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Global demand for alternative fuels to combat rising energy costs has sparked a renewed interest in catalysts that can effectively remediate NOx emissions resulting from combustion of a range of HC based fuels. Because many of these new engine technologies rely on lean operating environments to produce efficient power, the resulting emissions are also present in a lean atmosphere. While HCs are easily controlled in such environments, achieving high NOx conversion to N2 has continued to elude fully satisfactory solution. Until recently, most approaches have relied on catalysts with precious metals to either store NOx and subsequently release it as N2 under rich conditions, or use NH3 SCR catalysts with urea injection to reduce NOx under lean conditions. However, new improvements in Ag based technologies also look very promising for NOx reduction in lean environments.

Low-cost lean NOx aftertreatment is one of the main challenges facing high-efficiency gasoline and diesel engines operating with lean mixtures. While there are many candidate technologies, they all offer tradeoffs. We have investigated a multi-component Dual SCR aftertreatment system that is capable of obtaining NOx reduction efficiencies of greater than 90% under lean conditions, without the use of precious metals or urea injection into the exhaust. The Dual SCR approach here uses an Ag HC-SCR catalyst followed by an NH3-SCR catalyst. In bench reactor studies from 150 °C to 500 °C, we have found, for modest C/N ratios, that NOx reacts over the first catalyst to predominantly form nitrogen. In addition, it also forms ammonia in sufficient quantities to react on the second NH3-SCR catalyst to improve system performance. The operational window and the formation of NH3 are improved in the presence of small quantities of hydrogen (0.1–1.0%).

Diesel engines offer better fuel economy compared to their gasoline counterpart, but simultaneous control of NOx and particulates is very challenging. The blended 2-way SCR/DPF is recently emerging as a compact and cost-effective technology to reduce NOx and particulates from diesel exhaust using a single aftertreatment device. By coating SCR catalysts on and inside the walls of the conventional wall-flow filter, the 2-way SCR/DPF eliminates the volume and mass of the conventional SCR device. Compared with the conventional diesel aftertreatment system with a SCR and a DPF, the 2-way SCR/DPF technology offers the potential of significant cost saving and packaging flexibility. In this study, an engine dynamometer test cell was set up to repeatedly load and regenerate the SCR/DPF devices to mimic catalyst aging experienced during periodic high-temperature soot regenerations in the real world.

The need for improved emissions control in lean exhaust to meet tightening, world-wide NOx emissions standards has led to the development of selective catalytic reduction of NOx with ammonia as a major technology for emissions control. Current systems are being designed to use a solution of urea (32.5 wt %) dissolved in water or Diesel Exhaust Fluid (DEF) as the ammonia source. While DEF or AdBlue® is widely used as a source of ammonia, it has a number of issues at low temperatures, including freezing below −12 °C, solid deposit formation in the exhaust, and difficulties in dosing at exhaust temperatures below 200 °C. Additionally creating a uniform ammonia concentration can be problematic, complicating exhaust packaging and usually requiring a discrete mixer.

A fully flexible valve actuation (FFVA) system was developed for a single cylinder research engine to investigate high efficiency clean combustion (HECC) in a diesel engine. The main objectives of the study were to examine the emissions, performance, and combustion characteristics of the engine using late intake valve closing (LIVC) to determine the benefits and limitations of this strategy to meet Tier 2 Bin 5 NOx requirements without after-treatment. The most significant benefit of LIVC is a reduction in particulates due to the longer ignition delay time and a subsequent reduction in local fuel rich combustion zones. More than a 95% reduction in particulates was observed at some operating conditions. Combustion noise was also reduced at low and medium loads due to slower heat release. Although it is difficult to assess the fuel economy benefits of LIVC using a single cylinder engine, LIVC shows the potential to improve the fuel economy through several approaches.

Implementation of real-time combustion feedback for use in closed-loop combustion control is a technology that has potential to assist in the successful production implementation of advanced diesel combustion modes. Low-temperature, pre-mixed diesel combustion is presently of interest because it offers the ability to lower the engine-out emissions of oxides of nitrogen (NOx) and particulate matter (PM). The need for lowering these two emissions is driven by tighter regulations enacted worldwide, especially the NOx limits in the United States. Reducing engine-out emissions eases the need for additional exhaust aftertreatment devices and their associated cost and mass. In this paper we will describe an experimental cylinder pressure-based control system and present both steady-state and transient results from a diesel engine employing a pre-mixed type of combustion.

2-step variable valve actuation using early-intake valve closing is a strategy for high fuel economy on spark-ignited gasoline engines. Two discrete valve-lift profiles are used with continuously variable cam phasing. 2-step VVA systems are attractive because of their low cost/benefit, relative simplicity, and ease-of-packaging on new and existing engines. A 2-step VVA system was designed and integrated on a 4-valve-per-cylinder 4.2L line-6 engine. Simulation tools were used to develop valve lift profiles for high fuel economy and low NOx emissions. The intake lift profiles had equal lift for both valves and were designed for high airflow & residual capacity in order to minimize valvetrain switching during the EPA drive cycle. It was determined that an enhanced combustion system was needed to maximize fuel economy benefit with the selected valve lift profiles. A flow-efficient chamber mask was developed to increase in-cylinder tumble motion and combustion rates.

