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Fuel design concept has been proposed for low emission and combustion control in engine systems. In this concept, the multicomponent fuels, which are mixed with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components), are used for artificial control of fuel properties. In addition, these multicomponent fuels can easily lead to flash boiling which promote atomization and vaporization in the spray process. In order to understand atomization and vaporization process of multicomponent fuels in detail, the model for flash boiling spray of multicomponent fuel have been constructed and implemented into KIVA3V rel.2. This model considers the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets.

Ignition, combustion and emissions characteristics of dual-component fuel spray were examined for ranges of injection timing and intake-air oxygen concentration. Fuels used were binary mixtures of gasoline-like component i-octane (cetane number 12, boiling point 372 K) and diesel fuel-like component n-tridecane (cetane number 88, boiling point 510 K). Mass fraction of i-octane was also changed as the experimental variable. The experimental study was carried out in a single cylinder compression ignition engine equipped with a common-rail injection system and an exhaust gas recirculation system. The results demonstrated that the increase of the i-octane mass fraction with optimizations of injection timing and intake oxygen concentration reduced pressure rise rate and soot and NOx emissions without deterioration of indicated thermal efficiency.

Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

Fuel design for internal combustion engines has been proposed in our study. In this concept, the multicomponent fuel with high and low volatility fuels are used in order to control the spray and combustion processes in internal combustion engine. Therefore, it is necessary to understand the spray and combustion characteristics of the multicomponent fuels in detail. In the present study, the modeling of multicomponent spray vaporization was conducted using KIVA3V code. The physical fuel properties of multicomponent fuel were estimated using the source code of NIST Mixture Property Database. Peng-Robinson equation of state and fugacity calculation were applied to the estimation of liquid-vapor equilibrium in order to take account for non-ideal vaporization process. Two-zone model in which fuel droplet was divided into droplet surface and inner core was introduced in order to simply consider the temperature distribution in fuel droplet.

In this study, the novel fuel design concept has been proposed in order to realize the low emission and combustion control in engine systems. In this fuel design concept, the mixed fuels with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components) are used in order to improve the spray characteristics by flash boiling. In our previous papers on this study, the fundamental characteristics of spray and its combustion of mixed fuel were reported. In this paper, heat release and exhaust emission (smoke, NOx and THC) characteristics of single cylinder diesel engine operated with the mixed fuels were investigated under each load. The exhaust performance of diesel engine could be improved using mixed fuel, because fuel properties and spray characteristics were controlled by changing mixing fraction of the mixed fuel.

In the present study, we have proposed a novel fuel design concept in order to achieve low emissions and combustion control in engine systems. The fuel design concept is based on the combustion control that could be realized by using a mixed fuel with a lower boiling point fuel, such as gasoline or gaseous fuel components and a higher boiling point fuel, such as gas oil or fuel oil components. According to the fuel design concept proposed in this work, the characteristics of vaporization during mixture formation process as well as of combustion can be reasonably improved due to the formation of two-phase region. The heat release analysis was conducted to compare the temporal history of heat release for both a mixed fuel and a single component fuel that has the same transport properties of mixed fuels. In addition, the two-color method, which simultaneously allows the measurements of temperature distribution and soot concentration, is applied to the combustion field for mixed fuels.

In previous our work, we revealed that the flash boiling process could improve remarkably the spray atomization for the pure substance-single component fuel in relation to the port-injected S.I. engines. Then, we applied this flash boiling spray to the Diesel spray process by the use of the two phase region formed between liquefied CO2 and n-Tridecane as the first step of fuel design concept. And the promoted atomization properties could be obtained in this mixed fuel concept. Further, we could obtain the simultaneous reduction of NO and soot emissions in Diesel engine exhaust due to the spray internal EGR effect and reburning of soot. As the second step, we proposed a novel fuel design concept for low exhaust emission and combustion control, relating to mixed and reformulated fuels with a lower boiling point fuel such as gasoline components or gas fuel and a higher boiling point fuel such as gas oil or heavy oil components to obtain the both advantages of their fuels for combustion.