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Technical Paper

Assessment of Condensation Particle Counter-Based Portable Solid Particle Number System for Applications with High Water Content in Exhaust

2024-04-22
2024-01-5048
The Particle Number–Portable Emission Measurement System (PN-PEMS) came into force with Euro VI Phase E regulations starting January 1, 2022. However, positive ignition (PI) engines must comply from January 1, 2024. The delay was due to the unavailability of the PN-PEMS system that could withstand high concentrations of water typically present in the tailpipe (TP) of CNG vehicles, which was detrimental to the PN-PEMS systems. Thus, this study was designed to evaluate the condensation particle counter (CPC)-based PN-PEMS measurement capabilities that was upgraded to endure high concentration of water. The PN-PEMS measurement of solid particle number (SPN23) greater than 23 nm was compared against the laboratory-grade PN systems in four phases. Each phase differs based upon the PN-PEMS and PN system location and measurements were made from three different CNG engines. In the first phase, systems measured the diluted exhaust through constant volume sampler (CVS) tunnel.
Technical Paper

Implementing Ordinary Differential Equation Solvers in Rust Programming Language for Modeling Vehicle Powertrain Systems

2024-04-09
2024-01-2148
Efficient and accurate ordinary differential equation (ODE) solvers are necessary for powertrain and vehicle dynamics modeling. However, current commercial ODE solvers can be financially prohibitive, leading to a need for accessible, effective, open-source ODE solvers designed for powertrain modeling. Rust is a compiled programming language that has the potential to be used for fast and easy-to-use powertrain models, given its exceptional computational performance, robust package ecosystem, and short time required for modelers to become proficient. However, of the three commonly used (>3,000 downloads) packages in Rust with ODE solver capabilities, only one has more than four numerical methods implemented, and none are designed specifically for modeling physical systems. Therefore, the goal of the Differential Equation System Solver (DESS) was to implement accurate ODE solvers in Rust designed for the component-based problems often seen in powertrain modeling.
Technical Paper

Development of Time-Temperature Analysis Algorithm for Estimation of Lithium-Ion Battery Useful Life

2024-04-09
2024-01-2191
Due to the recent progress in electrification, lithium-ion batteries have been widely used for electric and hybrid vehicles. Lithium-ion batteries exhibit high energy density and high-power density which are critical for vehicle development with high driving range enhanced performance. However, high battery temperature can negatively impact the battery life, performance, and energy delivery. In this paper, we developed and applied an analytical algorithm to estimate battery life-based vehicle level testing. A set of vehicle level tests were selected to represent customer duty cycles. Thermal degradation models are applied to estimate battery capacity loss during driving and park conditions. Due to the sensitivity of Lithium-Ion batteries to heat, the effect of high ambient temperatures throughout the year is considered as well. The analysis provides an estimate of the capacity loss due to calendar and cyclic effects throughout the battery life.
Technical Paper

Diesel Oxidation Catalyst Performance with Biodiesel Formulations

2024-04-09
2024-01-2711
Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC.
Technical Paper

Performance Comparison Analysis between Biodiesel and Diesel over a Commercial DOC Catalyst

2024-04-09
2024-01-2707
Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.
Technical Paper

Sulfur Impact on Methane Steam Reforming over the Stoichiometric Natural Gas Three-Way Catalyst

2024-04-09
2024-01-2633
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.
Technical Paper

Proactive Battery Energy Management Using Navigation Information

2024-04-09
2024-01-2142
In this paper, a control strategy for state of charge (SOC) allocation using navigation data for Hybrid Electric Vehicle (HEV) propulsion systems is proposed. This algorithm dynamically defines and adjusts a SOC target as a function of distance travelled on-line, thereby enabling proactive management of the energy store in the battery. The proposed approach incorporates variances in road resistance and adheres to geolocation constraints, including ultra-low emission zones (uLEZ). The anticipated advantages are particularly pronounced during scenarios involving extensive medium-to-long journeys characterized by abrupt topological changes or the necessity for exclusive electric vehicle (EV) mode operation. This novel solution stands to significantly enhance both drivability and fuel economy outcomes.
Technical Paper

Statistical Treatise on Critical Biodiesel (B100) Quality Properties in the United States from 2004-2022

