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Spark ignition engines utilize catalytic converters to reform harmful exhaust gas emissions such as carbon monoxide, unburned hydrocarbons, and oxides of nitrogen into less harmful products. Aftertreatment devices require the use of expensive catalytic metals such as platinum, palladium, and rhodium. Meanwhile, tightening automotive emissions regulations globally necessitate the development of high-performance exhaust gas catalysts. So, automotive manufactures must balance maximizing catalyst performance while minimizing production costs. There are thousands of different recipes for catalytic converters, with each having a different effect on the various catalytic chemical reactions which impact the resultant tailpipe gas composition. In the development of catalytic converters, simulation models are often used to reduce the need for physical parts and testing, thus saving significant time and money.

In the light duty diesel segment, the need persists for an advanced control system to monitor the health of an aftertreatment system throughout a vehicle’s life in order to maintain compliance with ever tightening emissions levels. In on-board diagnostics (OBD), every diagnostic is validated during development stages to detect when a system under monitoring of that diagnostic has failed. This necessitates the need to create parts which represent a failure that would be observed on the vehicle. These failed parts, referred to as limit or threshold parts, are developed through a limit part creation process. Although there are commonalities amongst Original Equipment Manufacturers (OEM), each OEM has their own detection logic which will require a unique and specific limit part. Various methods exist for creating these limit parts, and each method produces a different combination of ability to detect the failure and its associated tailpipe emissions.

Autoignition delay times of two full blend gasoline fuels (high and low RON) were explored in a rapid compression machine. CO2 dilution by mass was introduced at 0%, 15%, and 30% levels with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy is used to represent exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines by using CO2 as a surrogate for major EGR constituents(N2, CO2, H2O). Experiments were conducted over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. The full blend fuels were admitted directly into the combustion chamber for mixture preparation using the direct test chamber (DTC) approach. CO2 addition retarded the autoignition times for the fuels studied here. The retarding effect of the CO2 dilution was more pronounced in the NTC region when compared to the lower and higher temperature range.

Mixture formation and combustion dynamics are the primary contributors to the performance and emission characteristics of direct-injected spark ignition (SI) engines. This requires assessing the benefits and tradeoffs of the design and control factors that influence mixing and the subsequent combustion event. In this study, Taguchi's L18 orthogonal array design of experiment (DoE) methodology has been applied to assess contributions and tradeoffs of varied compression ratio, piston bowl design, intake port tumble design, injector spray pattern, injection timing, injection pressure, exhaust gas recirculation (EGR) rate, and intake valve closing timing in a single-cylinder boosted gasoline direct injection (GDI) SI engine. This multiparameter study has been carried out across three speed-load conditions representative of typical automotive application operating ranges.

Rapid Compression Machines (RCM) offer the ability to easily change the compression ratio and the pressure/mixture composition/temperature to gather ignition delay data at various engine relevant conditions. Therefore, RCMs with optical access to the combustion chamber can provide an effective way to analyze macroscopic spray characteristics needed to understand the spray injection process and for spray model development, validation and calibration at conditions that are suitable for engines. Fuel surrogates can help control fuel parameters, develop models for spray and combustion, and perform laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of multicomponent gasoline surrogates in comparison to their gasoline counterparts, under gasoline direct injection (GDI) engine conditions.

In this work autoignition delay times of two multi-component surrogates (high and low RON) were experimentally compared with their target full blend gasoline fuels. The study was conducted in a rapid compression machine (RCM) test facility and a direct test chamber (DTC) charge preparation approach was used for mixture preparation. Experiments were carried over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. Dilution in the reactant mixture was varied from 0% to 30% CO2 (by mass), with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy emulates exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. The multicomponent surrogate captured the reactivity trends of the gasoline-air mixtures reasonably well in comparison to the single component (iso-octane) surrogate.

Advances in diesel engine and catalyst technologies have enabled light passenger vehicles in meeting the most stringent Tier 3/LEV III emission levels and durability requirements. The advancements in diesel aftertreatment catalyst technology have made catalysts more susceptible to low levels of impurities, typically referred to as poisons. Published studies over the last two decades, have shown a significant impact on the performance of catalysts, to the presence of sulfur and other inorganics in fuels and oils. The design of an aftertreatment system (ATS) typically sets limits for lubricant and fuel quality, specific to the geographical region and availability of certain level of regulated fuels. In this study, we investigate a real-world aged diesel vehicle which exhibited deterioration in tailpipe emissions, beyond levels targeted during engineering development.

