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Technical Paper

Reversible Sulfur Poisoning of 3-way Catalyst linked with Oxygen Storage Mechanisms

2021-09-05
2021-24-0069
Even though the 3-way catalyst chemistry has been studied extensively in the literature, some performance aspects of practical relevance have not been fully explained. It is believed that the Oxygen Storage Capacity function of 3-way catalytic components dominates the behavior during stoichiometry transitions from lean to rich mode and vice versa whereas a number of mathematical models have been proposed to describe the dynamics of pollutant conversion. Previous studies have suggested a strong impact of Sulfur on the pollutant conversion after a lean to rich transition, which has not been adequately explained and modelled. Lean to rich transitions are highly relevant to catalyst ‘purging’ needed after exposure to high O2 levels (e.g. after fuel cut-offs). This work presents engine test measurements with an engine-aged catalyst that highlight the negative impact of Sulfur on pollutant conversion after a lean to rich transition.
Technical Paper

A Simulation Method for the Calculation of Water Condensation inside Charge Air Coolers

2021-04-06
2021-01-0226
The automotive industry uses supercharging in combination with various EGR strategies to meet the increasing demand for Diesel engines with high efficiency and low engine emissions. The charge air is heated by the EGR and the compression in the turbocharger to such an extent that high NOx emissions and a reduction in engine performance occurs. For this reason, the charge air cooler cools down the charge air before it enters the air intake manifold. In case of low pressure EGR, the charge air possesses a high moisture content and under certain operating conditions an accumulation of condensate takes place within the charge air cooler. During demanding engine loads, the condensate is entrained from the charge air cooler into the combustion chamber, resulting in misfiring or severe engine damage.
Journal Article

Optimization of an Asymmetric Twin Scroll Volute Turbine under Pulsating Engine Boundary Conditions

2020-04-14
2020-01-0914
Future CO2 emission legislation requires the internal combustion engine to become more efficient than ever. Of great importance is the boosting system enabling down-sizing and down-speeding. However, the thermodynamic coupling of a reciprocating internal combustion engine and a turbocharger poses a great challenge to the turbine as pulsating admission conditions are imposed onto the turbocharger turbine. This paper presents a novel approach to a turbocharger turbine development process and outlines this process using the example of an asymmetric twin scroll turbocharger applied to a heavy duty truck engine application. In a first step, relevant operating points are defined taking into account fuel consumption on reference routes for the target application. These operation points are transferred into transient boundary conditions imposed on the turbine.
Technical Paper

Analysis of TWC Characteristics in a Euro6 Gasoline Light Duty Vehicle

2019-09-09
2019-24-0162
A Euro6 gasoline light duty vehicle has been tested at the engine dynamometer and the emissions have been analyzed upstream and downstream the Three-Way-Catalyst (TWC) during a WLTC cycle. Catalyst simulations have been used for assessing the processes inside the catalytic converter using a reaction scheme based on 19 brutto reactions (direct oxidation and reduction, selective catalytic reductions with CO, C3H6 and H2, steam reforming, water-gas shift and bulk ceria as well as surface ceria reactions). The reactions have been parameterized in order to best approximate the measurements. Based on the reactions taken into account, the real vehicle emissions can be predicted with good accuracy. The simulations show that the cycle emissions comprise mainly the cold start contribution as well as discrete emission break-through events during transients. During cold start no reactions are evident in the catalyst before the temperature of the gas entering the catalyst reaches 270°C.
Technical Paper

Possibilities of Wall Heat Transfer Measurements at a Supercharged Euro VI Heavy-Duty Diesel Engine with High EGR-Rates, an In-Cylinder Peak Pressure of 250 Bar and an Injection Pressure up to 2500 Bar

2019-09-09
2019-24-0171
A raise of efficiency is the strongest selling point concerning the total cost of ownership (TCO), especially for commercial vehicles (CV). Accompanied by legislations, with contradictive development demands, satisfying solutions have to be found. The analysis of energy losses in modern engines shows three influencing parameters. Wall heat transfer (WHT) losses are awarded with the highest optimization potential. Critical for the occurrence of these losses is the WHT, which can be described by representing coefficients. To reduce WHT accompanying losses a decrease of energy transfer between combustion gas and combustion chamber wall is necessary. A measurement of heat fluxes is necessary to determine the WHT relations of the combustion chamber in an engine. As this has not been done for a Heavy-Duty (HD) engine, with peak pressures up to 250 bar, an increased in-cylinder turbulence and high exhaust gas recirculation (EGR)-rates before, it is presented in the following.
Technical Paper

Steady-State Experimental and Meanline Study of an Asymmetric Twin-Scroll Turbine at Full and Unequal and Partial Admission Conditions

