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Technical Paper

The performance of diesel engine oil using ashless anti-wear additive and detergent

2023-09-29
2023-32-0027
To comply with increasingly strict emission regulations, diesel vehicles are equipped with Diesel Particulate Filters (DPF) to capture fine particulate matter (PM) from exhaust gas. However, due to the limited capacity of DPF to capture soot, periodic regeneration processing is required to burn it off. The ash created by metal-based additives in engine oil accumulates in DPF, leading to issues such as increased regeneration frequency and decreased fuel efficiency. To solve this problem, researchers have developed diesel engine oil with reduced ash content. However, the authors are taking it a step further and developing a diesel engine oil without metal-based detergents and anti-wear additives, for even more significant environmental impact reduction. This paper describes the development of an ashless engine oil with DH-2 performance, the effects of the developed engine oil on DPF, and the results of engine and actual field tests.
Technical Paper

Improvement of HC-SCR Performance by Fuel Reforming Using a Low Temperature Oxidation

2021-04-06
2021-01-0591
A fuel reforming technology using a low temperature oxidation was developed to improve a NOx reduction performance of HC-SCR (Hydrocarbons Selective Catalytic Reduction) system, which does not require urea. The low-temperature oxidization of a diesel fuel in gas phase produces NOx reduction agents with high NOx reduction ability such as aldehydes and ketones. A pre-evaporation-premixing-type reformer was adopted in order to generate a uniform temperature field and a uniform fuel/air premixed gas, and to promote the low temperature oxidation efficiently. As a fundamental study, elementary reaction analysis for n-hexadecane/air premixtures was carried out to investigate the suitable reformer temperature and fuel/air equivalence ratio for generation of oxygenated hydrocarbons. It was found that the reforming efficiency was highest at the reforming temperature around 623 to 673K, and aldehydes and ketones were produced.
Technical Paper

Numerical Investigation of Near Nozzle Flash-Boiling Spray in an Axial-Hole Transparent Nozzle

2020-04-14
2020-01-0828
Understanding and prediction of flash-boiling spray behavior in gasoline direct-injection (GDI) engines remains a challenge. In this study, computational fluid dynamics (CFD) simulations using the homogeneous relaxation model (HRM) for not only internal nozzle flow but also external spray were evaluated using CONVERGE software and compared to experimental data. High-speed extinction imaging experiments were carried out in a real-size axial-hole transparent nozzle installed at the tip of machined GDI injector fueled with n-pentane under various ambient pressure conditions (Pa/Ps = 0.07 - 1.39). The width of the spray during injection was assessed by means of projected liquid volume, but the structure and timing for boil-off of liquid within the sac of the injector were also assessed after the end of injection, including cases with different designed sac volumes.
Technical Paper

Transient Internal Nozzle Flow in Transparent Multi-Hole Diesel Injector

2020-04-14
2020-01-0830
An accurate prediction of internal nozzle flow in fuel injector offers the potential to improve predictions of spray computational fluid dynamics (CFD) in an engine, providing a coupled internal-external calculation or by defining better rate of injection (ROI) profile and spray angle information for Lagrangian parcel computations. Previous research has addressed experiments and computations in transparent nozzles, but less is known about realistic multi-hole diesel injectors compared to single axial-hole fuel injectors. In this study, the transient injector opening and closing is characterized using a transparent multi-hole diesel injector, and compared to that of a single axial hole nozzle (ECN Spray D shape). A real-size five-hole acrylic transparent nozzle was mounted in a high-pressure, constant-flow chamber. Internal nozzle phenomena such as cavitation and gas exchange were visualized by high-speed long-distance microscopy.
Technical Paper

Research on a DPF Regeneration Burner System for Use when Engine is not in Operation

2019-12-19
2019-01-2237
An on board burner that enables DPF regeneration even when an engine is at standstill has been researched. By employing pre evaporative combustion with a wick burner, miniaturization of the burner system was successfully accomplished as well as stable ignition and combustion. Total heat necessary for DPF regeneration was reduced in comparison to the active DPF regeneration by means of engine control and an oxidation catalyst. Uneven temperature distribution in DPF and excessive temperature rise, which had been recognized as issues in the regeneration of a DPF while engine is at standstill, were solved by increase of combustion air amount and multi-step control of regeneration temperature and reliable regeneration was accomplished.
Journal Article

Influence of Combustion Chamber Shape and In-Cylinder Density on Soot Formation in Diesel Combustion

2019-12-19
2019-01-2271
The change in the smoke emissions from a diesel engine with the shapes of the combustion chamber and the in-cylinder density was investigated with focuses on the mixing and the soot formation in a spray flame. First, the mixing of the fuel and air between the nozzle exit and the set-off length was used as an indicator for the formation of soot. Although this indicator can explain the influence of the density, it cannot explain the changes in the smoke emissions with a change in the shape of the combustion chamber. Next, by focusing on the soot distribution in a quasi-steady-state spray flame, the soot formed in the high-density condition of an optically accessible engine was investigated by applying two-color method. These results showed that the positional relationship between the maximum soot amount position and the flame impinging position can be a major influence on the smoke emissions.
Technical Paper

