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Formation of nitrogen oxides (NOx) in direct-injection premixed charge compression ignition (DI-PCCI) combustion simulated in a constant volume vessel was investigated using an ignition-combustion model that combines a stochastic mixing model with a reduced chemical reaction scheme. Several improvements were made to the model in order to predict the combustion processes in DI-PCCI. Calculations were carried out for the injection and ambient conditions equivalent to the measurements using the constant volume vessel. Analysis of the calculated results clarified the effects of mixture heterogeneity on NO concentrations and the mechanisms are discussed. The results show that the model successfully represents the experimental tendency for NO concentration when the injection conditions and ambient oxygen mole fraction are varied.

The effects of fuel injection conditions (injection pressure, nozzle orifice diameter and fuel injection quantity) on NOx formation in direct-injection Premixed Charge Compression Ignition (DI-PCCI) combustion were investigated using a constant-volume vessel and a total gas-sampling device. The results show that promotion of fuel-air mixing reduces final NOx mass accompanying a delayed hot flame. In particular, under low oxygen mole fraction conditions, in addition to the hot flame delay, the promotion of fuel-air mixing results in a lower heat release rate. In this case, the final NOx mass is further reduced. For a fixed nozzle orifice diameter, the final NOx mass is reduced with increasing injection pressure. This effect is remarkable for smaller nozzle orifice diameters. Regardless of the oxygen mole fraction, under the low injection fuel quantity condition, enhancement of fuel-air mixing reduces the final NOx mass per released heat.

Aim of this study is to clarify the NOx formation mechanism in diesel combustion under high-supercharged condition. Effects of ambient conditions and fuel injection parameters on diesel combustion were investigated using a constant volume chamber. NOx formation process was investigated using a total gas-sampling device. The results indicate that by using the above experimental setup it is possible to realize entirely diffusion combustion like what seen in the highly supercharged condition. Increasing ambient pressure up to 8MPa with high injection pressure shortens the ignition delay and offers a heat release rate proportional to the fuel injection rate with a short combustion duration. Increasing ambient pressure gives a higher NOx formation rate and final NOx concentration. This is due to enhancement in the fuel-air mixing which promotes the heat release.