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Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.

As GHG and fuel economy regulations of light-duty vehicles have become more stringent, advanced emissions reduction technology has extensively penetrated the US light-duty vehicle fleet. This new technology includes not only advanced conventional engines and transmissions, but also greater adoption of electrified powertrains. In 2022, electrified vehicles – including mild hybrids, strong hybrids, plug-ins, and battery electric vehicles – made up nearly 17% of the US fleet and are on track to further increase their proportion in subsequent years. The Environmental Protection Agency (EPA) has previously used its Advanced Light-Duty Powertrain and Hybrid Analysis (ALPHA) full vehicle simulation tool to evaluate the greenhouse gas (GHG) emissions of light-duty vehicles. ALPHA contains a library of benchmarked powertrain components that can be matched to specific vehicles to explore GHG emissions performance.

Multiple areas in the U.S. continue to struggle with achieving National Ambient Air Quality Standards for ozone. These continued issues highlight the need for further reductions in NOX emission standards in multiple industry sectors, with heavy-duty on-highway engines being one of the most important areas to be addressed. Starting in 2014, CARB initiated a series of technical demonstration programs aimed at examining the feasibility of achieving up to a 90% reduction in tailpipe NOX, while at the same time maintaining a path towards GHG reductions that will be required as part of the Heavy-Duty Phase 2 GHG program. These programs culminated in the Stage 3 Low NOX program, which demonstrated low NOX emissions while maintaining GHG emissions at levels comparable to the baseline engine.

Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.

This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement.

Despite considerable progress towards clean air in previous decades, parts of the United States continue to struggle with the challenge of meeting the ambient air quality targets for smog-forming ozone mandated by the U.S. EPA, with some of the most significant challenges being seen in California. These continuing issues have highlighted the need for further reductions in emissions of NOX, which is a precursor for ozone formation, from a number of key sectors including the commercial vehicle sector. In response, the California Air Resources Board (CARB) embarked on a regulatory effort culminating in the adoption of the California Heavy-Duty Low NOX Omnibus regulation.[1] This regulatory effort was supported by a series of technical programs conducted at Southwest Research Institute (SwRI).

In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.

Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.

This paper describes a new method for measuring oil consumption using laser induced breakdown spectroscopy (LIBS). LIBS focuses a high energy laser pulse on a sample to form a transient plasma. As the plasma cools, each element produces atomic emission lines which can be used to identify and quantify the elements present in the original sample. In this work, a LIBS system was used on simulated engine exhaust with a focus on quantifying the inorganic components (termed ash) of the particulate emissions. Because some of the metallic elements in the ash almost exclusively result from lube oil consumption, their concentrations can also be correlated to an oil consumption rate. Initial testing was performed using SwRI’s Exhaust Composition Transient Operation Laboratory®(ECTO-Lab®) burner system so that oil consumption and ash mass could be precisely controlled.

Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.

Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.

Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.

A novel total hydrocarbon (THC) emission concentration estimation model is proposed for reduction of engine development cost and simplification of exhaust measurements. The proposed method uses the absorbance spectra of a Fourier transform infrared (FTIR) spectrometer, which contains the information on a wide variety of hydrocarbons, as input. The model is based on machine learning algorithms including the least absolute shrinkage and selection operator (LASSO) regression and bagging techniques. To train the model, we created a dataset containing pairs of a spectrum of engine exhaust gas and the THC concentration. In addition, we incorporate absorbance spectra of individual hydrocarbon components and several inorganic components so that the model learns the contribution of each hydrocarbon to THC concentration and to ignore interferences of irrelevant gas components.

The U.S. Environmental Protection Agency (EPA) certifies gasoline deposit control additives for intake valve deposit (IVD) control utilizing ASTM D5500, a vehicle test using a1985 BMW 318i. Concerns with the age of the test fleet, its relevance in the market today, and the availability of replacement parts led the American Chemistry Council’s (ACC) Fuel Additive Task Group (FATG) to begin a program to develop a replacement. General Motors suggested using a 2.4L LE9 test engine mounted on a dynamometer and committed to support the engine until 2030. Southwest Research Institute (SwRI®) was contracted to run the development program in four Phases. In Phase I, the engine test stand was configured, and a test fuel selected. In Phase II, a series of tests were run to identify a cycle that would build an acceptable level of deposits on un-additized fuel. In Phase III, the resultant test cycle was examined for repeatability.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.

The objective of this research was to mitigate urea-derived deposit formation within selective catalytic reduction (SCR) aftertreatment systems by application of specific superhydrophobic coatings to exhaust pipe surfaces. Coatings were applied using a plasma immersion ion processing (PIIP)-like process denoted LotusFlo™. This process utilizes high DC-impulse power waveforms in conjunction with appropriate chemical precursors to generate coatings suited to a specific application. For the present research, organosiloxane (Lotus-130) and fluorinated organosiloxane (Lotus-131) coated surfaces were evaluated. Deposit accumulation studies were executed using the Exhaust Composition Transient Operation LaboratoryTM (ECTO-LabTM) burner system. An in-situ imaging system was installed in the ECTO-Lab to observe differences in the deposit formation process between coated and uncoated exhaust pipes.

SCR-on-filter, or SCRoF, is an emerging technology for different market segments and vehicle applications. The technology enables simultaneous particulate matter trapping and NOX reduction, and provides thermal management and aftertreatment packaging benefits. However, there is little information detailing the lubricant derived exposure effects on functional SCR performance. A study was conducted to evaluate the impact of various oil consumption pathways on a light duty DOC and SCRoF aftertreatment system. This aftertreatment system was aged utilizing an engine test bench modified to enable increased oil consumption rates via three unique oil consumption pathways. The components were characterized for functional SCR performance, ash morphology, and ash deposition characteristics. This included utilizing techniques, such as SEM / EDS, to evaluate the ash structures and quantify the ash elemental composition.

Lithium plating refers to the phenomenon where lithium metal is deposited onto the surface of the anode instead of being intercalated into the carbon sites of the graphite. The lithium metal will cover a portion of the surface area of the anode, which blocks intercalation sites and increases charge gradients. Lithium plating most often occurs when charging the battery at low ambient temperatures or at a high current rate, but lithium plating formation has also been linked to solid electrolyte interface (SEI) growth towards the later stages of life. Lithium plating may significantly reduce a battery cell’s performance in terms of charge capacity, and if severe enough, the lithium metal may form a bridge across the separator of the cell, leading to short circuits and potential safety concerns. The internal research performed by Southwest Research Institute explored how to create a battery model to detect the formation of lithium plating in real time.

Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.