Piston Detergency and Anti-Wear Performance of Non-Phosphorus and Non-Ash Engine Oil

2019-01-15
2019-01-0021
The deposition of ash derived from engine oil on the surface of diesel particle filters (DPF) has recently been reported to degrade the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst, reducing the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus, non-ash engine oil (NPNA) that does not contain metal-based detergents or zinc dialkyldithiophosphate (ZnDTP). Various engine tests were performed, and we confirmed that under normal running conditions, the NPNA oil had a sufficiently high piston detergency and wear resistance-two important requirements for engine oil-to meet current American and Japanese standards. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.
Technical Paper

Oxidative Deterioration Properties of FAME-Blended Diesel Fuel

2018-04-03
2018-01-0924
The correlation between newly approved EN 15751 and the internal diesel injector deposits (IDID) due to fuel oxidative deterioration has not been made clear. In the present research, the Rancimat method was slightly modified to research the relationship between fuel oxidative deterioration and the deterioration products generated from the fuel. After heating fuel at 120 to 150°C for a set period, insoluble deterioration products (IDID-like substances) were generated and their weights were measured. At the same time, the shifts of the conductivity in trap water were analyzed from a new perspective, and its relationship with the deterioration products was investigated. At 120°C and 130°C, conductivity rising rates after the inflection point (this set of data represents the rate of organic acid generation in the fuel, and we named “Oxidation rate”) exhibited a strong correlation with the quantity of deterioration products.
Technical Paper

A Study on Reducing Cooling loss in a Partially Insulated Piston for Diesel Engine

2018-04-03
2018-01-1276
To improve the thermal efficiency of an engine, it is particularly important to reduce the cooling loss from the combustion gas to the combustion chamber wall, which constitutes a major proportion of the total loss [1]. Previous studies addressing cooling loss reduction attempted to use ceramic in place of the conventional aluminum or iron alloys, but this led to a reduction in the volumetric efficiency and increased smoke emissions. This was caused by the ceramics having both a low thermal conductivity and high heat capacity, relative to aluminum and iron. These characteristics cause the piston wall temperature, which rises during combustion, to remain high during the intake stroke, thus increasing the intake temperature and reducing the volumetric efficiency. This increases the smoke emissions [2].
Technical Paper

Steric Effects on Tribochemical Reactivity in Detergent-Containing Lubricants under Nanoconfinement

2017-10-08
2017-01-2347
Modern formulation in a wide variety of lubricants including engine oils and transmission fluids is designed to control friction through film-forming tribochemical reactions induced by the functional additives mixtures. Although many cases on the synergistic or antagonistic effects of additives on friction have been reported, their mechanisms are poorly understood. This study focused on the influences of metallic detergents on tribochemical reactions. We examined the mechanical properties of detergent-containing lubricants confined at a single-asperity contact and their contributions to tribochemical phenomena. We found that detergents enlarged the confinement space required for generating repulsive force and shear resistance. This means that these detergents provide steric effects under nanoconfinement at interfacial contacts.
Technical Paper

A Study on the Effects of a Higher Compression Ratio in the Combustion Chamber on Diesel Engine Performance

2016-04-05
2016-01-0722
In order to improve the brake thermal efficiency of the engine, such as cooling and friction losses from the theoretical thermal efficiency, it is necessary to minimize various losses. However, it is also essential to consider improvements in theoretical thermal efficiency along with the reduction of the various losses. In an effort to improve the brake thermal efficiency of heavy-duty diesel engines used in commercial vehicles, this research focused on two important factors leading to the engine's theoretical thermal efficiency: the compression ratio and the specific heat ratio. Based on the results of theoretical thermodynamic cycle analyses for the effects of the above two factors, it was predicted that raising the compression ratio from a base engine specification of 17 to 26, and increasing the specific heat ratio would lead to a significant increase in theoretical thermal efficiency.
Journal Article

Influence of Ca-, Mg- and Na-Based Engine Oil Additives on Abnormal Combustion in a Spark-Ignition Engine

2015-11-17
2015-32-0771
One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.
Technical Paper

Development of Fuel Economy Engine Oil for Heavy Duty Diesel Engine

2015-09-01
2015-01-2034
More stringent emissions regulations, fuel economy standards, and regulations are currently being discussed to help reduce both CO2 and exhaust emissions. Vehicle manufacturers have been developing new engine technologies, such as downsizing and down-speeding with reduced friction loss, improved engine combustion and efficiency, heat loss recycling, power-train friction loss recycling, and reduced power-train friction loss. The use of more efficient fuel economy 5W-30 engine oils for heavy duty commercial vehicles has started to expand since 2009 in Japan as one technological solution to help reduce CO2 emissions. However, fuel economy 5W-30 oils for use in heavy duty vehicles in Europe are mainly based on synthetic oils, which are much expensive than the mineral oils that are predominantly used in Japan.
Technical Paper