In this paper we present an integrated approach which combines analysis of the effect of simultaneous variations in model input parameters on component or system temperatures. The sensitivity analysis can be conducted by varying model input parameters using specific values that may be of interest to the user. The alternative approach is to use a structured set of parameters generated in the form of a DFSS DOE matrix. The matrix represents a combination of simulation conditions which combine the control factors (CF) and noise factors. CF’s are the design parameters that the engineer can modify to achieve a robust design. Noise factors include parameters that are outside the control of the design engineer. In automotive thermal management, noise factors include changes in ambient temperature, exhaust gas temperatures or aging of exhaust system or heat shields for example.

Every passing year automotive engineers are challenged to attain higher fuel economy and improved emission targets. One widely used approach is to use Cooled Exhaust Gas Recirculation (CEGR) to meet these objectives. Apart from reducing emissions and improving fuel economy, CEGR also plays a significant role in knock mitigation in spark ignited gasoline engines. Generally, CEGR is introduced into the intake manifold in SI gasoline engine. Even though the benefits of using CEGR are significant, they can be easily negated by the uneven CEGR flow distribution between the cylinders, which can result in combustion instability. This paper describes the application of co-simulation between one and three dimensional tools to accurately predict the distribution of CEGR to the cylinders and the effect of its distribution on engine performance.

As automotive emissions become more stringent, accurate control of three-way catalyst temperature is increasingly important for maintaining high levels of conversion efficiency as well as preventing damage to the catalyst. A real-time catalyst temperature model provides critical information to the engine control system. In order to improve emissions and ensure regulatory compliance over a wide range of speed-load conditions, it is desirable to use modelled catalyst temperature as the primary input to catalyst efficiency control strategies. This requirement creates a challenge for traditional empirical models designed for component protection at high speed-load conditions. Simulation results show that a physics aligned model can estimate temperature in all operating conditions, including: cold-start, extended idle, engine shutdown, stop-start events, deceleration fuel shut-off, as well as traditional high load and part load points.

Cast aluminum alloys are used for cylinder heads in internal combustion engines to meet low weight and high strength (lightweight) design requirements. In the combustion chamber, the alloy experiences harsh operating conditions; i.e., temperature variation, constrained thermal expansion, chemical reaction, corrosion, oxidation, and chemical deposition. Under these conditions, thermomechanical fatigue (TMF) damage arises in the form of mechanical damage, environmental (oxidation) damage, and creep damage. In the present work, several important properties that influence the TMF life of the cylinder head have been identified through TMF and finite element analysis (FEA). The results show that improving the strength at high temperatures helps improve TMF life on the exhaust side of the head. On the other hand, improving strength and ductility extend TMF life at low temperature on the intake side.

As European and Chinese tailpipe emission regulations for gasoline light-duty vehicles impose particulate number limits, automotive manufacturers have begun equipping some vehicles with a gasoline particulate filter (GPF). Increased understanding of how soot morphology, reactivity, and GPF loading affect GPF filtration and regeneration characteristics is necessary for advancing GPF performance. This study investigates the impacts of morphology, reactivity, and filter soot loading on GPF filtration and regeneration. Soot morphology and reactivity are varied through changes in fuel injection parameters, known to affect soot formation conditions. Changes in morphology and reactivity are confirmed through analysis using a transmission electron microscope (TEM) and a thermogravimetric analyzer (TGA) respectively.

The Catalytic Converter along with the inlet pipe and heat shields are part of the exhaust system that emits powerful heat to the surrounding components. With increasing need for tight under-hood spaces it is very critical to manage the heat emitted by the exhausts that may significantly increase temperature of surrounding components. In this paper a design methodology for catalytic converter has been applied which optimizes the design of the catalytic converter to reduce the surface temperature. The exhaust surface temperature is simulated as a function of time to account for transient effects. The simulation also considers various duty cycles such as road load, city traffic and grade driving conditions. To control the heat output of the exhaust system to the surrounding components different materials and properties of catalytic converter have been considered to reduce radiative heat transfer.

This research proposes a control system for Spark Ignition (SI) engines with external Exhaust Gas Recirculation (EGR) based on model predictive control and a disturbance observer. The proposed Economic Nonlinear Model Predictive Controller (E-NMPC) tries to minimize fuel consumption for a number of engine cycles into the future given an Indicated Mean Effective Pressure (IMEP) tracking reference and abnormal combustion constraints like knock and combustion variability. A nonlinear optimization problem is formulated and solved in real time using Sequential Quadratic Programming (SQP) to obtain the desired control actuator set-points. An Extended Kalman Filter (EKF) based observer is applied to estimate engine states, combining both air path and cylinder dynamics. The EKF engine state(s) observer is augmented with disturbance estimation to account for modeling errors and/or sensor/actuator offset.

