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HEV and PHEV require an improved aftertreatment system to clean the exhaust gas in various driving situations. The efficiency of aftertreatment system is significantly influenced by the residence time of the gas in a catalyst which gas flow has generally strong pulsation. Simulation showed up to 70% reduction of exhaust gas emission if the pulsation could be completely attenuated. A new concept exhaust manifold was designed to minimize pulsation flow by wall impingement, with slight increase of pressure loss. Experimental results with new concept exhaust manifold showed exhaust gas emission were reduced 16% at cold condition and 40% at high-load condition.

Global focus on CO2 reduction and environmental protection is increasing. To comply with stricter exhaust gas regulations and reduce real world emissions, it is becoming increasingly important to improve the performance of three-way catalysts. Therefore, highly efficient conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) is required. In general, the more active the precious metals used, the better the conversion performance. However, precious metals have supply risks, such as price fluctuation and the uneven distribution of production areas. Therefore, it is necessary to lower emissions while also lowering the amount of precious metals used. This paper focuses on how catalysts are used and describes the development of a new three-way catalyst for the purpose of strengthening cold conversion and decreasing the usage of precious metals.

To prevent global warming, many countries are making efforts to reduce CO2 emissions toward achieving 2050 carbon neutrality. In order to reduce CO2 concentration quickly, in addition to spread of renewable energy and expansion of BEV, it is also important to reduce CO2 emissions by improving thermal efficiency of ICE (internal combustion engine) and utilizing carbon neutral fuels such as synthetic fuels and biofuels. It is well known that lean burn is an effective technology to increase thermal efficiency of engine highly. However, since NOx emission from lean burn engine cannot be reduced with three-way catalyst, there have been issues such as complicated system configuration due to the addition of NOx reduction catalyst or limiting lean operation to narrow engine speed and load in order to meet emission regulation of each country.

Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.

In recent years, electrically heated catalysts (EHCs) have been developed to achieve lower emissions. In several EHC heating methods, the direct heating method, which an electric current is applied directly to the catalyst substrate, can easily activate the catalyst before engine start-up. The research results reported on the use of the direct heating EHC to achieve significant exhaust gas purification during cold start-up [1]. From the perspective of catalyst loading, ceramics is considered to be a better material for the substrate than metal due to the difference in coefficient of thermal expansion between the catalyst and the substrate, but the EHC made of ceramics has difficulties such as controllability of the current distribution, durability and reliability of the connection between the substrate and the electrodes.

In recent years, GPFs (Gasoline particulate filters) have been installed in gasoline engines to comply with stricter environmental regulations in China and Europe. In particular, coated-GPFs having a catalytic purification function are required to have high conversion performances, high filter efficiencies in the sense of a high collection efficiency, and low pressure loss. It is not easy to design a filter that satisfies all these parameters. Experimental studies are being conducted, but it is costly to study in trial productions. In this technical paper, a GPF design optimization method will be proposed that combines multi-scale simulation, surrogate models by machine learning, and an optimization algorithm. By using this method, a GPF design that minimizes pressure loss while providing high conversion performance and particle collection rates that satisfy current regulations can be created.

The first MIRAI was launched in 2014 as the world’s first commercial fuel cell vehicle (FCV) [1]. Compared to the FC stack used in the first MIRAI, the FC stack in the new MIRAI achieved one of the highest volumetric power densities in the world (5.4 kW/L, excluding end plates, 1.5 times higher than the FC stack in the first MIRAI) by adopting a new flow channel for the bipolar plate and an improved electrode [2]. Enhancing the current density is an important means of increasing power performance and reducing size. The bipolar plate functions to distribute gas and drain water inside the cells to stabilize current generation. However, a conventional straight flow channel tends to cause flooding, which makes it difficult to maintain stable current generation. A partially narrow flow channel was developed to enhance oxygen diffusion without the 3D fine-mesh flow field that was adopted in the previous FC stack.

Combustion of a lean air-fuel mixture diluted with a large amount of air or Exhaust Gas Recirculation (EGR) gas is one of the important technologies that can reduce thermal NOx and improve gasoline engine fuel economy by reducing cooling loss. On the other hand, lean combustion increases unburned Hydro Carbon (HC) and unburned loss compared to stoichiometric combustion. This is because lean combustion reduces the burning rate of the air-fuel mixture and forms a thick quenching layer near the wall surface. In this study, the relationship between the thickness of the unburned HC and the excess air ratio is analyzed using Laser Induced Fluorescence (LIF) method and Computational Fluid Dynamic (CFD) of combustion. The HC distribution near the engine liner when the excess air ratio is increased is investigated by LIF. As a result, it is found that the quenching distance of the flame in the cylinder is larger for lean conditions than the general single-wall quenching relationship.

Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.

Increasingly stringent regulations call for the reduction of emissions at engine startup to purify exhaust gas and reduce the amount of CO2 emitted. Air-fuel ratio (A/F) sensors detect the composition of exhaust gas and provide feedback to control the fuel injection quantity in order to ensure the optimal functioning of the catalytic converter. Reducing the time needed to obtain feedback control and enabling the restriction-free installation of A/F sensors can help meet regulations. Conventional sensors do not activate feedback control immediately after engine startup as the combination of high temperatures and splashes of condensed water in the exhaust pipe can cause thermal shock to the sensor element. Moreover, sensors need to be installed near the engine to increase the catalyst reaction efficiency. This increases the possibility of water splash from the condensed water in the catalyst.

To correspond to the social requirements such as climate change, air pollution, and energy security, enhancing the engine thermal efficiency is strongly required in these days. As for the specific engine technologies to improve the engine thermal efficiency, Atkinson cycle, cooled EGR (Exhaust Gas Recirculation), and low friction technologies have been developed [1–4]. In regard to combustion technology, lean boosted concept has a potential to reduce CO2 emission because lean boosted concept is expected to enhance the engine thermal efficiency. Although expanding lean combustion limit is important for both increasing the engine thermal efficiency and reducing NOx emission, there is a limitation to realize stable lean combustion with SI (Spark Ignition) gasoline engine. In this study, fuel effects on the combustion characteristics from the viewpoint of chemical reaction capability are focused on.

The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.

With accelerating exhaust gas regulations in recent years, not only CO / HC / NOx but also PN regulation represented by Euro 6 d, China 6 are getting stricter. PN reduction by engine combustion technology development also progresses, but considering RDE, PN reduction by after treatment technology is also indispensable. To reduce PN exhausted from the gasoline engine, it is effective to equip GPF with a filter structure. Considering the installation of GPF in limited space, we developed a system that so far replaces the second TWC with GPF for the TWC 2 bed system. In order to replace the second TWC with GPF, we chose the coated GPF with filtering and TWC functions. Since the initial pressure drop and the catalyst amount (purification performance) of coated GPF have a conflicting relationship, we developed the coated GPF that can achieve both the low initial pressure drop and high purification performance.

In recent years along with stringent the regulations, vehicles equipped with gasoline particulate filter (GPF) have started to launch. Compared to bare GPF, coated GPF (cGPF) requires not only PN filtration efficiency, low pressure drop, but also purification performance. In the wall flow type cGPF having a complicated the pore shape, the pore structure further irregularly changes depending on the coated state of the catalyst, so it is difficult to understand the matter of in-wall. In order to advance of cGPF function, it was researched that revealing the relevance between pore structure change in the wall and GPF function. Therefore, to understand the catalyst coated state difference, cGPF of several coating methods were prepared, and their properties were evaluated by various analyses, and performance was tested.

To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.

At present, measurements of running resistance are conducted outdoors as a matter of course. Because of this, the ambient temperature at the time of the measurements has a considerable impact on the measurement data. The research discussed in this paper focused on the temperature characteristic of the tires and developed a new correction technique using a special rolling test apparatus. Specifically, using a tire rolling test apparatus that made it possible to vary the ambient temperature, measurements were conducted while varying the levels of factors other than temperature that affect rolling resistance (load, inflation pressure, and speed). Next, a regression analysis was applied to the data for each factor, and coefficients for a relational expression were derived, making it possible to derive a quadratic equation for the tire rolling resistance correction formula.

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.

We studied a simple and cost effective controlled auto ignition (CAI) combustion engine in order to achieve simultaneous reduction of NOx and soot, which are issues in diffusion combustion. The engine type was a uniflow scavenging 2-stroke engine, and the fuel used was diesel, as is common in diesel engines. We examined the position of the injector that effectively forms the premixture and realized stable operation with diesel fuel by the low pressure fuel injection device for port fuel injection (PFI), and it was found that the CAI combustion ignition timing can be controlled through setting the air/fuel ratio that obtains the optimal ignition timing per operation conditions.

Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.