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Water vapor is, aside from carbon dioxide, the major fossil fuel combustion by-product. Depending on its concentration in the exhaust gas mixture as well as on the exhaust gas pressure, its condensation temperature can be derived. For typical gasoline engine stoichiometric operating conditions, the water vapor dew point lies at about 53 °C. The exhaust gas mixture does however contain some pollutants coming from the fuel, engine oil, and charge air, which can react with the water vapor and affect the condensation process. For instance, sulfur trioxide present in the exhaust, reacts with water vapor forming sulfuric acid. This acid builds a binary system with water vapor, which presents a dew point often above 100 °C. Exhaust composition after leaving the combustion chamber strongly depends on fuel type, engine concept and operation point. Furthermore, the exhaust undergoes several chemical after treatments.

This paper investigates the effect of the cetane number (CN) of a diesel fuel on the energy balance between a light duty (1.9L) and medium duty (4.5L) diesel engine. The two engines have a similar stroke to bore (S/B) ratio, and all other control parameters including: geometric compression ratio, cylinder number, stroke, and combustion chamber, have been kept the same, meaning that only the displacement changes between the engine platforms. Two Coordinating Research Council (CRC) diesel fuels for advanced combustion engines (FACE) were studied. The two fuels were selected to have a similar distillation profile and aromatic content, but varying CN. The effects on the energy balance of the engines were considered at two operating conditions; a “low load” condition of 1500 rev/min (RPM) and nominally 1.88 bar brake mean effective pressure (BMEP), and a “medium load” condition of 1500 RPM and 5.65 BMEP.

Certain diesel fuel specification properties are considered to be environmental parameters according to the European Fuels Quality Directive (FQD, 2009/EC/30) and previous regulations. These limits included in the EN 590 specification were derived from the European Programme on Emissions, Fuels and Engine Technologies (EPEFE) which was carried out in the 1990’s on diesel vehicles meeting Euro 2 emissions standards. These limits could potentially constrain FAME blending levels higher than 7% v/v. In addition, no significant work has been conducted since to investigate whether relaxing these limits would give rise to performance or emissions debits or fuel consumption benefits in more modern vehicles. The objective of this test programme was to evaluate the impact of specific diesel properties on emissions and fuel consumption in Euro 4, Euro 5 and Euro 6 light-duty diesel vehicle technologies.

In a modern diesel engine, a high fuel injection pressure is achieved by a common-rail system. Therefore, it is important to understand the effects of fuel properties on engine performances because a diesel fuel could deteriorate inside an injector at such severe conditions. The test methods so far basically use the fuel with pro-fouling agent to form deposit on injector. In this study, a novel test procedure was developed to evaluate the effect of the use of the fuel with and without zinc contaminant on injector performance. With Zn doped European specification B7 fuel (7% biodiesel) as a reference, the test result showed that an engine torque decreased almost lineally over time, and the overall torque drop was 9% after 300 hours. The investigation of the dismantled injector after the test revealed that the deposit was not formed on the sliding parts of the injector, but on the nozzle hole surface.

The formation of deposits within injector nozzle holes of common-rail injection fuel systems fitted to modern diesel cars can reduce and disrupt the flow of fuel into the combustion chamber. This disruption in fuel flow results in reduced or less efficient combustion and lower power output. Hence there is sustained interest across the automotive industry in studying these deposits, with the ultimate aim of controlling them. In this study, we describe the use of Scanning Electron Microscopy (SEM) imaging to characterise fuel injector hole deposits at intervals throughout an adaptation of the CEC Direct Injection Common Rail Diesel Engine Nozzle Coking Test, CEC F-98-08 (DW10B test)[1]. In addition, a similar adaptation of a previously published Shell vehicle test method [2] was employed to analyse fuel injector hole deposits from a fleet of Euro 5 vehicles. During both studies, deposits were compared after fouling and after subsequent cleaning using a novel fuel borne detergent.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Regulations on emissions from diesel and gasoline fuelled engines are becoming more stringent in all parts of the world. Hence there is a great deal of interest in developing advanced combustion systems that offer the efficiency of a diesel engine, but with low PM and NOx. One promising approach is that of Partially-Premixed Compression Ignition (PPCI) or Low Temperature Combustion (LTC). Using this approach, PM can be reduced in compression ignition engines by promoting the mixing of fuel and air prior to combustion. This paper describes the application of an advanced combustion simulator for fuels, combustion and emissions to analyze the key processes which occur in PPCI combustion mode. A detailed chemical kinetic model with advanced PM population balance sub-model is employed in a PPCI engine context to examine the impact of ignition resistance on combustion, mixing, ignition and emissions.

