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March 2011, the Great East Japan Earthquake and subsequent Giant Tsunami caused insufficient nuclear reactor cooling at the Fukushima Daiichi Nuclear Power Station (1F), resulting in a catastrophe of hydrogen explosion. The development of long-term safe storage technology for high-dose radioactive fuel debris collected by the decommissioning of nuclear power plants is an urgent issue. Inside the storage canister, strong radiation from fuel debris decomposes water to generate hydrogen and oxygen. The research and development have been proceeding in order to secure safety by simply placing a catalyst in the canister for oxidizing hydrogen and returning it into water. The catalyst is called a Passive Autocatalytic Recombiner (PAR), and unlike catalysts for chemical plants, it is required to have robustness that can maintain its activity for more than 30 years in an environment where temperature, humidity, gas concentration, etc. cannot be controlled.

Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.

Cyclic variation on heavy knocking was reproduced using 3D SI combustion simulation with RANS / LES turbulence models and detailed kinetic mechanisms. A 0.66 liter, inline 3 cylinder gasoline engine operated at 1200 rpm, WOT was mainly investigated. It was revealed that the combination of RANS, Liu mech. and calculation over multiple cycles worked well. Detailed process of heavy-knock was also suggested and it was thought that SWACER-like mechanism had concerned. RANS could describe typical behavior of heavy-knock within the first 3 cycle calculation and it showed good agreement with both the actual engine measurement and LES calculation result.

Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

The aim of this research is to develop the diesel combustion simulation (UniDES: Universal Diesel Engine Simulator) that incorporates multiple-injection strategies and in-cylinder composition changes due to exhaust gas recirculation (EGR), and that is capable of high speed calculation. The model is based on a zero-dimensional (0D) cycle simulation, and represents a multiple-injection strategy using a multi-zone model and inhomogeneity using a probability density function (PDF) model. Therefore, the 0D cycle simulation also enables both high accuracy and high speed. This research considers application to actual development. To expand the applicability of the simulation, a model that accurately estimates nozzle sac pressure with various injection quantities and common rail pressures, a model that accounts for the effects of adjacent spray interaction, and a model that considers the NOx reduction phenomenon under high load conditions were added.

A one-dimensional (1-D) micro-kinetic reaction model with considering mass transport inside porous washcoat was developed to promote an effective development of multi-functional catalysts. The validation of this model has been done successfully through the comparison with a set of basic experiments. A numerical simulation study was conducted for the various catalyst configurations of three-way catalysts under Federal Test Procedure (FTP75) condition. It was found that a double layer type had a significant advantage in the total mass emissions, especially in NOx emissions. The reaction mechanisms in these catalysts were numerically clarified from the view point of detailed reaction dynamics. We concluded that the utilization of the numerical simulation with the detailed chemistry was effective for the optimization of catalyst design.

The effects of an increasing boost pressure, a high EGR rate and a high injection pressure on exhaust emissions from an HSDI (High Speed Direct Injection) diesel engine were examined. The mechanisms were then investigated with both in-cylinder observations and 3DCFD coupled with ϕT-map analysis. Under a high-load condition, increasing the charging efficiency combined with a high injection pressure and a high EGR rate is an effective way to reduce NOx and soot simultaneously, which realized an ultra low NOx of 16ppm at 1.7MPa of IMEP (Indicated Mean Effective Pressure). The flame temperature with low NOx and low soot emissions is decreased by 260K from that with conventional emissions. Also, the distribution of the fuel-air mixture plot on a ϕT-map is moved away from the NOx and soot formation peninsula, compared to the conventional emissions case.

In case of the turbocharged engine, it is difficult to control both the air mass flow and the EGR flow. Because the air mass flow and the Exhaust Gas Recirculation (EGR) flow are influenced by the boost pressure, it becomes necessary to manipulate the many inputs to control them. Therefore, to overcome this problem, we developed the new Multi Input Multi Output (MIMO) algorithm based on the adaptive sliding mode control (SMC) which eliminated the observer. And consequently, it is confirmed that this new algorithm makes it possible to track both the air mass flow and EGR flow to the desired value.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

Natural gas homogeneous charge compression ignition (HCCI) engines require high compression ratios and intake air heating because of the high auto-ignition temperature of natural gas. In the first study, the natural gas fueled HCCI combustion with internal exhaust gas recirculation (EGR) was achieved without an intake air heater. The effects of the combustion chamber configuration, turbocharging, and external EGR were investigated for expanding the operating range. As a result, it was cleared that the combination of internal / external EGR and turbocharging is effective for expanding the HCCI operational range toward high loads. Meanwhile, the HCCI combustion characteristics at high engine speeds were unstable because of an insufficient reaction time for auto-ignition. Although the engine operation with a richer air-fuel ratio was effective for improving the combustion stability, the combustion noise (CN) was at an unacceptable level.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

