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Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

This paper discusses a method developed to counter the variability of media interferences for the measurement of aldehydes and ketones in automotive exhaust. Dinitrophenylhydrazine (DNPH) Derivatization Methodology for the collection of aldehyde and ketone compounds in vehicle exhaust has been in use for over thirty years. These carbonyl compounds are captured by passing diluted exhaust gas through a sample medium containing DNPH. The sampling medium can take the form of DNPH dispersed on a solid sorbent or as a DNPH solution in a solvent such as acetonitrile. Carbonyl compounds react readily to form DNPH derivatives which are stable and which absorb ultra-violet (UV) light, facilitating quantitative measurement. However, when the procedure was developed, emissions rates from vehicles were much higher than the current (2010) emissions levels.

Research has shown that there are many factors that affect the long-term performance of nitrogen oxides (NOx) control systems used in diesel engine applications. However, if the NOx emissions can be accurately monitored, it might be possible to restore performance by making adjustments to the control systems. This paper presents results from a study that tested the durability of 25 NOx sensors exposed to heavy-duty diesel exhaust for 6,000 hours. The study, conducted by the Advanced Petroleum-Based Fuels - Diesel Emission Controls (APBF-DEC) project, tested the sensors at various locations in the exhaust stream.

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.

In the United States, most school buses are powered by diesel engines. Some have advocated replacing diesel school buses with natural gas school buses, but little research has been conducted to understand the emissions from school bus engines. This work provides a detailed characterization of exhaust emissions from school buses using a diesel engine meeting 1998 emission standards, a low emitting diesel engine with an advanced engine calibration and a catalyzed particulate filter, and a natural gas engine without catalyst. All three bus configurations were tested over the same cycle, test weight, and road load settings. Twenty-one of the 41 “toxic air contaminants” (TACs) listed by the California Air Resources Board (CARB) as being present in diesel exhaust were not found in the exhaust of any of the three bus configurations, even though special sampling provisions were utilized to detect low levels of TACs.

The emission performance of a 1997 Mercedes OM 366 LA medium heavy-duty diesel engine and a 1998 Detroit Diesel Corporation (DDC) Series 60 heavy heavy-duty diesel engine was investigated using the US EPA hot-start transient cycle using different candidate diesel fuels developed by the Empresa Nacional Del Petroleo (ENAP), the state-owned oil production and refining company of Chile. The aim of the work was to identify a clean diesel fuel that can be readily produced and reduces emissions from diesel engines in Chile, particularly in Santiago Metropolitan Area where air pollution is a serious problem. Using a Mercedes engine of the type found in Chile, several candidate fuel formulations were tested in both the Mercedes and DDC engines to identify leading candidate formulations that would effectively reduce emission in both traditional and modern technology engines.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. As part of Tier 1 compliance requirements for EPA's Fuel Registration Program, a detailed chemical characterization of the transient exhaust emissions from three modern diesel engines was performed, both with and without an oxidation catalyst. This characterization included several forms of hydrocarbon speciation, as well as measurement of aldehydes, ketones, and alcohols. In addition, both particle-phase and semivolatile-phase PAH and nitro-PAH compounds were measured. Unregulated emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. Transient exhaust emissions from three modern diesel engines were measured during this study, both with and without an oxidation catalyst. Emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel. Regulated emissions and performance data are presented in this paper, while the results of a detailed chemical characterization of exhaust emissions are presented in a companion paper. The use of biodiesel resulted in lower emissions of unburned hydrocarbons, carbon monoxide, and particulate matter, with some increase in emissions of oxides of nitrogen on some engines.

The United States Environmental Protection Agency (EPA) has initiated Phase I of a regulatory program to control exhaust emissions of nonroad diesel engines over 37 kW. Central to any emissions regulation is the test procedure, which must include an appropriate test cycle. Based on actual in-use speed and estimated torque data collected from an agricultural tractor, a backhoe-loader, and a crawler tractor, three duty cycles were developed. Using an iterative process, comparison of chi-square statistical data was used to identify representative microtrips, segments of engine operation gathered during performance of selected activities. Representative microtrips for specific activities for a particular nonroad application were “strung” together to make up a test cycle. Before accepting the test cycle, data for the cycle was compared to statistical data used to characterize the raw data in an effort to validate that the cycle was representative of the raw data.

Over twenty prototype hybrid buses and other commercial vehicles are currently being completed and deployed. These vehicles are primarily “series” hybrid vehicles which use electric motors for primary traction while internal combustion engines, or high-speed turbine engines connected to generators, supply some portion of the electric propulsion and battery recharge energy. Hybrid-electric vehicles have an electric energy storage system on board that influences the operation of the heat engine. The storage system design and level affect the vehicle emissions, electricity consumption, and fuel economy. Existing heavy-duty emissions test procedures require that the engine be tested over a transient cycle before it can be used in vehicles (over 26,000 lbs GVW). This paper describes current test procedures for assessing engine and vehicle emissions, and proposes techniques for evaluating engines used with hybrid-electric vehicle propulsion systems.