2023-08-28
2023-24-0097
The quality of neat biodiesel (B100) is critical for ensuring biodiesel blends used in diesel-powered vehicles do not adversely impact engine performance. In the United States, B100 is required to meet ASTM International’s purity and fuel property requirements in D6751, “Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels.” Here we review the development of this standard for the different grades of B100. The BQ-9000 program, which currently covers over 90% of U.S. and Canadian production volumes, is also described. Engine and original equipment manufacturers have expressed a desire for credible, third-party data on values of various ASTM B100 properties in the commercial market to inform their efforts to address future emissions and durability requirements.
Technical Paper

Optimization of Aluminum Sleeve Design for the tow eye Durability Using DFSS Approach

2023-04-11
2023-01-0092
The automotive industry is moving towards larger SUVs and also electrification is a need to meet the carbon neutrality target. As a result, we see an increase in overall gross vehicle weight (GVW), with the additional weight coming from the HV battery pack, electric powertrain, and other electrical systems. Tow-eye is an essential component that is provided with every vehicle to use for towing during an emergency vehicle breakdown. The tow-eye is usually connected to the retainer/sleeve available in the bumper system and towed using the recovery vehicle or other car with towing provision. Therefore, the tow-eye should meet the functional targets under standard operating conditions. This study is mainly for cars with bumper and tow-eye sleeves made of aluminum which is used in the most recent development of vehicles for weight-saving opportunities. Tow-eye systems in aluminum bumpers are designed to avoid any bending or buckling of the sleeve during towing for whatever the GVW loads.
Technical Paper

Transient Electrochemical Modeling and Performance Investigation Under Different Driving Conditions for 144Ah Li-ion Cell with Two Jelly Rolls

2023-04-11
2023-01-0513
Recently, the automotive industry has experienced rapid growth in powertrain electrification, with more and more battery electric vehicles (BEV) and hybrid electric vehicles being launched. Lithium-ion batteries play an important role due to their high energy capacity and power density, however they experience high heat generation in their operation, and if not properly cooled it can lead to serious safety issues as well as lower performance and durability. In that way, good prediction of a battery behavior is crucial for successful design and management. This paper presents a 1D electrochemical model development of a 144 Ah prismatic rolled cell using the GT-Autolion software with a pseudo 2D approach. The model correlation is done at cell level comparing model results and test data of cell open circuit voltage at different temperatures and voltage and temperature profile under different C-rates and ambient temperatures.
Journal Article

Development of a Heavy-Duty Electric Vehicle Integration and Implementation (HEVII) Tool

2023-04-11
2023-01-0708
As demand for consumer electric vehicles (EVs) has drastically increased in recent years, manufacturers have been working to bring heavy-duty EVs to market to compete with Class 6-8 diesel-powered trucks. Many high-profile companies have committed to begin electrifying their fleet operations, but have yet to implement EVs at scale due to their limited range, long charging times, sparse charging infrastructure, and lack of data from in-use operation. Thus far, EVs have been disproportionately implemented by larger fleets with more resources. To aid fleet operators, it is imperative to develop tools to evaluate the electrification potential of heavy-duty fleets. However, commercially available tools, designed mostly for light-duty vehicles, are inadequate for making electrification recommendations tailored to a fleet of heavy-duty vehicles.
Technical Paper

Accurate Automotive Spinning Wheel Predictions Via Deformed Treaded Tire on a Full Vehicle Compared to Full Width Moving Belt Wind Tunnel Results

2023-04-11
2023-01-0843
As the automotive industry is quickly changing towards electric vehicles, we can highlight the importance of aerodynamics and its critical role in reaching extended battery ranges for electric cars. With all new smooth underbodies, a lot of attention has turned into the effects of rim designs and tires brands and the management of these tire wakes with the vehicle. Tires are one of the most challenging areas for aerodynamic drag prediction due to its unsteady behavior and rubber deformation. With the simulation technologies evolving fast regarding modeling spinning tires for aerodynamics, this paper takes the prior work and data completed by the authors and investigates the impact on the flow fields and aerodynamic forces using the most recent developments of an Immerse Boundary Method (IBM). IBM allows us to mimic realistically a rotating and deformed tire using Lattice Boltzmann methods.
Technical Paper

Assessing the National Off-Cycle Benefits of 2-Layer HVAC Technology Using Dynamometer Testing and a National Simulation Framework

2023-04-11
2023-01-0942
Some CO2-reducing technologies have real-world benefits not captured by regulatory testing methods. This paper documents a two-layer heating, ventilation, and air-conditioning (HVAC) system that facilitates faster engine warmup through strategic increased air recirculation. The performance of this technology was assessed on a 2020 Hyundai Sonata. Empirical performance of the technology was obtained through dynamometer tests at Argonne National Laboratory. Performance of the vehicle across multiple cycles and cell ambient temperatures with the two-layer technology active and inactive indicated fuel consumption reduction in nearly all cases. A thermally sensitive powertrain model, the National Renewable Energy Laboratory’s FASTSim Hot, was calibrated and validated against vehicle testing data. The developed model included the engine, cabin, and HVAC system controls.
Technical Paper