Close-coupled or manifold catalysts have been extensively employed to reduce emissions during cold start by achieving quick catalyst light-off. These catalysts must have good thermal durability, high intrinsic light-off activity and high HC/CO/NOx conversions at high temperature and flow conditions. A number of studies have been dedicated to engine control, manifold design and converter optimization to reduce cold start emissions. The current paper focuses on the effect of catalyst design parameters and their performance response to different engine operating conditions. Key design parameters such as catalyst formulation (CeO2 vs. non CeO2), precious metal loading and composition (Pd vs. Pd/Rh), washcoat loading, catalyst thermal mass, substrate properties and key application (in use) parameters such as catalyst aging, exhaust A/F ratio, A/F ratio modulation, exhaust temperature, temperature rise rate and exhaust flow rate were studied on engine dynamometers in a systematic manner.

Superior fuel economy was achieved for a small-displacement spark-ignition direct-injection (SIDI) engine by optimizing the stratified combustion operation. The optimization was performed using computational analyses and subsequently testing the most promising configurations experimentally. The fuel economy savings are achieved by the use of a multihole injector with novel spray shape, which allows ultra-lean stratification for a wide range of part-load operating conditions without compromising smoke and hydrocarbon emissions. In this regard, a key challenge for wall-controlled SIDI engines is the minimization of wall wetting to prevent smoke, which may require advanced injection timings, while at the same time minimizing hydrocarbon emissions, which may require retarding injection and thereby preventing over-mixing of the fuel vapor.

A new single-brick Ba + alkali metals NOx-Trap catalyst has been developed to replace a two-brick NOx-Trap system containing a downstream three-way catalyst. Major development efforts include: 1) platinum group metals selection for higher HC oxidation with potassium-containing washcoat, 2) alumina and ceria selection, and Rh architecture design for more efficient NOx reduction and 3) NiO to suppress H2S odor. Mitsubishi Motors' 1.8L GDI™ with this Delphi new NOx-Trap catalyst with H2S control achieves J-LEV standard with less cost and lower backpressure compared to the previous model. It is further discovered that incorporation of NiO into the NOx-Trap washcoat is effective for H2S control during sulfur purge but has a negative impact on thermal durability and sulfur resistance. Further study to improve this trade-off has been made and preliminary results of an advanced washcoat design are presented in this paper. Details will be reported in a future publication.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

As automotive exhaust emission levels reduce, there is a need for increased sensitivity of the NOx measurement. This paper documents work performed to increase the sensitivity of the existing Rosemount NGA 2000 CLD Analyzer. The effects of sample flow rate, ozone flow rate and ozone supply gas were explored. Limit of Detection (LOD) and Converter Efficiency were evaluated. The goal of this optimization has been to provide a cost effective and expeditious method to improve the low level NOx measurement. Changing the ozone generator supply gas from air to oxygen and increasing the sample and ozone flow rates resulted in a LOD improvement from 17 ppb to 8 ppb.

Experimentally obtained combustion responses of a typical reverse-tumble wall-controlled direct-injection stratified-charge engine to operating variables are described. During stratified-charge operation, the injection timing, ignition timing, air-fuel ratio, and levels of exhaust gas recirculation (EGR) generally determine the fuel economy and emissions performance of the engine. A detailed heat-release analysis of the experimental cylinder-pressure data was conducted. It was observed that injection and ignition timings determine the thermal efficiency of the engine by controlling primarily the combustion efficiency of the stratified charge. Hence, combustion phasing is determined by a compromise between work-conversion efficiency and combustion efficiency. To reduce nitric-oxide (NOx) emissions, a reduction in overall air-fuel ratio as well as EGR addition is required.

Three-way catalysts provide a means of catalytically achieving lower NOx emission levels while maintaining good control of HC and CO emissions. However, very accurate control of air-fuel ratio is necessary. The precise air-fuel ratio control required is accomplished by employing a closed loop fuel metering system in conjunction with an exhaust gas sensor and an electronic control unit. To gain production experience with this type of system, General Motors is introducing it on two 1978 engine families sold in California. One is a 2.5 litre L-4 engine and the other is a 3.8 litre V-6 engine. Closed loop controlled carburetors are used on both systems. This paper discusses these 1978 systems. The components used on both systems are described and emission and fuel economy results are reviewed.

The stringent 1978 emission standards of 0.41 gm/mi HC, 3.4 gm/mile CO, and 0.4 gm/mi NOx may require the use of a dual catalytic converter system (reducing and oxidizing catalyst). These emission requirements have been achieved at low mileage with such a system, but it is complex and has exhibited poor durability. This system also results in the loss of fuel economy at the 1978 emission levels.