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Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

Previous work of the authors' group has shown that biodiesel fuels as a replacement for conventional diesel fuel in engine combustion can reduce PM level dramatically while lowering some other regulated emissions as well. It has shown that these fuels have the potential to increase the overall engine performance due to their lower sulphur and/or aromatics content compared with standard diesel fuels. This paper presents a study on a single cylinder naturally aspirated direct injection (DI) diesel engine, equipped with a pump-line-nozzle injection system, operating with varied biodiesel fuel blends (0%, 25%, and 50% of RME by volume) with ultra low sulphur diesel fuel (ULSD). The detailed analysis of the measurement data shows that the ignition delay and exhaust emissions are affected by the proportion of biodiesel due to the effect of different physical and chemical properties of the two fuels.