The Effect of Ashless Additives for Non-Phosphorus and Non-Ash Engine Oil on Piston Detergency

2015-09-01
2015-01-2031
Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.
Technical Paper

Characterization of Emissions from Urea-SCR and DPF System for Heavy Duty Engine

2015-09-01
2015-01-2016
Urea selective catalyst reduction (SCR) systems have a high NOx conversion rate because the ammonia formed by the hydrolyzing urea solution reacts with NOx efficiently as a reducing agent. Systems combining urea-SCR and a diesel particulate filter (DPF) have been adopted in heavy duty vehicles to meet the post new long term emissions regulations in Japan. This study examined the emissions reduction performance of these systems after 160,000 km. The emissions that were examined included both regulated emissions (NOx, PM, HC, and CO) and unregulated emissions. As a result, the cleanness of diesel emissions from a urea-SCR and DPF system was confirmed.
Journal Article

Abnormal Combustion Induced by Combustion Chamber Deposits Derived from Engine Oil Additives in a Spark-Ignited Engine

2014-11-11
2014-32-0091
Although metallic compounds are widely known to affect combustion in internal combustion engines, the potential of metallic additives in engine oils to initiate abnormal combustion has been unclear. In this study, we investigated the influence of combustion chamber deposits derived from engine oil additives on combustion in a spark-ignited engine. We used a single-cylinder four-stroke engine, and measured several combustion characteristics (e.g., cylinder pressure, in-cylinder ultraviolet absorbance in the end-gas region, and visualized flame propagation) to evaluate combustion anomalies. To clarify the effects of individual additive components, we formed combustion products of individual additives in a combustion chamber prior to measuring combustion characteristics. We tested three types of metallic additives: a calcium-based detergent, a zinc-based antiwear agent, and a molybdenum-based friction modifier.
Journal Article

Impact of Boundary Lubrication Performance of Engine Oils on Friction at Piston Ring-Cylinder Liner Interface

2014-10-13
2014-01-2787
To explore the measures that can be used to improve the fuel economy of internal combustion engines, we investigated how friction at the piston ring-cylinder liner interface is influenced by the boundary lubrication performance of engine oils. We formulated several engine oils with varying boundary lubrication performance and tested them for ring-liner friction by using a floating liner friction tester. We used friction modifiers (FMs) to modify the boundary lubrication performance of engine oils. We found that ring-liner friction is well correlated with the friction coefficients in boundary lubrication regimes when measured by a laboratory friction tester. We also found that the impact of the boundary lubrication performance of engine oils was emphasized in low viscosity engine oils. It makes it possible for improved boundary lubrication performance to inhibit or overcome the viscosity reduction-induced increase of friction energy.
Journal Article

Engine Oil Development for Preventing Pre-Ignition in Turbocharged Gasoline Engine

2014-10-13
2014-01-2785
Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.
Technical Paper

Impact of Non-Phosphorus and Non-Ash Engine Oil on After-Treatment Devices

2014-10-13
2014-01-2782
Automobile exhaust gas contains various harmful substances other than carbon dioxide, so exhaust gas post-processing devices have been developed to reduce their environmental load. Engine oil has contributed to the improvement of automobiles' environmental performance due to its excellent fuel-saving and long-drain properties. Recently, the lifetime of an exhaust gas post-processing device has been reported to decrease due to ash and phosphorus in engine oil. We have developed non-phosphorus and non-ash engine oil (NPNA), in which metal-based detergents and zinc dialkyldithiophosphate (ZnDTP) were not contained. We have performed a verification test for NPNA using an actual engine. In a performance test for a diesel particulate filter (DPF), the amount of soot and ash deposited onto a DPF was smaller when NPNA was used than when commercially available engine oil was used.
Technical Paper

Development of Road's Gradient Anticipatory Algorithm for Hybrid Heavy Duty Truck

2014-09-30
2014-01-2377
For the purpose of reducing fuel consumption, a hybrid heavy duty truck was considered. Generally, HV (Hybrid Vehicle)'s energy is regenerated from deceleration energy in urban area. Hybrid heavy duty truck's energy is regenerated from potential energy on highway. Under this circumstance, some portion of energy may not be accumulated, because capacity of HV battery is limited. In order to maximize accumulating energy in the next descent, HV battery's energy shall be adequately reduced beforehand. This can be achieved by optimizing motor assist torque considering road's altitude and gradient. In this paper, performance of the algorithm is discussed.
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