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Thermal barrier coatings (TBCs) have long been studied as a potential pathway to achieve higher thermal efficiency in spark ignition engines. Researchers have studied coatings with different thicknesses and thermophysical properties to counteract the volumetric efficiency penalty associated with TBCs in spark ignition. To achieve an efficiency benefit with minimal charge heating during the intake stroke, low thermal inertia coatings characterized by their larger temperature swings are required. To study the impact of low thermal inertia coatings in spark ignition, coatings were applied to the cylinder head, piston crown, intake and exhaust valve faces, and intake and exhaust valve backsides. Tier III EEE E10 certification gasoline was used to keep the experiments relevant to the present on-road vehicles. This study is aimed at analyzing durability of the coatings as well as efficiency and emissions improvements.

Spark ignition knock is highly sensitive to changes in intake air temperature. Hot surface temperatures due to ceramic thermal barrier coatings increase knock propensity by elevating the incoming air temperature, thus mitigating the positive impacts of low heat transfer losses by requiring spark retard to avoid knock. Low thermal inertia coatings (i.e. Temperature swing coatings) have been proposed as a means of reducing or eliminating the open cycle charge heating penalty of traditional TBCs through a combination of low thermal conductivity and low volumetric heat capacity materials. However, in order to achieve a meaningful gain in efficiency, a significant fraction of the combustion chamber must be coated. In this study, a coated piston and intake and exhaust valves with coated combustion faces, backsides, and stems are installed in a single-cylinder research engine to evaluate the effect of high coated fractions of the combustion chamber in a knock-sensitive architecture.

In-cylinder surface temperature is of heightened importance for Homogeneous Charge Compression Ignition (HCCI) combustion since the combustion mechanism is thermo-kinetically driven. Thermal Barrier Coatings (TBCs) selectively manipulate the in-cylinder surface temperature, providing an avenue for improving thermal and combustion efficiency. A surface temperature swing during combustion/expansion reduces heat transfer losses, leading to more complete combustion and reduced emissions. At the same time, achieving a highly dynamic response sidesteps preheating of charge during intake and eliminates the volumetric efficiency penalty. The magnitude and temporal profile of the dynamic surface temperature swing is affected by the TBC material properties, thickness, morphology, engine speed, and heat flux from the combustion process. This study follows prior work of authors with Yttria Stabilized Zirconia, which systematically engineered coatings for HCCI combustion.