Internal combustion engines with lean homogeneous charge and auto-ignition combustion of gasoline fuels have the capability to significantly reduce fuel consumption and realize ultra-low engine-out NOx emissions. Group research of Volkswagen AG has therefore defined the Gasoline Compression Ignition combustion (GCI®) concept. A detailed investigation of this novel combustion process has been carried out on test bench engines and test vehicles by group research of Volkswagen AG and IAV GmbH Gifhorn. Experimental results confirm the theoretically expected potential for improved efficiency and emissions behavior. Volkswagen AG and IAV GmbH will utilize a highly flexible externally supercharged variable valve train (VVT) engine for future investigations to extend the understanding of gas exchange and EGR strategy as well as the boost demands of gasoline auto-ignition combustion processes.

The regeneration of a Diesel Particulate Filter (DPF) is dependent on both the amount and type of soot present on the filter. The objective of this work is to understand how the fuel can affect this ease with which soot can be oxidized. This soot was produced in a two-cylinder four-stroke direct-injection diesel engine, operated with a matrix of fuels with varying aromatic and sulphur level. Their oxidation behaviour in different environments was determined by Temperature Programmed Oxidation in TGA and a six-flow reactor. Transmission electron microscopy was used to examine the soot morphology. Oxidation with only O2 shows oxidation temperatures strongly dependent on the fuel type. Soot oxidation in the presence of NO and a Pt-catalyst results in a lower oxidation temperature. SO2 has an inhibiting effect leading to higher soot oxidation temperature.

An investigation was conducted to elucidate, how the latest turbocharged, direct injection Volkswagen diesel engine generation with cylinder pressure based closed loop control, to be launched in the US in 2008, reacts to fuel variability. A de-correlated fuels matrix was designed to bracket the range of US market fuel properties, which allowed a clear correlation of individual fuel properties with engine response. The test program consisting of steady state operating points showed that cylinder pressure based closed loop control successfully levels out the influence of fuel ignition quality, showing the effectiveness of this new technology for markets with a wide range of fuel qualities. However, it also showed that within the cetane range tested (39 to 55), despite the constant combustion mid-point, cetane number still has an influence on particulate and gaseous emissions. Volatility and energy density also influence the engine's behavior, but less strongly.

This paper compares 4 different EGR systems by means of simulation in GT-Power. The demands of optimum massive EGR and fresh air rates were based on experimental results. The experimental data were used to calibrate the model and ROHR, in particular. The main aim was to investigate the influence of pumping work on engine and vehicle fuel consumption (thus CO2 production) in different EGR layouts using optimum VG turbine control. These EGR systems differ in the source of pressure drop between the exhaust and intake pipes. Firstly, the engine settings were optimized under steady operation - BSFC was minimized while taking into account both the required EGR rate and fresh air mass flow. Secondly, transient simulations (NEDC cycle) were carried out - a full engine model was used to obtain detailed information on important parameters. The study shows the necessity to use natural pressure differences or renewable pressure losses if reasonable fuel consumption is to be achieved.

Control of NOx and Particulate Matter (PM) emissions from diesel engines remains a significant challenge. One approach to reduce both emissions simultaneously without fuel economy penalty is the reformed exhaust gas recirculation (REGR) technique, where part of the fuel is catalytically reacted with hot engine exhaust gas to produce a hydrogen-rich combustible gas that is then fed to the engine. On the contrary to fuel cell technology where the reforming requirements are to produce a reformate with maximized H2 concentration and minimized (virtually zero) CO concentration, the key requirement of the application of the exhaust gas fuel reforming technique in engines is the efficient on-demand generation of a reformate with only a relatively low concentration of hydrogen (typically up to 20%).