Optical and laser diagnostics enable in-depth spray characterization in regards to macroscopic spray characteristics and in-situ fuel mixture quality information, which are needed in understanding the spray injection process and for spray model development, validation and calibration. Use of fuel surrogates in spray researches is beneficial in controlling fuel parameters, developing spray and combustion kinetic models, and performing laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of a single and multi-component surrogate in comparison to a gasoline with 10% ethanol under gasoline direct injection (GDI) engine conditions. In addition, the effect of fuel tracers on spray evolution and vaporization is also investigated. Both diethyl-methyl-amine/fluorobenzene as a laser-induced exciplex (LIEF) fluorescence tracer pair and 3-pentanone as a laser-induced fluorescence (LIF) tracer are examined.

The Three Way Catalyst (TWC) is an effective pollutant conversion system widely used in current production vehicles to satisfy emissions regulations. A TWC’s conversion efficiency degrades over time due to chemical and/or thermal mechanisms causing the catalyst to age. This reduction in conversion efficiency must be accounted for to ensure full useful life emissions compliance. This paper presents an experimental study of the aging impact on TWC performance. Four TWCs differentiated by their age, given in terms of miles driven, were tested. It is shown that the dynamics of oxygen storage are substantially affected by aging of the TWC. A previously developed physics-based oxygen storage model [1] is subsequently used to incorporate the effect of aging on the total Oxygen Storage Capacity (OSC). Parameter identification results for the different age catalysts show that total oxygen storage capacity decreases substantially with aging and is insensitive to operating conditions.

New Particulate Matter (PM) and Particulate Number (PN) regulations throughout the world have created a need for aftertreatment solutions that include particulate control as an option to comply with the legislation. However, limitations in other criteria emissions cannot be sacrificed to accomplish the reduction of PM/PN. For this work, three-way washcoat catalyzed wall-flow Gasoline Particulate Filters (GPF) and similarly catalyzed flow-through catalysts of common defined volume were tested. Their catalytic performance was determined by measuring NOx, CO and HC conversion efficiencies and CO2 levels over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) cycles. Analysis of the impact on CO2 emissions was also evaluated in relation to backpressure from 1-D modeling analysis. All exhaust systems used the same loading and ratio of Platinum Group Metals (PGM), but employed different cell structures in their substrates.

In order to meet LEV III, EURO 6C and Beijing 6 emission levels, Original Equipment Manufacturers (OEMs) can potentially implement unique aftertreatment systems solutions which meet the varying legislated requirements. The availability of various washcoat substrates and PGM loading and ratio options, make selection of an optimum catalyst system challenging, time consuming and costly. Design for Six Sigma (DFSS) methodologies have been used in industry since the 1990s. One of the earliest applications was at Motorola where the methodology was applied to the design and production of a paging device which Consumer Reports called “virtually defect-proof”.[1] Since then, the methodology has evolved to not only encapsulate complicated “Variation Optimization” but also “Design Optimization” where multiple factors are in play. In this study, attempts are made to adapt the DFSS concept and methodology to identify and optimize a catalyst for diesel applications.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III Emissions Standards for Light Duty Diesel passenger vehicles (LDD). As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, robustness and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR) catalyst. The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) typically provided as urea, adequate operating temperatures, and optimum Nitrogen Dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is mostly influenced by Precious Group Metals (PGM) containing catalysts located upstream of the SCR catalyst. Different versions of zeolite based SCR technologies are available on the market today and these vary in their active metal type (iron, copper, vanadium), and/or zeolite type.

In this paper, the development of a transient thermal analysis model for the exhaust system is presented. Given the exhaust gas temperature out of the engine, a software tool has been developed to predict changes in exhaust gas temperature and exhaust surface temperature under various operating conditions. The software is a thermal solver that will predict exhaust gas and wall surface temperatures by modeling all heat transfer paths in the exhaust system which includes multi-dimensional conduction, internal forced/natural convection, external forced/natural convection, and radiation. The analysis approach involves the breaking down of the thermal system into multiple components, which include the exhaust system (manifold, takedown pipe, tailpipe, etc.), catalytic converter, DPF (diesel particulate filter), if they exist, thermal shields, etc. All components are modeled as 1D porous and 1D non-porous flow streams with 3D wall layers (solid and air gaps).