Three-Dimensional Thermal Simulation of a Hybrid Vehicle with Energy Consumption Estimation and Prediction of Battery Degradation under Modern Drive-Cycles

2023-04-11
2023-01-0135
As more electric vehicles (BEV, HEV, PHEV, etc.) are adopted in the upcoming decades, it is becoming increasingly important to conduct vehicle-level thermal simulations under different drive-cycle conditions while incorporating the various subsystem thermal losses. Thermal management of the various heat sources in the vehicle is essential both in terms of ensuring passenger safety as well as maintaining all the subsystems within their corresponding safe temperature limits. It is also imperative that these thermal simulations include energy consumption prediction, while considering the effect of battery degradation both in terms of increased thermal losses as well as reduction in the vehicle’s range. For this purpose, a three-dimensional transient thermal analysis framework was coupled with an electrochemical P2D-based battery model and a vehicle dynamics model to test different scenarios and their effect on a hybrid vehicle’s range and the lithium-ion battery life.
Technical Paper

Experimental and Modeling Study on the Thermal Aging Impact on the Performance of the Natural Gas Three-Way Catalyst

2023-04-11
2023-01-0375
The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.
Journal Article

Laboratory sulfation of an ammonia slip catalyst with a real-world SO2 concentration

2023-04-11
2023-01-0380
Upcoming, stricter diesel exhaust emissions standards will likely require aftertreatment architectures with multiple diesel exhaust fluid (DEF) introduction locations. Managing NH3 slip with technologies such as an ammonia slip catalyst (ASC) will continue to be critical in these future aftertreatment systems. In this study, we evaluate the impact of SO2 exposure on a state-of-the-art commercially available ASC. SO2 is co-fed at 0.5 or 3 ppmv to either approximate or accelerate a real-world exhaust SO2 impact. ASC performance during sulfur co-feeding is measured under a wide variety of simulated real-world conditions. Results indicate that the loss of NO conversion during SCR is dependent on the cumulative SO2 exposure, regardless of the inlet SO2 concentration. Meanwhile, N2O formation under SCR conditions is nonlinearly affected by SO2 exposure, with formation increasing during 0.5 ppmv SO2 exposure but decreasing in the presence of 3 ppmv SO2.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part II: Chemical and Microscopic Characterization of Aged DPFs

2023-04-11
2023-01-0296
This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part I: Accelerated Ash Loading and DPF Performance Evaluation

2023-04-11
2023-01-0297
The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.
Technical Paper

Advanced Tire to Vehicle Connectivity for Safety and Fuel Economy of Automated Heavy-Duty Trucks

2022-03-29
2022-01-0881
Safety, fuel economy and uptime are key requirements for the operation of heavy-duty line-haul trucks within a fleet. With the penetration of connectivity and automation technologies, energy optimal and safe operation of the trucks are further improved through Advanced Driver Assistance System (ADAS) features and automated technologies as in truck platooning. Understanding the braking capability of the vehicle is very important for optimal ADAS and platooning control system design and integration. In this paper, the importance of tire connectivity and tire conditions on truck stopping distance are demonstrated through testing. The test data is further utilized to develop tire models for integration in an optimal vehicle automation for platooning. New ways to produce and use the tire related information in real-time optimal control of platooning trucks are proposed and the contribution of tire information in fuel economy is quantified through simulations.
Technical Paper

3D FEA Thermal Modeling with Experimentally Measured Loss Gradient of Large Format Ultra-Fast Charging Battery Module Used for EVs

2022-03-29
2022-01-0711
A large amount of heat is generated in electric vehicle battery packs during high rate charging, resulting in the need for effective cooling methods. In this paper, a prototype liquid cooled large format Lithium-ion battery module is modeled and tested. Experiments are conducted on the module, which includes 31Ah NMC/Graphite pouch battery cells sandwiched by a foam thermal pad and heat sinks on both sides. The module is instrumented with twenty T-type thermocouples to measure thermal characteristics including the cell and foam surface temperature, heat flux distribution, and the heat generation from batteries under up to 5C rate ultra-fast charging. Constant power loss tests are also performed in which battery loss can be directly measured.
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