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The Particle Number–Portable Emission Measurement System (PN-PEMS) came into force with Euro VI Phase E regulations starting January 1, 2022. However, positive ignition (PI) engines must comply from January 1, 2024. The delay was due to the unavailability of the PN-PEMS system that could withstand high concentrations of water typically present in the tailpipe (TP) of CNG vehicles, which was detrimental to the PN-PEMS systems. Thus, this study was designed to evaluate the condensation particle counter (CPC)-based PN-PEMS measurement capabilities that was upgraded to endure high concentration of water. The PN-PEMS measurement of solid particle number (SPN23) greater than 23 nm was compared against the laboratory-grade PN systems in four phases. Each phase differs based upon the PN-PEMS and PN system location and measurements were made from three different CNG engines. In the first phase, systems measured the diluted exhaust through constant volume sampler (CVS) tunnel.

Ammonia is one of the carbon-free alternatives considered for power generation and transportation sectors. But ammonia’s lower flame speed, higher ignition energy, and higher nitrogen oxides emissions are challenges in practical applications such as internal combustion engines. As a result, modifications in engine design and control and the use of a secondary fuel to initiate combustion such as natural gas are considered for ammonia-fueled engines. The higher-octane number of methane (the main component in natural gas) and ammonia allows for higher compression ratios, which in turn would increase the engine's thermal efficiency. One simple approach to initiate and control combustion for a high-octane fuel at higher compression ratios is to use a spark plug. This study experimentally investigated the operation of a heavy-duty compression ignition engine converted to spark ignition and ammonia-methane blends.

Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.

The combustion process in spark-ignition engines can vary considerably cycle by cycle, which may result in unstable engine operation. The phenomena amplify in natural gas (NG) spark-ignition (SI) engines due to the lower NG laminar flame speed compared to gasoline, and more so under lean burn conditions. The main goal of this study was to investigate the main sources and the characteristics of the cycle-by-cycle variation in heavy-duty compression ignition (CI) engines converted to NG SI operation. The experiments were conducted in a single-cylinder optically-accessible CI engine with a flat bowl-in piston that was converted to NG SI. The engine was operated at medium load under lean operating conditions, using pure methane as a natural gas surrogate. The CI to SI conversion was made through the addition of a low-pressure NG injector in the intake manifold and of a NG spark plug in place of the diesel injector.

Machine learning models were shown to provide faster results but with similar accuracy to multidimensional computational fluid dynamics or in-depth experiments. This study used a support-vector machine (SVM), a set of related supervised learning methods, to predict the dynamic performance (i.e., engine power and torque) of a heavy-duty natural gas spark ignition engine. The single-cylinder four-stroke test engine was fueled with methane. The engine was operated at different spark timings, mixture equivalence ratios, and engine speeds to provide the data for training and testing the proposed SVM. The results indicated that the performance and accuracy of the built regression model were satisfactory, with correlation coefficient quantities all larger than 0.95 and root-mean-square errors close to zero for both training and validation datasets.

The measurement of solid particles down to 10 nm is being incorporated into global technical regulations (GTR). This study explores the measurement of solid particles below 23 nm by using both current and proposed particle number (PN) systems having different volatile particle remover (VPR) methodologies and condensation particle counter (CPC) cutoff diameters. The measurements were conducted in dynamometer test cells using ten diesel and eight natural gas (NG) engines that were going under development for a variety of global emission standards. The PN systems measured solid PN from more than 700 test cycles. The results from the preliminary campaign showed a 10-280% increase in PN emissions with the inclusion of particles below 23 nm.

The present study examines the impact of using low thermal mass (LTM) turbine housing designs on the transient characteristics of the turbine outlet temperature for a light-duty diesel standard certification cycle (FTP75). For a controlled exhaust flow, the turbine outlet temperature will directly determine the impact on an aftertreatment system warm-up from a cold state, typical of engine-off and engine idling conditions. The performance of the aftertreatment system such as a Selective Catalytic Reduction (SCR) system is highly dependent on how quickly it warms up to its desirable temperature to be able to convert the harmful oxides of Nitrogen (NOx) to gaseous Nitrogen. Previous works have focused on mostly insulating the exhaust manifold and turbine housing to conserve the heat going into the aftertreatment system. The use of LTM turbine housing has not been previously considered as a means for addressing this requirement.

Performance of a natural gas two-stroke engine incorporated in a 1-kW free-piston oscillating Linear Engine Alternator (LEA) - a household electricity generator - was investigated under different resonant frequencies for pre-design phase purposes. To increase the robustness, power density, and thermal efficiencies, the crank mechanism in free-piston LEA is omitted and all moving parts of the generator operate at a fixed resonant frequency. Flexure springs are the main source of the LEA’s stiffness and the mass-spring dynamics dominates the engine’s speed. The trade-off between the engine’s performance, mass-spring system limits, and power and efficiency targets versus the LEA speed is very crucial and demands a careful investigation specifically at the concept design stages to find the optimum design parameters and operating conditions. CFD modeling was performed to analyze the effects of resonant frequency on the engine’s gas exchange behavior.

The conversion of compression ignition (CI) internal combustion engines to spark-ignition (SI) operation by adding a spark plug to ignite the mixture and fumigating the fuel inside the intake manifold can increase the use of alternative gaseous fuels (e.g., natural gas) in heavy-duty applications. This study proposed a novel, less-complex methodology based on the inflection points in the apparent rate of heat release (ROHR) that can identify and separate the fast-burning stage inside the piston bowl from the slower combustion stage inside the squish region (a characteristic of premixed combustion inside a diesel geometry). A single-cylinder 2L CI research engine converted to natural gas SI operation provided the experimental data needed to evaluate the methodology, at several spark timings, equivalence ratios, and engine speeds.

