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SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

It is generally accepted that knocking combustion influences the heat transfer in SI engines. However, the effects of heat transfer on the onset of knock is still not clear due to lack of experimental data of the thermal boundary layer close to the combustion chamber wall. This paper presents measurements of the temperature in the thermal boundary layer under knocking and non-knocking conditions. The temperature was measured using dual-broadband rotational Coherent anti-Stokes Raman Spectroscopy (CARS). Simultaneous time-resolved measurements of the cylinder pressure, at three different locations, and the heat flux to the wall were carried out. Optical access to the region near the combustion chamber wall was achieved by using a horseshoe-shaped combustion chamber with windows installed in the rectangular part of the chamber. This arrangement made CARS temperature measurements close to the wall possible and results are presented in the range 0.1-5 mm from the wall.

Eight different cylinder pressure trace based knock detection methods are compared using two reference cycles of different time-frequency content, reflecting single blast and developing blast, and a test population of 300 knocking cycles. It is shown that the choice of the pass window used for the pressure data has no significant effect on the results of the different methods, except for the KI20. In contrast to other authors, no sudden step in the knock characteristics is expected; first, because the data investigated contain only knocking cycles, and second, because a smooth transition between normal combustion and knock is expected, according to recent knock theory. It is not only the correlation coefficient, but also the Kendall coefficient of concordance, that is used to investigate the differences between the knock classification methods.

Cycle-resolved end-gas temperatures were measured using dual-broadband rotational CARS in a single-cylinder spark-ignition engine. Simultaneous cylinder pressure measurements were used as an indicator for knock and as input data to numerical calculations. The chemical processes in the end-gas have been analysed with a detailed kinetic mechanism for mixtures of iso-octane and n-heptane at different Research Octane Numbers (RON'S). The end-gas is modelled as a homogeneous reactor that is compressed or expanded by the piston movement and the flame propagation in the cylinder. The calculated temperatures are in agreement with the temperatures evaluated from CARS measurements. It is found that calculations with different RON'S of the fuel lead to different levels of radical concentrations in the end-gas. The apperance of the first stage of the autoignition process is marginally influenced by the RON, while the ignition delay of the second stage is increased with increasing RON.

The wavelet transform is used in the analysis of the cylinder pressure trace and the ionic current trace of a knocking, single-cylinder, spark ignition engine. Using the wavelet transform offers a significant reduction of mathematical operations when compared with traditional filtering techniques based on the Fourier transform. It is shown that conventional knock analysis in terms of average energy in the time domain (AETD), corresponding to the signal's energy content, and maximum amplitude in the time domain (MATD), corresponding to the maximum amplitude of the bandpass filtered signal, can be applied to both the reconstructed filtered cylinder pressure and the wavelet coefficients. The use of the filter coefficients makes possible a significant additional reduction in calculation effort in comparison with filters based on the windowed Fourier transform.