A Coordinating Research Council sponsored test program was conducted to determine the effects of diesel fuel properties on emissions from two heavy-duty diesel engines designed to meet EPA emission requirements for 1994. Results for a prototype 1994 DDC Series 60 were reported in SAE Paper 941020. This paper reports the results from a prototype 1994 Navistar DTA-466 engine equipped with an exhaust catalyst. A set of ten fuels having specific variations in cetane number, aromatics, and oxygen were used to study effects of these fuel properties on emissions. Using glycol diether compounds as an oxygenated additive, selected diesel fuels were treated to obtain 2 and 4 mass percent oxygen. Cetane number was increased for selected fuels using a cetane improver. Emissions were measured during transient FTP operation of the Navistar engine tuned for a nominal 5 g/hp-hr NOx, then repeated using a 4 g/hp-hr NOx calibration.

As stringent emission regulations further constrain engine manufacturers by tightening both NOx and particulate emission limits, a knowledge of fuel effects becomes more important than ever. Among the fuel properties that affect heavy-duty diesel engine emissions, cetane number can be very important. Part of the CRC-APRAC VE-10 Project was developed to quantify the effects of cetane number on NOx and other emissions from a prototype 1998 Detroit Diesel Series 60. Three fuels with different natural cetane number (41, 45, 52) were treated with several levels and types of cetane improvers to study a range of cetane number from 40 to 60. Statistical analysis was used to define how regulated emissions from this prototype 1998 engine decreased with chemically-induced cetane number increase. Variation of HC, CO, NOx, and PM were modeled using a combination of a fuel's naturally-occurring cetane number and its total cetane number obtained with cetane improver.

Concern over emissions from heavy-duty diesel engines at high altitudes prompted an investigation into the effects of increasing altitude on gaseous and particulate emissions. On behalf of the Engine Manufacturers Association, emissions from a Detroit Diesel Corporation Series 60 at local test conditions (barometer 98.9 kPa), and two simulated altitudes, Denver (82.6 kPa) and Mexico City (77.9 kPa) were examined using a special altitude simulation CVS. Transient torque output and full load steady-state torque, for this turbocharged aftercooled engine, decreased slightly with increasing altitude. Although, the DDC Series 60 compensates for variation in barometer, transient composite emissions of HC, CO, CO2, smoke, and particulate matter generally increased with increasing altitude for both transient and steady-state operation.

Several studies have investigated the effects of diesel fuel properties on heavy-duty engine emissions. The objective of this CRC-sponsored test program was to determine the effects of oxygenated diesel fuel, and to further investigate the effects of cetane number and aromatic content on emissions from a heavy-duty engine set to obtain transient NOx emissions below 5 and then 4 g/hp-hr. A fuel set was developed with controlled variations in cetane number, aromatics, and oxygen to superette their effects on emissions. Ignition improver was used to increase cetane number of several fuels. Oxygenated diesel fuel was achieved by adding a “glyme” compound to selected fuels to obtain 2 and 4 mass percent oxygen concentrations. With these fuels, emissions were measured over the EPA transient FTP using a prototype 1994 DDC Series 60 tuned for 5 and then 4 g/hp-hr NOx. No exhaust aftertreatment device was used on this engine.

The use of compressed natural gas as an alternative to conventional fuels has received a great deal of attention as a strategy for reducing air pollution from motor vehicles. In many cases, regulatory action has been taken to displace diesel fuel with natural gas in truck and bus applications. Emissions results of heavy-duty transient FTP testing of two Cummins L10-240G natural gas engines are presented. Regulated emissions of non-methane hydrocarbons, total hydrocarbons, CO, NOx, and particulate were characterized, along with emissions of formaldehyde. The effects of air/fuel ratio adjustments on these emissions were explored, as well as the effectiveness of catalytic aftertreatment in reducing exhaust emissions. Compared to typical heavy-duty diesel engine emissions, CNG-fueled engines using exhaust aftertreatment have great potential for meeting future exhaust emission standards, although in-use durability is unproven.

Emissions from existing diesel-powered urban buses are increasingly scrutinized as local, state, and federal governments require enforcement of more stringent emission regulations and expectations. Currently, visual observation of high smoke levels from diesel-powered equipment is a popular indicator of potential emission problems requiring tune-up or engine maintenance. It is important that bus inspection and maintenance (I/M) operations have a quality control “test” to check engine emissions or diagnose the engine state-of-tune before or after maintenance. Ideally, the “emission test” would be correlated to EPA transient emissions standards, be of short duration, and be compatible with garage procedures and equipment. In support of developing a useful “short-test,” equipment was designed to collect samples of raw exhaust over a short time period for gaseous and particulate emissions.