Laser-based measurements of charge temperature and exhaust gas recirculation (EGR) ratio in an homogeneous charge compression ignition (HCCI) engine are demonstrated. For this purpose, the rotational coherent anti-Stokes Raman spectroscopy technique (CARS) was used. This technique allows temporally and locally resolved measurements in combustion environments through only two small line-of-sight optical accesses and the use of standard gasoline as a fuel. The investigated engine is a production-line four-cylinder direct-injection gasoline engine with the valve strategy modified to realize HCCI-operation. CARS-measurements were performed in motored and fired operation and the results are compared to polytropic calculations. Studies of engine speed, load, valve timing, and injection pressure were conducted showing the strong influence of charge temperature on the combustion timing.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

BMW VALVETRONIC technology is able to maintain the most important measures to reduce emissions. The further optimized charge movement created by VALVETRONIC stabilizes the combustion in the catalyst heating mode with extremely retarded ignition timing. When the engine is warm the high residual gas tolerance ensures very low Engine-Out NOx emissions and at the same time a low level of hydrocarbons. The atomization of fuel droplets due to high flow velocity in the valve gap area leads to improved mixture formation and reduced wall wetting. Engine-Out HC emissions in a cold engine are therefore reduced. Combined, the emission measures achieve robust and efficient emission control. In combination with additional after-treatment like secondary air system and catalysts using high cell density VALVETRONIC engines form an excellent base for SULEV emission regulations without neglecting the typical BMW claim of efficient dynamics.

The control over particulate emissions is becoming increasingly important in modern diesel engines for Heavy Duty applications, that will comply to more and more stringent emissions norms. Use of particulate traps is an effective means of achieving this with the need to regenerate the particulate trap being imperative. Passive regeneration using NO2 by conversion of NO, as well as regeneration at lower temperatures with catalyzed DPF and the influence of NOx to soot ratio on this, is the subject of the paper. Both coated and uncoated filters in fresh and aged state are evaluated at temperatures typical of passive NO2 and Oxygen-based soot regenerations and the results discussed.

In direct-injection gasoline (GDI) engines with charge stratification, minimizing engine-out nitrogen oxide (NOx) emission is crucial since exhaust-gas aftertreatment tolerates only limited amounts of NOx. Reduced NOx production directly lowers the frequency of energy-inefficient catalyst regeneration cycles. In this paper we investigate NO formation in a realistic GDI engine. Quantitative in-cylinder measurements of NO concentrations are carried out via laser-induced fluorescence imaging with excitation of NO (A-X(0,2) band at 248 nm), and subsequent fluorescence detection at 220-240 nm. Engine modifications were kept to a minimum in order to provide results that are representative of practical operating conditions. Optical access via a sapphire ring enabled identical engine geometry as a production line engine. The engine is operated with commercial gasoline (“Super-Plus”, RON 98).

Future catalyst systems need to be highly efficient in a limited packaging space. This normally leads to a design where the flow distribution, in front of the catalyst, is not perfectly uniform. Measurements on the flow test bench show that the implementation of perforated foils for the corrugated and flat foils has the capability to distribute the flow within the channels in the radial direction so that the maximum of the given catalyst surface is of use, even under very poor uniformity indices. Therefore a remarkable reduction in back pressure is measured. Emission results demonstrate cold start improvement due to reduced heat capacity. The use of LS - structured ( Longitudinal structured ) corrugated foils creates a high turbulence level within the single channels. The substrate lights-up earlier and the maximum conversion efficiency is reached more quickly.

1 In this paper results obtained with different particulate matter (PM) reduction technologies are presented. Diesel oxidation catalysts (DOC) are well known as a reliable PM reduction technology which can efficiently remove the soluble organic fraction (SOF) but which has no effect on the solid particles in PM. A drawback is that in combination with high sulfur fuel, oxidation of SO2 to SO3 by the DOC can occur, resulting in an increase of PM emissions. An alternative technology that is proven to significantly reduce soot emissions comprises diesel particulate wall-flow filters. High filtration efficiencies of up to 90% and beyond are feasible. The main obstacle is the combustion of the trapped soot. As shown in this paper, the application of a catalyst coating to the filter aids the filter regeneration by lowering the balance-point temperature. The main disadvantages of wall-flow filters are an increase in back-pressure and possible plugging caused by oil-ash accumulations.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.