A concept of dual-fuel, Premixed Compression Ignition (PCI) combustion controlled by two fuels with different ignitability has been developed to achieve drastically low NOx and smoke emissions. In this system, isooctane, which was used to represent high-octane gasoline, was supplied from an intake port and diesel fuel was injected directly into an engine cylinder at early timing as ignition trigger. It was found that the ignition timing of this PCI combustion can be controlled by changing the ratio of amounts of injected two fuels and combustion proceeds very mildly by making spatial stratifications of ignitability in the cylinder even without EGR, as preventing the whole mixture from igniting simultaneously. The operable range of load, where NOx and smoke were less than 10ppm and 0.1 FSN, respectively, was extended up to 1.2MPa of IMEP using an intake air boosting system together with dual fueling.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.

The stratification feature of DI gasoline combustion was studied by using a constant volume combustion vessel. An index of stratification degree, defined as volumetric burning velocity, has been proposed based on the thermodynamic analysis of the indicated pressure data. The burning feature analysis using this stratification degree and the fuel vapor concentration measurement using He-Ne laser ray absorption method were carried out for the swirl nozzle spray with 90° cone angle and the slit nozzle spray with 60° fan angle. Ambient pressure and ambient temperature were changed from atmospheric condition to 0.5∼0.6 MPa and 465 K, respectively. Air Swirl with swirl ratio of 0∼1.0 were added for the 90° swirl nozzle spray. Single component fuels with different volatility and self-ignitability from each other were used besides gasoline fuel. The major findings are as follows. High ambient temperature improves stratification degree due to the enhanced fuel vaporization and vapor diffusion.

We have already reported that a LaFeCoPdO3 perovskite catalyst has the function for self-regeneration of Pd [1, 2, 3, 4, 5 and 6]. But cobalt was recognized as an environmental burden. In order to prepare for its practical application, we examined the composition of perovskite without cobalt. In this paper, we have investigated the catalytic activity, the structural durability and the regenerative ability of Co-free perovskites LaFePdO3, in comparison with LaFeCoPdO3 and Pd/Al2O3. As a result, the structural durability of LaFePdO3 is high, and the light-off performance is excellent even after aging. “Co-free Intelligent Catalyst” is regarded as the next technology for practical use especially as it is efficient in the reduction of emissions at cold starting.

The stoichiometric direct injection gasoline engines have higher torque performance than the port injection engines, as the volumetric efficiency can be increased due to the cooling effects of charging air by the fuel evaporation in the cylinder. They need only 3-way catalyst, leading to the cost down. However there exists the injection timing (region) that increased volumetric efficiency does not lead to higher torque. In order to investigate the phenomena, the in-cylinder mixture formation process has been analyzed by the LIF and the CFD techniques. As the results, it has been revealed that the phenomena are caused by the inhomogeneous mixture distribution before the ignition timing.

We have reported the innovation of “An Intelligent Catalyst” which has the function for self-regeneration of Pd realized through the solid solution and segregation of Pd in a perovskite crystal. In this study, we did further research on regeneration for three different precious metals (Rh, Pd and Pt) in two types of perovskite systems (LaCeFeO3 and LaCeCoO3). In perovskite catalysts loaded with precious metals, the durability of the perovskite structure in redox fluctuation at high temperature is indispensable to suppression of the grain growth of precious metals. The key technology for the development of intelligent catalysts is considered to be the affinity of precious metals to durable perovskite oxides. In the six kinds of perovskite catalysts investigated here, only the Pd loaded LaCeFeO3 catalyst was considered “intelligent”.

With emission regulations getting tighter and tighter, catalysts will need to be active at ever lower temperatures in order to meet future standards. To meet this need, automotive catalysts are being installed closer to the engine so as to be active immediately after start-up. In this location, catalysts must have high temperature durability. In this paper, we examined a heat-resistant support material, “hexa-aluminate”, for possible use in future automotive catalysts. Catalytic activity of hexa-aluminate was more better than La added γ - alumina after redox treatment in model gas and after engine aging. Since hexa-aluminate had the excellent thermal durability, and Pd, which are supported on it, maintains finer particles than those on La added γ-alumina. We suggest that hexa-aluminate is a effective support material for automotive catalysts. More specifically, hexa-aluminate is expected to be a key technology for meeting the stringent emission standards of the future.