Matthey DPF + SCR (SCRT™) system. Testing was conducted over eight steady-state engine operating modes which provided a wide range of exhaust temperature and exhaust chemistry conditions. Fuels tested were a 2007 certification quality ultra-low sulfur diesel (ULSD), as well as a soy derived biodiesel in a B20 blend. B20 produced slightly lower catalyst temperatures and higher NO2:NOx ratios relative to ULSD, but no measureable difference in the overall NOx conversion over the SCR system. The dominant variable influencing SCR performance is the catalyst space velocity, which is unchanged with the use of B20.

In order to achieve simultaneous removal of particulate matters (PM) and NOX in diesel exhaust, a new kind of aftertreatment prototype has been developed. The prototype combined effects of static, cyclone, non-thermal plasma and hydrocarbon selective catalytic reduction. Experiments have been carried out with standard gases simulating diesel exhaust. Physical and chemical effects that took place in the prototype are as follows: the collection of PM by electrostatic-cyclone system, the oxidative combustion of PM, the selective catalytic reduction of NOX, and the reaction between PM and NOX. The effect of non-thermal plasma makes the density of NO decrease and that of NO2 increase, whereas, the amount of NOX remains the same. Employing catalyst coupled with non-thermal plasma debase the temperature by about 50◻, there the peak value of transform rate appears.