The conversion of existing diesel engines to natural-gas operation can reduce the dependence on petroleum imports and curtail engine-out emissions. A convenient way to perform such conversion is by adding a gas injector in the intake manifold and replacing the diesel fuel injector with a spark plug to initiate and control the combustion process. However, challenges may appear with respect to engine’s efficiency and emissions as natural-gas spark-ignition combustion inside a diesel combustion chamber is different to that in conventional spark ignition engines. For example, major difference is the phasing and duration of the fast burn, defined as the period in which the rate of heat release increases linearly with crank angle. This study presents a methodology to investigate the fast burn inside a diesel geometry using heat release data.

Recent development in hydraulic fracking made natural gas (NG) to be a promising alternative gaseous fuel for heavy-duty diesel engines. The existing compression ignition (CI) engine can be retrofitted to NG spark ignition (SI) operation by replacing the diesel injector with a spark plug and fumigating NG into the intake manifold. However, the original diesel piston geometry (flat head and bowl-in-piston chamber) was usually retained to reduce modification cost. The goal of this study was to increase the understanding of the NG lean-burn characteristics in a diesel-like, fast-burn SI combustion chamber. The experimental platform can operate in conventional (i.e., all engine parts are metal) or in optical configuration (i.e., the stock piston and cylinder block are replaced with a see-through piston and an extended cylinder block). The optical data indicated a fast-propagated flame inside the piston bowl.

Our research focused on the assessment of fuel variation effects on performance of a 34 cc two-stroke, natural gas combustion engine designed for use as the prime mover in either slider-crank or novel linear generator applications. Nearly two-thirds of US homes have either natural gas or liquefied petroleum gas available at low pressures. We tested the engine with three different natural gas blends, pure methane, and pure propane. In order to reduce fuel compression power, we modified the engine to use low-pressure direct injection (LPDI) of gaseous fuels. We examined regulated gaseous emissions, greenhouse gas emissions, and combustion trends over a range of delivered air fuel ratios. Start of Injection (SOI) occurred at either 180 or 190 CA BTDC and efficiency improved by reducing fuel slip. However, for natural gas blends, the predominant emissions were methane - a potent greenhouse gas.

On- and off-road heavy-duty diesel engines modified to spark-ignition natural gas operation can reduce U.S. dependence on imported oil and enhance national energy security. Engine conversion can be achieved through the addition of a gas injector in the intake manifold and of a spark plug in place of the diesel injector. This paper investigated combustion characteristics and engine performance at several lean-burn operating conditions that changed spark timing, mixture equivalence ratio, and engine speed, using methane as NG surrogate.

Three-way catalysts have been used in a variety of stoichiometric natural gas engines for emission control. During real-world operation, these catalysts have experienced a large number of temporary and permanent deactivations including thermal aging and chemical contamination. Thermal aging is typically induced either by high engine-out exhaust temperatures or the reaction exotherm generated on the catalysts. Chemical contamination originates from various inorganic species such as Phosphorous (P) and Sulfur (S) that contain in engine fluids, which can poison and/or mask the catalyst active components. Such deactivations are quite difficult to simulate under laboratory conditions, due to the fact that multiple deactivation modes may occur at the same time in the real-world operations. In this work, a set of field-aged TWCs has been analyzed through detailed laboratory research in order to identify and quantify the real-world aging mechanisms.

Internal combustion engines with optical access (a.k.a. optical engines) provide additional information in the quest for understanding the fundamental in-cylinder combustion phenomena. However, most optical engines have flat bowl-in-piston combustion chamber to optimize the visualization process, which is different, for example, from the traditional re-entrant bowl in compression ignition engines. A conventional heavy-duty direct-injection compression ignition engine was converted to spark ignition operation by replacing the fuel injector with a spark plug in both optical and metal setups to investigate the effect of the bowl geometry on flame propagation. Experimental data from steady-state lean-burn conditions was used to develop and validate a 3D CFD model of the engine. Numerical simulation results show that flame propagation in the radial direction was similar for both combustion chambers despite their different geometries.

Internal combustion diesel engines with optical access (a.k.a. optical engines) increase the fundamental understanding of combustion phenomena. However, optical access requirements result in most optical engines having a different in-cylinder geometry compared with the conventional diesel engine, such as a flat bowl-in-piston combustion chamber. This study investigated the effect of the bowl geometry on the flow motion and emissions inside a conventional heavy-duty direct-injection diesel engine that can operate in both metal and optical-access configurations. This engine was converted to natural-gas spark-ignition operation by replacing the fuel injector with a spark plug and adding a low-pressure gas injector in the intake manifold for fuel delivery, then operated at steady-state lean-burn conditions. A 3D CFD model based on the experimental data predicted that the different bowl geometry did not significantly affect in-cylinder emissions distribution.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Dynamometer (dyno) durability testing plays a significant role in reliability and durability assessment of commercial engines. Frequently, durability test procedures are based on warranty history and corresponding component failure modes. Evolution of engine designs, operating conditions, electronic control features, and diagnostic limits have created challenges to historical-based testing approaches. A physics-based methodology, known as Load Matrix, is described to counteract these challenges. The technique, developed by AVL, is based on damage factor models for subsystem and component failure modes (e.g. fatigue, wear, degradation, deposits) and knowledge of customer duty cycles. By correlating dyno test to field conditions in quantifiable terms, such as customer equivalent miles, more effective and efficient durability test suites and test procedures can be utilized. To this end, application of Load Matrix to a heavy-duty diesel engine is presented.