2018-04-03
2018-01-0971
The use of twin-scroll turbocharger turbines has gained popularity in recent years. The main reason is its capability of isolating and preserving pulsating exhaust flow from engine cylinders of adjacent firing order, hence enabling more efficient pulse turbocharging. Asymmetrical twin-scroll turbines have been used to realize high pressure exhaust gas recirculation (EGR) using only one scroll while designing the other scroll for optimal scavenging. This research is based on a production asymmetrical turbocharger turbine designed for a heavy duty truck engine of Daimler AG. Even though there are number of studies on symmetrical twin entry scroll performance, a comprehensive modeling tool for asymmetrical twin-scroll turbines is yet to be found. This is particularly true for a meanline model, which is often used during the turbine preliminary design stage.
Technical Paper

Stoichiometric Natural Gas Combustion in a Single Cylinder SI Engine and Impact of Charge Dilution by Means of EGR

2013-09-08
2013-24-0113
In this paper experimental results of a medium duty single cylinder research engine with spark ignition are presented. The engine was operated with stoichiometric natural gas combustion and additional charge dilution by means of external and cooled exhaust gas recirculation (EGR). The first part of this work considers the benefits of cooled EGR on thermo-mechanical stress of the engine including exhaust gas temperature, cylinder head temperature, and knock behaviour. This is followed by the analysis of the influence of cooled EGR on the heat release rate. In this context the impact of fuel gas composition is also under investigation. The influence of increasing EGR on fuel efficiency, which is caused by a changed combustion process due to higher fractions of inert gases, is shown in this section. By application of different pistons a relationship between the piston bowl geometry and the flame propagation has been demonstrated.
Technical Paper

SCR System Optimization and Control Supported by Simulation Tools

2013-04-08
2013-01-1075
The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.
Journal Article

Cold Start Effect Phenomena over Zeolite SCR Catalysts for Exhaust Gas Aftertreatment

2013-04-08
2013-01-1064
NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.
Technical Paper

Ash Transport in Diesel Particle Filters

2012-09-10
2012-01-1732
Lubricant oil derived ash deposits still represent a major issue in diesel particulate filter operation in vehicles. In literature various ash deposition patterns are described. The two boundary deposition patterns are (a) wall layer and (b) filling at the back end of the inlet channels. The patterns are often associated with different regeneration methods. Continuous regeneration is supposed to result in a homogeneous ash layer, whereas periodic (active) regeneration is reported to result in back end filling. The current contribution describes the basic mechanisms associated with ash transport phenomena in particle filters. On the basis of (a) frequency of ash exposure to flow (b) ash particle structure re-entrainment and finally (c) axial ash transport the different deposition pattern can be explained. Exposure to flow accomplished by periodical soot removal, either by passive or active regeneration is the first step.
Technical Paper

Modeling the Interactions Of Soot and SCR Reactions in Advanced DPF Technologies with Non-homogeneous Wall Structure

2012-04-16
2012-01-1298
The pressure for compact and efficient deNO systems has led to increased interest of incorporating SCR coatings in the DPF walls. This technology could be very attractive especially if high amounts of washcoat loadings could be impregnated in the DPF porous walls, which is only possible with high porosity filters. To counterbalance the filtration and backpressure drawbacks from such high porosity applications, the layered wall technology has already been proposed towards minimizing soot penetration in the wall and maximizing filtration efficiency. In order to deal with the understanding of the complex interactions in such advanced systems and assist their design optimization, this paper presents an advanced modeling framework and selected results from simulation studies trying to illustrate the governing phenomena affecting deNO performance and passive DPF regeneration in the above combined systems.
Technical Paper

Modeling of Injected Diesel Fuel Conversion and Heat Release in Oxidation Catalyst: 3D-CFD & 1D Channels Approach

2012-04-16
2012-01-1293
A system for controlled heat generation in exhaust pipeline is studied, consisting of fuel injector and oxidation catalyst (plus connecting pipes). A 3D-CFD software (StarCD) coupled with a tailored 1D model of catalytic monolith channel (XMR) are employed for simulations of realistic, fully 3D system geometry. Exhaust gas flow, fuel injection, and distribution at the catalyst inlet is solved by 3D-CFD, while the processes inside individual representative channels are simulated by the effective 1D model. The 3D-CFD software calls iteratively the 1D channel model with proper boundary conditions and solves 3D temperature profile over the monolith, utilizing local enthalpy fluxes (including gas-solid heat transfer and reaction enthalpy) calculated by the 1D channel model. Seven representative hydrocarbons are used for characterisation of Diesel fuel composition with respect to catalytic oxidation kinetics.
Technical Paper

A Modeling Study of Soot and De-NOx Reaction Phenomena in SCRF Systems

2011-06-09
2011-37-0031
The development of thermally durable zeolite NH3/Urea-SCR formulations coupled with that of high porosity filters substrates has opened the way to integrate PM and NOx control into a single device, namely an SCR-coated Diesel Particulate Filter (SCRF). A few experimental works are already present in the literature regarding SCRF systems, mainly addressing the DeNOx performances of the system (in both presence and absence of soot) under both steady state and transient conditions. The purpose of the present work is to perform a simulation study focused on phenomena which are expected to play key roles in SCRF systems, such as coupling of reaction and diffusion phenomena, soot effect on DeNOx activity, SCR coating effect on soot regeneration and filtration efficiency and competition between soot oxidation and DeNOx processes involving NO2.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Journal Article

Modelling of NOx Storage + SCR Exhaust Gas Aftertreatment System with Internal Generation of Ammonia

2010-04-12
2010-01-0887
Combination of an NOx storage and reduction catalyst (NSRC, called also lean NOx trap, LNT) and a catalyst for the selective catalytic reduction of NOx by NH₃ (NH₃-SCR) offers a potential to significantly increase the efficiency of NSRC-based exhaust gas aftertreatment systems. Under most situations the SCR catalyst is able to adsorb the NH₃ peaks generated in the NSRC during the regeneration and utilize it for additional NOx reduction in the course of the consequent lean phase. This synergy becomes more important with the aged NSRC, where generally lower NOx conversions and higher NH₃ yields in wider range of operating temperatures are observed (in comparison with the fresh or de-greened NSRC). In this paper we present global kinetic models for the NSRC (Pt/Ba/Ce/gγ-Al₂O₃ catalyst type) and NH₃-SCR (Fe-ZSM5 catalyst type).
Technical Paper

Applications of Multi-layer Catalyst Modeling in deNOx and DPF Systems

2010-04-12
2010-01-0893
Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.
Technical Paper

Specifics of Daimler's new SCR system (BLUETEC) in the Diesel Sprinter Van - Certified for NAFTA 2010

2010-04-12
2010-01-1172
Beginning in 2010, Daimler's well-known Diesel Sprinter van has to fulfill the new and clearly tighter NOx emission standards of NAFTA10 (EPA, CARB). This requires an integrated approach of further engine optimizations and the implementation of an innovative exhaust aftertreatment technology. The goal was to develop an overall concept which meets simultaneously the tightened emission standards (including OBD limits) and the increasing customer demands of more power and torque without losing the high fuel efficiency of the small and highly efficient 3-liter V6 diesel engine OM642, which already has been installed in the NAFTA07 Sprinter. In the early stages of the concept phase, the most appropriate NOx aftertreatment technology and certification form (engine or vehicle) had to be selected for this specific vehicle class in the van segment with enhanced requirements to durability, economical efficiency and specific driving behavior.
Technical Paper

Investigations on Chemical Ageing of Diesel Oxidation Catalysts and Coated Diesel Particulate Filters

2010-04-12
2010-01-1212
For medium- and heavy-duty diesel engines, the development of new catalyst technologies and particulate filters is necessary to fulfill increasingly stringent emission regulations. An important aspect is the durability of the after-treatment system and therefore its efficiency over lifetime. Lubrication oil additives contain components such as phosphorous or zinc to ensure engine durability. Diesel oxidation catalyst (DOC) and coated diesel particulate filter (cDPF) catalytic coatings are negatively influenced by contamination on the surface with these components (chemical ageing). The components have a negative impact on the exhaust after-treatment systems performance. Additionally the cDPF is filled with oil ash. Engine tests are conducted to analyze the effect of lubrication oil additives on after-treatment system performance. In one study, lubrication oil with increased sulfur ash content is used.
Technical Paper

A Modeling and Experimental Investigation on an Innovative Substrate for DPF Applications

2010-04-12
2010-01-0891
XP-SiC is an innovative type of a porous substrate material on the basis of a reaction formed SiC for DPF applications. The high porosity, large pore size inside the cell wall and low specific weight are the special characteristics of this substrate. The aim of the current paper is to present an investigation based on the experimental and modeling approaches to evaluate the back pressure, filtration efficiency and the thermal durability. The latter one was assessed by measuring and predicting the temperature field, as well as calculating the thermal stresses. For this purpose the filter was modeled in the commercial computational code axitrap as a stand-alone tool, in which the conservation equations of mass continuity, momentum, energy and species were solved. The soot filtrations, loading as well as the regeneration by fuel-borne catalyst were modeled.
Journal Article

Numerical Simulation of DOC+DPF+SCR systems:DOC Influence on SCR Performance

2008-04-14
2008-01-0867
A numerical model for a diesel oxidation catalyst (DOC) is presented. It is based on a spatially 1D, physical and chemically based modeling of the relevant processes within the catalytic monolith. A global reaction kinetic approach has been chosen to describe the chemical reactions. Water condensation and evaporation was also considered, in order to predict the cold start behavior. Reaction kinetic parameters have been evaluated from a series of laboratory experiments. A correlation between the kinetic parameters and the noble metal loading was developed. The model was used in combination with a SCR-Model to study the influence of changes of noble metal loading and DOC volume on the overall transient NOx performance of a DOC+DPF+SCR system.
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